scholarly journals Enhancement of A Cationic Surfactant by Capping Nanoparticles: Synthesis, Characterization and Multiple Applications

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2007 ◽  
Author(s):  
A. Labena ◽  
M. A. Hegazy ◽  
W. M. Kamel ◽  
Amr Elkelish ◽  
Wael N. Hozzein
Keyword(s):  
Corrosion Inhibition ◽  
Cationic Surfactant ◽  
Corrosion Inhibitors ◽  
Oil Field ◽  
Metal Corrosion ◽  
Bacterial Biofilms ◽  
Pseudomonas Sp ◽  
Formation Water ◽  
Yeast Strains ◽  
Field Formation

There is scarce information on cationic surfactants’ biocidal and corrosion inhbibition effects on Slime-Forming Bacteria (SFB) isolated from oil field formation water. Therefore, this work focused on the the synthesis of a cationic surfactant (CS) to increase its features by capping different metal nanoparticles (zinc, ZnNPs-C-CS; manganese, MnNPs-C-CS and tin, SnNPs-C-CS) and used them as biocides and corrosion inhibitors. The cationic surfactant was synthesized and characterized by Fourier-Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. Afterwards, different nanoparticles were synthesized, characterized, and exploited to cap by the CS. The CS and the different nanoparticles capped by the CS were tested for their antimicrobial susceptibility against standard bacterial and yeast strains. The synthesized compounds were further evaluated as anti-biofilms agents against positively-developed bacterial biofilms. Moreover, the CS and the ZnNPs-C-CS, MnNPs-C-CS, and SnNPs-C-CS were assessed as potential biocides against SFB, particularly Pseudomonas sp. (isolated from contaminated formation water), and as corrosion inhibitors against cultivated salinity. The results revealed the great effect of the different CS-capped NPs as broad-spectrum antimicrobial and anti-biofilm agents at lower Minimum Inhibitory Concentrations (MICs), Minimum Bactericidal Concentrations (MBCs), Minimum Fungicidal Concentrations (MFCs) and Minimum Biofilm Inhibitory Concentrations (MBICs), and the activities were reported in order of SnNPs-C-CS > MnNPs-C-CS > ZnNPs-C-CS > CS. Furthermore, the ZnNPs-C-CS, MnNPs-C-CS, and SnNPs-C-CS demonstrated biocidal and corrosion inhibition effects against Pseudomonas sp. at a salinity of 3.5% NaCl, with metal corrosion inhibition efficiencies of 88.6, 94.0 and 96.9%, in comparison to a CS efficiency of 85.7%. In conclusion, the present work provides a newly synthesized cationic surfactant and has enhanced its antimicrobial and its metal corrosion inhibition effects by capping different nanoparticles, and it has been successfully applied against slime-forming bacteria at a salinity of 3.5% NaCl.

Corrosion of N80 carbon steel in oil field formation water containing CO2 in the absence and presence of acetic acid

2011 ◽  
Vol 53 (10) ◽  
pp. 3156-3165 ◽  
Author(s):  
S.D. Zhu ◽  
A.Q. Fu ◽  
J. Miao ◽  
Z.F. Yin ◽  
G.S. Zhou ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Carbon Steel ◽  
Oil Field ◽  
Formation Water ◽  
Field Formation

Application of bioflocculating property ofPseudomonas aeruginosastrain IASST201 in treatment of oil-field formation water

2014 ◽  
Vol 54 (7) ◽  
pp. 658-669 ◽  
Author(s):  
Mihirjyoti Pathak ◽  
Arundhuti Devi ◽  
Hridip Kumar Sarma ◽  
Banwari Lal
Keyword(s):  
Oil Field ◽  
Formation Water ◽  
Field Formation

scholarly journals Corrosion Behavior of Austenitic Stainless Steels in CO2-Saturated Synthetic Oil Field Formation Water

2019 ◽  
Vol 22 (4) ◽  
Author(s):  
Jorge Luiz Cardoso ◽  
Marcel Mandel ◽  
Lutz Krüger ◽  
Luís Flávio Gaspar Herculano ◽  
Pedro de Lima Neto ◽  
...  
Keyword(s):  
Corrosion Behavior ◽  
Stainless Steels ◽  
Austenitic Stainless Steels ◽  
Oil Field ◽  
Formation Water ◽  
Synthetic Oil ◽  
Field Formation

scholarly journals Progressive Applications of Hyperbranched Polymer Based on Diarylamine: Antimicrobial, Anti-Biofilm and Anti-Aerobic Corrosion

Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2076
Author(s):  
Khalid I. Kabel ◽  
Ahmed Labena ◽  
Mohamed Keshawy ◽  
Wael N. Hozzein
Keyword(s):  
Corrosion Inhibition ◽  
Methyl Acrylate ◽  
Chemical Structure ◽  
Antimicrobial Activities ◽  
Metal Corrosion ◽  
Gram Negative Bacteria ◽  
One Pot ◽  
Yeast Strains ◽  
1Hnmr Spectroscopy ◽  
Positive Controls

