scholarly journals Experimental Study on Nano-Parameters of Styrene-Butadiene-Styrene Block Copolymer Modified Bitumen Based on Atomic Force Microscopy

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 989 ◽  
Author(s):  
Wengang Zhang ◽  
Fang Wang ◽  
Jun Shi ◽  
Zhongmei Li ◽  
Xiaofei Liang
Keyword(s):  
Maximum Height ◽  
Short Term ◽  
Modified Bitumen ◽  
Height Difference ◽  
Atomic Force ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Lightweight Component ◽  
Morphology Parameters ◽  
Butadiene Styrene

In this paper, an atomic force microscope (AFM) was used to study the nano-morphology characteristics of styrene-butadiene-styrene block copolymer (SBS) modified bitumen. The effects of SBS content and short-term aging on the nano-morphology parameters of bitumen were studied. The correlation between nano-morphology parameters and main pavement performances of SBS modified bitumen was analyzed. The results show that with the increase of SBS content, the average area of bee-like structure and the proportions of bee-like structure area of SBS modified bitumen increases gradually, the roughness of the whole image and the roughness of the lightweight component region decreases gradually, but the increasing or decreasing trend is no longer obvious when the content of SBS is more than 4%. The maximum height difference of SBS modified bitumen is linear with the content of SBS. The larger the content of SBS, the smaller the influence of short-term aging on the nano-morphology of SBS modified bitumen. The penetration degree will decrease and the softening point will increase with the increase of the proportion of bee-like structure area of SBS modified bitumen. The ductility will decrease with the increase of the roughness of the lightweight component region. The ductility and the Brookfield viscosity will increase with the increase of the maximum height difference. The research results provided a reference for defining quantifiable nano-parameters of SBS modified bitumen and establishing the relationship between nano-parameters and pavement performances.

scholarly journals Study on Styrene-Butadiene-Styrene Modified Asphalt Binders Relaxation at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2888
Author(s):  
Sylwia Dziadosz ◽  
Mieczysław Słowik ◽  
Filip Niwczyk ◽  
Marcin Bilski
Keyword(s):  
Low Temperature ◽  
Force Measurement ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Short Term ◽  
Modified Bitumen ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The paper presents the results of laboratory investigation on asphalt binders relaxation at low temperature, carried out in a ductilometer using the tensile test with continuous force measurement. Polymer modified asphalt binder samples consisting of a 50/70 penetration grade bitumen mixed with a concentrate of styrene-butadiene-styrene (SBS) modified bitumen—a 160/220 penetration grade bitumen modified with a SBS copolymer in the amount of 9%—were tested. Therefore, polymer modified binders containing 3%, 4.5%, 6% and 7.5% SBS, respectively, were obtained and investigated. Tensile tests were performed at −16 °C on samples before aging and subjected to short-term aging (RTFOT). Test results in the form of relaxation curves have been mathematically described using a modified generalized Maxwell model. Based on the acquired results, it was shown that the increase of the SBS copolymer content in asphalt binder precipitates the relaxation process, while aging slows down this phenomenon. It has also been proven that with increased content of SBS elastomer in asphalt binder, the effect of short-term aging on binder’s stress relaxation ability at low temperatures is reduced.

TUNING PROPERTIES AND MORPHOLOGY IN HIGH VINYL CONTENT SBS BLOCK COPOLYMER, A THERMOPLASTIC ELASTOMER VIA THIOL-ENE MODIFICATION

2017 ◽  
Vol 90 (3) ◽  
pp. 550-561 ◽  
Author(s):  
Prithwiraj Mandal ◽  
Siva Ponnupandian ◽  
Soumyadip Choudhury ◽  
Nikhil K. Singha
Keyword(s):  
Block Copolymer ◽  
Thermoplastic Elastomer ◽  
Atomic Force Microscopy Analysis ◽  
Ene Reaction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Microscopy Analysis ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

ABSTRACT Thiol-ene modification of high vinyl content thermoplastic elastomeric styrene butadiene styrene (SBS) block copolymer (BCP) was carried out using different thiolating agents in toluene at 70 °C. 1H NMR analysis confirmed the participation of vinyl double bond in the thiol-ene modification reaction of SBS. Surface morphology of the block copolymers evaluated by atomic force microscopy analysis showed higher roughness after the thiol-ene reaction. The thiol-modified SBS block copolymer showed better adhesion strength and oil resistance properties than the pristine SBS.

