scholarly journals Hybrid CoO Nanowires Coated with Uniform Polypyrrole Nanolayers for High-Performance Energy Storage Devices

Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 586 ◽  
Author(s):  
Yang ◽  
Chen ◽  
Guan
Keyword(s):  
Electric Conductivity ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Rate Capability ◽  
Carbon Support ◽  
Carbon Substrate ◽  
Energy Storage Devices ◽  
Step Method ◽  
Practical Applications ◽  
Hybrid Supercapacitors

Transition metal oxides with high theoretic capacities are promising materials as battery-type electrodes for hybrid supercapacitors, but their practical applications are limited by their poor electric conductivity and unsatisfied rate capability. In this work, a hybrid structure of CoO nanowires coated with conformal polypyrrole (Ppy) nanolayer is proposed, designed and fabricated on a flexible carbon substrate through a facile two-step method. In the first step, porous CoO nanowires are fabricated on flexible carbon substrate through a hydrothermal procedure combined with an annealing process. In the second step, a uniform nanolayer of Ppy is further coated on the surfaces of the CoO nanowires, resulting in a hybrid core-shell CoO@Ppy nanoarrays. The CoO@Ppy aligned on carbon support can be directly utilized as electrode material for hybrid supercapacitors. Since the conductive Ppy coating layer provides enhanced electric conductivity, the hybrid electrode demonstrates much higher capacity and superior rate capability than pure CoO nanowires. As a further demonstration, Ppy layer can also be realized on SnO2 nanowires. Such facile conductive-layer coating method can be also applied to other types of conducting polymers (as the shell) and metal oxide materials (as the core) for various energy-related applications.

scholarly journals Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 372
Author(s):  
Liyang Lin ◽  
Susu Chen ◽  
Tao Deng ◽  
Wen Zeng
Keyword(s):  
Energy Storage ◽  
Gas Sensors ◽  
High Performance ◽  
Gas Sensing ◽  
Synthesis Method ◽  
Rate Capability ◽  
Stannic Oxide ◽  
Energy Storage Devices ◽  
Graphene Nanocomposites ◽  
Storage Devices

The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.

Building sponge-like robust architectures of CNT–graphene–Si composites with enhanced rate and cycling performance for lithium-ion batteries

2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycling Stability ◽  
Great Promise ◽  
Practical Applications ◽  
Excellent Cycling Stability

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.

Nitrogen-enriched carbon spheres coupled with graphitic carbon nitride nanosheets for high performance supercapacitors

2018 ◽  
Vol 47 (29) ◽  
pp. 9724-9732 ◽  
Author(s):  
Jun Zhu ◽  
Lirong Kong ◽  
Xiaoping Shen ◽  
Hu Zhou ◽  
Guoxing Zhu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Carbon Nitride ◽  
Clean Energy ◽  
Carbon Spheres ◽  
Energy Storage Devices ◽  
Step Method ◽  
Storage Devices ◽  
Excellent Electrochemical Performance ◽  
Carbon Nitride Nanosheets

A facile two-step method is proposed to synthesize g-CN/NCS composites, which exhibit an excellent electrochemical performance in clean energy storage devices.

Facile preparation of MoS2/maleic acid composite as high-performance anode for lithium ion batteries

2020 ◽  
Vol 44 (37) ◽  
pp. 15887-15894
Author(s):  
Jingshi Wang ◽  
Zhigang Shen ◽  
Min Yi
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
Composite Anode ◽  
Step Method ◽  
Practical Applications ◽  
Excellent Electrochemical Performance ◽  
One Step ◽  
Facile Preparation

We propose a facile one-step method to prepare a MoS2 composite anode with excellent electrochemical performance and potential for practical applications in lithium ion batteries.

Mixed-metallic MOF based electrode materials for high performance hybrid supercapacitors

2017 ◽  
Vol 5 (3) ◽  
pp. 1094-1102 ◽  
Author(s):  
Yang Jiao ◽  
Jian Pei ◽  
Dahong Chen ◽  
Chunshuang Yan ◽  
Yongyuan Hu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Electrode Material ◽  
High Performance ◽  
Electrode Materials ◽  
Metal Organic Frameworks ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Hybrid Supercapacitors ◽  
Metal Organic

Metal–organic frameworks (MOFs) have obtained increasing attention as a kind of novel electrode material for energy storage devices.

scholarly journals A universal electrochemical lithiation–delithiation method to prepare low-crystalline metal oxides for high-performance hybrid supercapacitors

RSC Advances ◽  
2021 ◽  
Vol 11 (48) ◽  
pp. 30407-30414
Author(s):  
Zhuo-Dong Wu ◽  
De-Jian Chen ◽  
Long Li ◽  
Li-Na Wang
Keyword(s):  
Transition Metal ◽  
Electrochemical Performance ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Hybrid Supercapacitors ◽  
Electrochemical Lithiation ◽  
Low Crystalline ◽  
Crystalline Metal

The electrochemical performance of transition metal oxides (TMOs) for hybrid supercapacitors has been optimized through various methods in previous reports.