New generations of hyperbranched aramids were synthesized from diarylamine and methyl acrylate using an AB2 monomer approach in a straightforward one-pot preparation. The chemical structure of hyperbranched Phenylenediamine/Methyl Acrylate HB(PDMA was confirmed by Fourier Transform Infrared (FTIR) and Nuclear Magnetic Resonance (1HNMR) spectroscopy. In addition, the particle’s size and distribution were recorded using Dynamic Light Scattering (DLS). Moreover, the synthesized HB(PDMA)s displayed broad-spectrum antimicrobial activities against Gram-positive and Gram-negative bacteria as well as yeast strains and anti-biofilm activity where the highest activity was attributed to HB(PDMA)G4 at the lowest Minimum Inhibitory, Minimum Bactericidal, and Fungicidal Concentrations (MIC, MBC, and MFC, respectively). Furthermore, the HB(PDMA)s expressed anti-bacterial activity against isolated Pseudomonas sp. (R301) at a salinity of 35,000 ppm (NaCl). In addition, they revealed different corrosion inhibition efficiencies at the cultivated medium salinity at the estimated minimum bactericidal concentrations. The highest metal corrosion inhibition efficiencies were 59.5 and 94.3% for HB(PDMA)G4 at the Minimum Bactericidal Concentrations (MBCs) and two times Minimum Bactericidal Concentrations (2XMBCs), respectively, in comparison to both negative and positive controls.

scholarly journals A cost-effective and environmentally sustainable process for phycoremediation of oil field formation water for its safe disposal and reuse

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Bhaskar Das ◽  
Suresh Deka
Keyword(s):  
Algal Species ◽  
Complex Mixture ◽  
Cost Effective ◽  
Oil Field ◽  
Oil Well ◽  
Formation Water ◽  
Safe Disposal ◽  
Initial Inoculum ◽  
Field Formation ◽  
Remediation Process

Abstract High volumes of formation water comprising of complex mixture of hydrocarbons is generated during crude oil exploration. Owing to ecotoxicological concerns, the discharge of the formation water without remediation of hydrocarbonaceous pollutants is not permitted. Keeping this into mind, we carried out phycoremediation of hydrocarbons in formation water so that it can be safely discharged or re-used. For this, a native algal species was isolated from formation water followed by its morphological and 18S ribosomal RNA based identification confirming the algal isolate to be Chlorella vulgaris BS1 (NCBI GenBank Accession No. MH732950). The algal isolate exhibited high biomass productivity of 1.76 gm L−1 d−1 (specific growth rate: 0.21 d−1, initial inoculum: 1500 mg L−1) along with remediation of 98.63% petroleum hydrocarbons present in formation water within 14 days of incubation indicating an efficient hydrocarbon remediation process. Concomitantly, the hydrocarbon remediation process resulted in reduction of 75% Chemical Oxygen Demand (COD) load and complete removal of sulfate from formation water making it suitable for safe disposal or reuse as oil well injection water respectively. The present process overcomes the bottlenecks of external growth nutrient addition or dilution associated with conventional biological treatment resulting in a practically applicable and cost-effective technology for remediation of oil field formation water.

New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media

2019 ◽  
Vol 233 (11) ◽  
pp. 1571-1601
Author(s):  
Elsayed A. El-Sharaky ◽  
Eman A. Khamis ◽  
Olfat E. El-Azabawy ◽  
Aziza S. El-Tabei
Keyword(s):  
Surface Tension ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Cationic Surfactant ◽  
Steel Surface ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Measurements ◽  
Carbon Steel Surface ◽  
Corrosion Inhibition Efficiency

Abstract A new star shape tetra-cationic surfactant was synthesized to evaluate as corrosion inhibitors for carbon steel in different acid media. This surfactant prepared by the reaction of tris(2-(dimethylamino)ethyl) O,O′,O′′-(nitrilotris(ethane-2,1-diyl)) trimaleate with 1-bromododecane and abbreviated as STCS. The chemical structure of the prepared surfactant was confirmed by FT-IR, 13C and 1HNMR and elemental analysis. Their aggregation behavior in watery solution was explored by surface tension measurements. The surface tension of water was decreased nearly to 35 mN m−1 when adding the surfactant. This result demonstrates that the surfactant shows remarkable surface activity, due to the effect of the head groups. Corrosion inhibition efficiency of the surfactant on the carbon steel surface in 1 M hydrochloride acid and 1 M H2SO4 was evaluated using the electrochemical measurements. These measurements revealed that the synthesized surfactant act as effective mixed-type corrosion inhibitors. Their adsorption on a carbon steel surface was well described by the Langmuir adsorption isotherm. Corrosion inhibition efficiency was enhanced with increasing the concentration of inhibitor and increasing the temperatures. The results of the quantum chemical calculations and the electrochemical measurements were in good agreement.

Theoretical evaluation of the corrosion inhibition performance of aliphatic dipeptides

2021 ◽  
Author(s):  
Anton Kasprzhitskii ◽  
Georgy Lazorenko ◽  
Tatyana Nazdracheva ◽  
Aleksandr Kukharskii ◽  
Victor Yavna ◽  
...  
Keyword(s):  
Service Life ◽  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Environmentally Friendly ◽  
Metals And Alloys ◽  
Theoretical Evaluation ◽  
Operational Capabilities ◽  
Inhibition Performance

Corrosion significantly limits the operational capabilities of metals and alloys reducing their service life. Finding environmentally friendly and economically justified alternatives to commercially used corrosion inhibitors is an important problem....

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