scholarly journals Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7406
Author(s):  
Asmaa Kamal El-Deen ◽  
Kuniyoshi Shimizu

Deep eutectic solvents (DESs) have recently attracted attention as a promising green alternative to conventional hazardous solvents by virtue of their simple preparation, low cost, and biodegradability. Even though the application of DESs in analytical chemistry is still in its early stages, the number of publications on this topic is growing. Analytical procedures applying dispersive liquid–liquid microextraction based on the solidification of floating organic droplets (DLLME-SFOD) are among the more appealing approaches where DESs have been found to be applicable. Herein, we provide a summary of the articles that are concerned with the application of DESs in the DLLME-SFOD of target analytes from diverse samples to provide up-to-date knowledge in this area. In addition, the major variables influencing enrichment efficiency and the microextraction mechanism are fully investigated and explained. Finally, the challenges and future perspectives of applying DESs in DLLME-SFOD are thoroughly discussed and are critically analyzed.

2021 ◽  
Author(s):  
Huazi Wang ◽  
Qinqin Xu ◽  
Jinglong Jiao ◽  
Hai Wu

A solidified floating organic drop-dispersive liquid-liquid microextraction (SFOD-DLLME) was established for extraction of four benzophenone-ultraviolet filters (BP-UV filters) from water samples using a fatty acid deep eutectic solvent (DES) as...


2017 ◽  
Vol 33 (6) ◽  
Author(s):  
Tayeb Aissaoui ◽  
Inas M. AlNashef ◽  
Umair A. Qureshi ◽  
Yacine Benguerba

AbstractNovel solvents named deep eutectic solvents (DESs) have been intensively investigated in recent years. Their non-toxicity, biodegradability, low volatility, easy preparation and low cost make them promising green solvents for several industrial processes. This article provides a status review of the possible applications of DESs in natural gas (NG) sweetening by carbon dioxide (CO


2014 ◽  
Vol 675-677 ◽  
pp. 181-184 ◽  
Author(s):  
Gui Qi Huang ◽  
She Ying Dong ◽  
Zhen Yang ◽  
Ting Lin Huang

An ultrasound-assisted ionic liquid based dispersive liquid-liquid microextraction (UA-IL-DLLME) was developed for the determination of four plant hormones (6-benzyladenine (6-BA), kinetin (6-KT), 2, 4-dichlorophenoxy acetic acid (2, 4-D) and uniconazole (UN)) in soil, using high performance liquid chromatography (HPLC)-diode array detection (DAD). Several important parameters including the type and volume of extraction solvent, the volume of disperser solvent, ultrasound time, pH of the solution and salt effect were studied and optimized. Under optimum conditions, the limits of detections (LODs) for the target analytes were in the range of 0.002-0.01 μg g-1. And satisfactory recoveries of the target analytes in the soil samples were 79.3-96.7 %, with relative standard deviations (RSD, n=5) that ranged from 4.3 to 6.7%.


RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 50710-50720 ◽  
Author(s):  
A. Golbabanezhadazizi ◽  
E. Ranjbari ◽  
M. R. Hadjmohammadi ◽  
H. Daneshinejad

This work reports an efficient, quick and low-cost procedure for the determination of serotonin reuptake inhibitors (SSRIs) in low concentration levels in biological fluids.


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