scholarly journals FDM 3D Printing of Polymers Containing Natural Fillers: A Review of their Mechanical Properties

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1094 ◽  
Author(s):  
Valentina Mazzanti ◽  
Lorenzo Malagutti ◽  
Francesco Mollica

As biodegradable thermoplastics are more and more penetrating the market of filaments for fused deposition modeling (FDM) 3D printing, fillers in the form of natural fibers are convenient: They have the clear advantage of reducing cost, yet retaining the filament biodegradability characteristics. In plastics that are processed through standard techniques (e.g., extrusion or injection molding), natural fibers have a mild reinforcing function, improving stiffness and strength, it is thus interesting to evaluate whether the same holds true also in the case of FDM produced components. The results analyzed in this review show that the mechanical properties of the most common materials, i.e., acrylonitrile-butadiene-styrene (ABS) and PLA, do not benefit from biofillers, while other less widely used polymers, such as the polyolefins, are found to become more performant. Much research has been devoted to studying the effect of additive formulation and processing parameters on the mechanical properties of biofilled 3D printed specimens. The results look promising due to the relevant number of articles published in this field in the last few years. This notwithstanding, not all aspects have been explored and more could potentially be obtained through modifications of the usual FDM techniques and the devices that have been used so far.

Author(s):  
Sara M. Damas ◽  
Cameron J. Turner

Abstract Additive manufacturing methods are becoming more prominent in the world of design and manufacturing due to their reduction of material waste versus traditional machining methods such as milling. The technology to 3D print has been around since the 1970’s. In today’s present time, we now can multi-material 3D print, however. even though we have the technology for multi-material 3D printing, standards in this field are severely lacking. Research on multi-material 3D printing and/or the combination of 3D printing filaments combined with nanoparticles is needed. One of the most common methods of 3D printing is fused deposition modeling (FDM). In this research, FDM was used to dope Acrylonitrile Butadiene Styrene (ABS), to introduce conductive properties for strain measurements. The researchers in this paper used N-Methyl-2-Pyrrolidinone (NMP) to bind the selected nanoparticles. In the first experiment the researchers tested the conductivity of the strain gages, while in the next experiment they studied the effect the various nanoparticles had on the stiffness of the 3D printed ABS strain gages. This extensive and detailed study concluded several points. First, nickel nanoparticles consistently yields the least amount of resistance. Second, multiple binder doped nanoparticle layers yield the lowest resistance. Third, NMP, does indeed improve the performance of the nanoparticles. Finally, the research demonstrated that the various nanoparticles used, when bound increased the stiffness of the ABS strain gages.


Author(s):  
Michael A. Luzuriaga ◽  
Danielle R. Berry ◽  
John C. Reagan ◽  
Ronald A. Smaldone ◽  
Jeremiah J. Gassensmith

Biodegradable polymer microneedle (MN) arrays are an emerging class of transdermal drug delivery devices that promise a painless and sanitary alternative to syringes; however, prototyping bespoke needle architectures is expensive and requires production of new master templates. Here, we present a new microfabrication technique for MNs using fused deposition modeling (FDM) 3D printing using polylactic acid, an FDA approved, renewable, biodegradable, thermoplastic material. We show how this natural degradability can be exploited to overcome a key challenge of FDM 3D printing, in particular the low resolution of these printers. We improved the feature size of the printed parts significantly by developing a post fabrication chemical etching protocol, which allowed us to access tip sizes as small as 1 μm. With 3D modeling software, various MN shapes were designed and printed rapidly with custom needle density, length, and shape. Scanning electron microscopy confirmed that our method resulted in needle tip sizes in the range of 1 – 55 µm, which could successfully penetrate and break off into porcine skin. We have also shown that these MNs have comparable mechanical strengths to currently fabricated MNs and we further demonstrated how the swellability of PLA can be exploited to load small molecule drugs and how its degradability in skin can release those small molecules over time.


2021 ◽  
Vol 896 ◽  
pp. 29-37
Author(s):  
Ján Milde ◽  
František Jurina ◽  
Jozef Peterka ◽  
Patrik Dobrovszký ◽  
Jakub Hrbál ◽  
...  

The article focused on the influence of part orientation on the surface roughness of cuboid parts during the process of fabricating by FDM technology. The components, in this case, is simple cuboid part with the dimensions 15 mm x 15mm x 30 mm. A geometrical model is defined that considers the shape of the material filaments after deposition, to define a theoretical roughness profile, for a certain print orientation angle. Five different print orientations in the X-axis of the cuboid part were set: 0°, 30°, 45°, 60°, and 90°. According to previous research in the field of FDM technology by the author, the internal structure (infill) was set at the value of 70%. The method of 3D printing was the Fused Deposition Modeling (FDM) and the material used in this research was thermoplastic ABS (Acrylonitrile butadiene styrene). For each setting, there were five specimens (twenty five prints in total). Prints were fabricated on a Zortrax M200 3D printer. After the 3D printing, the surface “A” was investigated by portable surface roughness tester Mitutoyo SJ-210. Surface roughness in the article is shown in the form of graphs (Fig.7). Results show increase in part roughness with increasing degree of part orientation. When the direction of applied layers on the measured surface was horizontal, significant improvement in surface roughness was observed. Findings in this paper can be taken into consideration when designing parts, as they can contribute in achieving lower surface roughness values.


