scholarly journals Stable Isotope (S, Mg, B) Constraints on the Origin of the Early Precambrian Zhaoanzhuang Serpentine-Magnetite Deposit, Southern North China Craton

Minerals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 377 ◽  
Author(s):  
Jie Meng ◽  
Houmin Li ◽  
Yanhe Li ◽  
Zhaochong Zhang ◽  
Lixing Li ◽  
...  
Keyword(s):  
North China Craton ◽  
Carbonate Rocks ◽  
North China ◽  
Mean Value ◽  
Coarse Grained ◽  
Sulfur Source ◽  
Marine Carbonate ◽  
Isotopic Analyses ◽  
Wide Range ◽  
Marine Carbonate Rocks

The origin of the Zhaoanzhuang serpentine-magnetite deposit in the southern North China Craton (NCC) is highly disputed, with some investigators having proposed an ultramafic origin, whereas others favor a chemical sedimentary origin. These discrepancies are largely due to the difficulty in determining the protolithic characteristics of the highly metamorphosed rocks. Sulfur, magnesium, and boron isotope geochemistry combined with detailed petrography was carried out in this study to constrain the original composition of the Zhaoanzhuang iron orebodies. Anhydrite is present as coarse crystals intergrown with magnetite, indicating that the anhydrite formed simultaneously with the magnetite during metamorphism rather than as a product of later hydrothermal alteration. The anhydrite has a narrow range of positive δ34S values from +19.8 to +22.5‰ with a mean value of +21.1‰. These values are significantly higher than that of typical magmatic sulfur (δ34S = 0 ± 5‰) and deviate away from primary igneous anhydrite towards mantle-sulfur isotopic values, but they are similar to those of marine evaporitic anhydrite and gypsum (~+21‰). The sulfur isotopic compositions of several samples show obvious signs of mass-independent sulfur fractionation (Δ33S = −0.47‰ to +0.90‰), suggesting that they were influenced by an external sulfur source through a photochemical reaction at low oxygen concentrations, which is consistent with the Neoarchean-Paleoproterozoic atmosphere. Coarse-grained tourmaline from the tourmaline-rich interlayers of the orebodies occurs closely with Mg-rich minerals such as phlogopite, talc, and diopside, indicating that it has a metamorphic origin. The δ11B values of the tourmaline range from −0.2‰ to +3.6‰ with a mean value of +2.0‰, which is much positive relative to that of magmatic tourmaline but is consistent with that of carbonate-derived tourmaline. The magnesium isotopic analyses of the serpentine–magnetite ores and the magnesium-rich wall rocks revealed a wide range of very negative δ26Mg values from −1.20‰ to −0.34‰ with an average value of −0.80‰. The value is higher than that of ultramafic rocks (δ26Mg = −0.25‰) and exhibits minor Mg isotopic fractionation. However, these values are consistent with those of marine carbonate rocks, which have lower δ26Mg values and larger Mg isotopic variations (δ26Mg = −0.45‰ to −4.5‰). Collectively, the S–Mg–B isotopic characteristics of the Zhaoanzhuang iron orebodies clearly indicate a chemical sedimentary origin. The protoliths of these orebodies most likely reflect a series of Fe–Si–Mg-rich marine carbonate rocks with a considerable evaporite component, indicating a carbonate-rich superior-type banded iron formation precipitated in an evaporitic shallow marine sedimentary environment.

scholarly journals The Remagnetization of Marine Carbonate Rocks of the Late Ordovician in Pingliang Section, Southwest Ordos (China)

2019 ◽  
Vol 93 (S3) ◽  
pp. 132-134
Author(s):  
Junhua LUO ◽  
Shuang DAI ◽  
Mark DEKKERS ◽  
Weiguo WANG ◽  
Xiaoke QIANG ◽  
...  
Keyword(s):  
Carbonate Rocks ◽  
Late Ordovician ◽  
Marine Carbonate ◽  
Marine Carbonate Rocks