High-Performance Anode Materials with Superior Structure of Fe3O4/FeS/rGO Composite for Lithium Ion Batteries

NANO ◽  
2020 ◽  
Vol 15 (10) ◽  
pp. 2050128 ◽  
Author(s):  
Ruirui Gao ◽  
Suqin Wang ◽  
Zhaoxiu Xu ◽  
Hongbo Li ◽  
Shuiliang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Composite Electrode ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Charging And Discharging Processes ◽  
New Perspective

In this work, we developed a simple one-step hydrothermal method to successfully prepare Fe3O4/FeS-reduced graphene oxide (Fe3O4/FeS/rGO) composite directly, which is a novel Lithium-ion batteries (LIBs) anode material. The characterization of Fe3O4/FeS/rGO composite demonstrates that octahedral Fe3O4/FeS particles are uniformly deposited on the rGO, leading to a strong synergy between them. The excellent structural design can make Fe3O4/FeS/rGO composite to have higher reversible capacity (744.7[Formula: see text]mAh/g at 0.1[Formula: see text]C after 50 cycles), excellent cycling performance and superior rate capability. This outstanding electrochemical behavior can be attributed to the conductivity network of rGO, which improves the composite electrode conductivity, facilitates the diffusion and transfer of ions and prevents the aggregation and pulverization of Fe3O4/FeS particles during the charging and discharging processes. Moreover, the Fe3O4/FeS/rGO electrode surface is covered with a thin solid-electrolyte interface (SEI) film and the octahedral structure of Fe3O4/FeS particles is still clearly visible, which indicates that composite electrode has excellent interface stability. We believe that the design of this composite structure will provide a new perspective for the further study of other transition metal oxides for LIBs.

Bioinspired tailoring of nanoarchitectured nickel sulfide@nickel permeated carbon composite as highly durable and redox chemistry enabled battery-type electrode for hybrid supercapacitors

2021 ◽  
Author(s):  
Mohan Reddy Pallavolu ◽  
Ramesh Reddy N ◽  
Hemachandra Rao Goli ◽  
Arghya Narayan Banerjee ◽  
G. Rajasekhara Reddy ◽  
...  
Keyword(s):  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Cost Effective ◽  
Carbon Composite ◽  
Metal Chalcogenides ◽  
Energy Storage Devices ◽  
Active Electrode ◽  
Storage Devices ◽  
Hybrid Supercapacitors

Rational design of highly conductive and redox-active electrode materials composed of metal chalcogenides and carbon composites has attracted promising attention for the development of high-performance energy storage devices. Herein, cost-effective...

scholarly journals Ternary MOF-Based Redox Active Sites Enabled 3D-on-2D Nanoarchitectured Battery-Type Electrodes for High-Energy-Density Supercapatteries

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Goli Nagaraju ◽  
S. Chandra Sekhar ◽  
Bhimanaboina Ramulu ◽  
Sk. Khaja Hussain ◽  
D. Narsimulu ◽  
...  
Keyword(s):  
Active Sites ◽  
High Performance ◽  
Nickel Foam ◽  
Rate Capability ◽  
Negative Electrode ◽  
High Energy ◽  
High Energy Density ◽  
Phase Method ◽  
Charge Storage ◽  
Energy Storage Devices

Abstract Designing rationally combined metal–organic frameworks (MOFs) with multifunctional nanogeometries is of significant research interest to enable the electrochemical properties in advanced energy storage devices. Herein, we explored a new class of binder-free dual-layered Ni–Co–Mn-based MOFs (NCM-based MOFs) with three-dimensional (3D)-on-2D nanoarchitectures through a polarity-induced solution-phase method for high-performance supercapatteries. The hierarchical NCM-based MOFs having grown on nickel foam exhibit a battery-type charge storage mechanism with superior areal capacity (1311.4 μAh cm−2 at 5 mA cm−2), good rate capability (61.8%; 811.67 μAh cm−2 at 50 mA cm−2), and an excellent cycling durability. The superior charge storage properties are ascribed to the synergistic features, higher accessible active sites of dual-layered nanogeometries, and exalted redox chemistry of multi metallic guest species, respectively. The bilayered NCM-based MOFs are further employed as a battery-type electrode for the fabrication of supercapattery paradigm with biomass-derived nitrogen/oxygen doped porous carbon as a negative electrode, which demonstrates excellent capacity of 1.6 mAh cm−2 along with high energy and power densities of 1.21 mWh cm−2 and 32.49 mW cm−2, respectively. Following, the MOF-based supercapattery was further assembled with a renewable solar power harvester to use as a self-charging station for various portable electronic applications.

In Situ Growth of FeCo-Selenide on Ni Foam as High-Performance Electrode for Electrochemical Energy Storage Devices

NANO ◽  
2018 ◽  
Vol 13 (07) ◽  
pp. 1850078 ◽  
Author(s):  
An Ye ◽  
Jiqiu Qi ◽  
Yanwei Sui ◽  
Fei Yang ◽  
Fuxiang Wei ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Specific Capacity ◽  
Negative Electrode ◽  
Storage Device ◽  
Asymmetric Supercapacitor ◽  
Ni Foam ◽  
Energy Storage Devices ◽  
Practical Applications ◽  
Nanosheet Arrays

A solid-state energy storage device has been fabricated using FeCo-selenide nanosheet arrays as positive electrode and Fe2O3 nanorod as negative electrode. As an electrode material, the ternary FeCo-selenide nanosheet arrays supported by Ni foam show a highest specific capacitance of 978 F/g (specific capacity of 163[Formula: see text]mAh/g) at 1 A/g and a superior cycle behavior of 81.2% are obtained after 5000 cycles at current density of 4 A/g. The asymmetric supercapacitor achieves the maximum energy density of 34.6[Formula: see text]W[Formula: see text]h/kg at the power density of 759.6[Formula: see text]W/kg. Furthermore, the superior cycling stability with 83% retention of initial capacitance after 5000 cycles further verify the practical applications of FeCo-selenide//Fe2O3 asymmetric supercapacitor. Meanwhile, the LED bulb and the light board of “CUMT” are lighted by connecting several capacitors to form a series circuit.

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