The modification of bitumen with styrene–butadiene–styrene, ethylene vinyl acetate and varying the amount of reactive ethylene terpolymer

2017 ◽  
Vol 50 (3) ◽  
pp. 241-255 ◽  
Author(s):  
Seyfullah Keyf
Keyword(s):  
Vinyl Acetate ◽  
Softening Point ◽  
Elastic Recovery ◽  
Ethylene Vinyl Acetate ◽  
Modified Bitumen ◽  
Penetration Index ◽  
Different Types ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this article, 50/70 penetration grade TUPRAS bitumen was modified. Reactive elastomeric terpolymer (Elvaloy RET; DuPont Company), ethylene vinyl acetate (EVA) and styrene–butadiene–styrene (SBS) polymers were used in bitumen modification. Set hours of the tests were applied to samples taken from the obtained modified bitumen mixture. Varying amount of reactive ethylene terpolymer with weight ratios of 0.5%, 1.0%, 1.5%, 2.0% and 2.5% were introduced to the mixture of raw bitumen with 1.0% SBS and 1.0% EVA. Penetration, penetration index, softening point, ductility and elastic recovery tests were performed with these modified bitumen and raw bitumen. The samples of raw bitumen and modified bitumens of 2.0% Elvaloy RET, 1.0% SBS and 1.0% EVA were investigated by means of IR spectroscopy. The raw bitumen was modified with SBS, EVA and RET, and it was determined that penetration and ductility values were decreased while penetration index, softening point and elastic recovery were increased. The purpose of this study is to research the improving properties of 50/70 penetration grade–modified bitumen used in highways of Turkey. The most important characteristics (such as softening point, penetration and % elastic recovery) of new polymer-modified bitumen (NPMB) containing 2.5% EVA, 1% RET and 1% SBS were compared with eight different types of polymer-modified bitumens in Turkey (TPMB). NPMB provided all required parameters (softening point, penetration and % elastic recovery) for five different types of TPMBs (TPMB 70-16, TPMB 70-22, TPMB 76-16, TPMB 76-22 and TPMB 82-16).

scholarly journals Evolution of Rheological Behaviors of Styrene-Butadiene-Styrene/Crumb Rubber Composite Modified Bitumen after Different Long-Term Aging Processes

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2345 ◽  
Author(s):  
Yangsheng Ye ◽  
Gang Xu ◽  
Liangwei Lou ◽  
Xianhua Chen ◽  
Degou Cai ◽  
...  
Keyword(s):  
Low Temperature ◽  
High Speed ◽  
Crumb Rubber ◽  
Modified Bitumen ◽  
High Speed Railway ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this study, a new type of composite modified bitumen was developed by blending styrene-butadiene-styrene (SBS) and crumb rubber (CR) with a chemical method to satisfy the durability requirements of waterproofing material in the waterproofing layer of high-speed railway subgrade. A pressure-aging-vessel test for 20, 40 and 80 h were conducted to obtain bitumen samples in different long-term aging conditions. Multiple stress creep recovery (MSCR) tests, linear amplitude scanning tests and bending beam rheometer tests were conducted on three kinds of asphalt binders (SBS modified asphalt, CR modified asphalt and SBS/CR composite modified asphalt) after different long-term aging processes, including high temperature permanent deformation performance, resistance to low temperature thermal and fatigue crack. Meanwhile, aging sensitivities were compared by different rheological indices. Results showed that SBS/CR composite modified asphalt possessed the best properties before and after aging. The elastic property of CR in SBS/CR composite modified asphalt improved the ability to resist low temperature thermal and fatigue cracks at a range of low and middle temperatures. Simultaneously, the copolymer network of SBS and CR significantly improved the elastic response of the asphalt SBS/CR modified asphalt at a range of high temperatures. Furthermore, all test results indicated that the SBS/CR modified asphalt possesses the outstanding ability to anti-aging. SBS/CR is an ideal kind of asphalt to satisfy the demand of 60 years of service life in the subgrade of high speed railway.

Effect of montmorillonite on properties of styrene–butadiene–styrene copolymer modified bitumen

2007 ◽  
Vol 47 (9) ◽  
pp. 1289-1295 ◽  
Author(s):  
Jianying Yu ◽  
Lin Wang ◽  
Xuan Zeng ◽  
Shaopeng Wu ◽  
Bin Li
Keyword(s):  
Modified Bitumen ◽  
Styrene Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene
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