The Shibantan Lagerstätte: insights into the Proterozoic–Phanerozoic transition

2020 ◽  
Vol 178 (1) ◽  
pp. jgs2020-135
Author(s):  
Shuhai Xiao ◽  
Zhe Chen ◽  
Ke Pang ◽  
Chuanming Zhou ◽  
Xunlai Yuan
Keyword(s):  
South China ◽  
Carbonate Rocks ◽  
Microbial Mats ◽  
Ecological Interactions ◽  
Benthic Organisms ◽  
Important Data ◽  
Ediacara Biota ◽  
Marine Carbonate ◽  
Fossil Assemblages ◽  
Marine Carbonate Rocks

The Shibantan Lagerstätte (551–543 Ma) in the Yangtse Gorges area in South China is one of the best-known examples of terminal Ediacaran fossil assemblages preserved in marine carbonate rocks. Taxonomically dominated by benthic organisms, the Shibantan Lagerstätte preserves various photoautotrophs, biomineralizing tubular fossils, Ediacara-type macrofossils (including rangeomorphs, arboreomorphs, erniettomorphs, palaeopascichnids, a possible dickinsoniomorph, the mobile bilaterian Yilingia and soft-bodied tubular fossils), abundant ichnofossils and a number of problematic and dubious fossils. Shibantan fossils provide intriguing insights into ecological interactions among mobile bilaterians, sessile benthic Ediacara-type organisms and microbial mats, thus offering important data to test various hypotheses accounting for the decline of the Ediacara biota and the concurrent expansion of bilaterian bioturbation and mobility across the Proterozoic–Phanerozoic transition.

U–Pb and Hf isotopic study of detrital zircons from the Lüliang khondalite, North China Craton, and their tectonic implications

2009 ◽  
Vol 146 (5) ◽  
pp. 701-716 ◽  
Author(s):  
XIAOPING XIA ◽  
MIN SUN ◽  
GUOCHUN ZHAO ◽  
FUYUAN WU ◽  
LIEWEN XIE
Keyword(s):  
North China Craton ◽  
North China ◽  
Detrital Zircons ◽  
Crustal Material ◽  
Isotopic Data ◽  
Isotopic Study ◽  
Metasedimentary Rocks ◽  
The North ◽  
Wide Range ◽  
Western Block

AbstractTwo types of metasedimentary rocks occur in the Trans-North China Orogen of the North China Craton. One type consists of highly metamorphosed supracrustal rocks with protoliths of mature cratonic shale, called khondalites, as found in the Lüliang Complex; rocks of the other type are also highly metamorphosed but less mature, as represented by the Wanzi supracrustal assemblage in the Fuping Complex. U–Pb isotopic data for detrital zircons from khondalites show a provenance dominated by 1.9–2.1 Ga Palaeoproterozoic rocks. These detrital zircons display a wide range of εHfvalues from −16.0 to +9.2 and give Hf isotopic model ages mostly around 2.3 Ga. The high positive εHfvalues approach those for the depleted mantle at 2.1 Ga, highlighting a juvenile crustal growth event in Palaeoproterozoic times. Hf isotopic data also imply thatc.2.6 Ga old crustal material was involved in the Palaeoproterozoic magmatic event. These data are similar to those for the khondalitic rocks from the interior of the Western Block of the North China Craton, suggesting a common provenance. In contrast, other metasedimentary rocks in the Trans-North China Orogen, such as the Wanzi supracrustal assemblage in the Fuping Complex, have a source region with both Palaeoproterozoic and Archaean rocks. Their detrital zircon Hf isotopic data indicate reworking of old crustal material and a lack of significant juvenile Palaeoproterozoic magmatic input. These rocks are similar to the coevally deposited meta-sedimentary rocks in the interior of the Eastern Block. We propose that the Lüliang khondalites were deposited on the eastern margin of the Western Block in a passive continental margin environment and were thrust eastward later during collision with the Eastern Block. Other metasedimentary rocks in the Trans-North China Orogen were deposited on the western margin of the Eastern Block in a continental arc environment. Our data support the eastward subduction model for the Palaeoproterozoic tectonic evolution of the North China Craton.

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