2021 ◽  
pp. 089270572110530
Author(s):  
Nagarjuna Maguluri ◽  
Gamini Suresh ◽  
K Venkata Rao

Fused deposition modeling (FDM) is a fast-expanding additive manufacturing technique for fabricating various polymer components in engineering and medical applications. The mechanical properties of components printed with the FDM method are influenced by several process parameters. In the current work, the influence of nozzle temperature, infill density, and printing speed on the tensile properties of specimens printed using polylactic acid (PLA) filament was investigated. With an objective to achieve better tensile properties including elastic modulus, tensile strength, and fracture strain; Taguchi L8 array has been used for framing experimental runs, and eight experiments were conducted. The results demonstrate that the nozzle temperature significantly influences the tensile properties of the FDM printed PLA products followed by infill density. The optimum processing parameters were determined for the FDM printed PLA material at a nozzle temperature of 220°C, infill density of 100%, and printing speed of 20 mm/s.


2021 ◽  
Vol 6 (2) ◽  
pp. 119
Author(s):  
Nanang Ali Sutisna ◽  
Rakha Amrillah Fattah

The method of producing items through synchronously depositing material level by level, based on 3D digital models, is named Additive Manufacturing (AM) or 3D-printing. Amongs many AM methods, the Fused Deposition Modeling (FDM) technique along with PLA (Polylactic acid) material is commonly used in additive manufacturing. Until now, the mechanical properties of the AM components could not be calculated or estimated until they've been assembled and checked. In this work, a novel approach is suggested as to how the extrusion process affects the mechanical properties of the printed component to obtain how the parts can be manufactured or printed to achieve improved mechanical properties. This methodology is based on an experimental procedure in which the combination of parameters to achieve an optimal from a manufacturing experiment and its value can be determined, the results obtained show the effect of the extrusion process affects the mechanical properties.


Author(s):  
Shajahan Bin Maidin ◽  
Zulkeflee Abdullah ◽  
Ting Kung Hieng

One of the disadvantages of fused deposition modeling (FDM) is waste produced during the printing processes. This investigation focuses on using 100% recycled Acrylonitrile Butadiene Styrene (ABS) for the FDM process. The recycling begins with re-granule the waste ABS material and produces it into a new filament. The new recycled filament was used to print the test specimen. Investigation on the mechanical properties and the surface quality of the test specimen and comparison with standard ABS specimen was done. The result shows that the recycled ABS can be produced into filament with 335°C of extrusion temperature and 1.5 mm/s travel speed of the extruder conveyor. The surface roughness of recycled specimen is 6.94% higher than the standard ABS specimen. For ultimate tensile strength, there is a small difference in X and Y orientation between the standard and the recycled ABS specimen which are 22.93% and 19.98%, respectively. However, in Z orientation, it is 52.33% lower. This investigation proves that ABS can be recycled without significantly affecting its mechanical properties.


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2416
Author(s):  
Thossapit Wissamitanan ◽  
Charoenyutr Dechwayukul ◽  
Ekwipoo Kalkornsurapranee ◽  
Wiriya Thongruang

Flexible thermoplastic elastomers (TPE) were prepared for fused deposition modeling (FDM) or 3D printing. These materials can be used for medical purposes such as disposable soft splints and other flexible devices. Blends of 50% epoxidized natural rubber (ENR-50) and block rubber (Standard Thai Rubber 5L (STR5L)) with polycaprolactone (PCL) were produced and compared. The purpose of this study was to investigate the properties of natural rubber (NR) and PCL in simple blends with PCL contents of 40%, 50%, and 60% by weight (except at 75% for morphology study) in the base mixture (NR/PCL). The significant flow factors for FDM materials, such as melting temperature (Tm) and melt flow rate (MFR), were observed by differential scanning calorimetry (DSC) and via the melt flow index (MFI). In addition, the following mechanical properties were also determined: tensile strength, compression set, and hardness. The results from DSC showed that the melting temperature changed slightly (1–2 °C) with amount of PCL used, and there was a suspicious point in the 50/50 blends with both types of rubber. The lowest melting enthalpy of both blends was found at the 50/50 blended composition. The MFI results showed that PCL significantly affected the melt flow rate of both blends. The ENR-50/PCL blend flowed better than the STR5L/PCL blend. The conclusion was that this was due to the morphology of its phase structure having better uniformity than that of the STR5L/PCL blend. In compression set testing or measuring shape recovery, rubber directly influenced the recovery in all blends. The ENR-50/PCL blend had less recovery than the STR5L/PCL blend, probably due to the functional effects of epoxide groups and polarity mismatch. The hard phase PCL significantly affected the hardness of samples but improved shape recovery of the material. The ENR-50/PCL blend had better tensile properties than the STR5L/PCL blend. The elongation at break of both blends improved with a high rubber content. Hence, the ENR-50/PCL blend was superior to STR5L/PCL for printing purposes due to its better miscibility, uniformity, and flow, which are the keys to success for optimizing the fused deposition modeling conditions as well as the overall mechanical properties of products. Most blends in this study were only slightly different, but the 50/50 blend of ENR-50/PCL seemed to be near optimal for 3D printing.


Author(s):  
Tran Linh Khuong ◽  
Zhao Gang ◽  
Muhammad Farid ◽  
Rao Yu ◽  
Zhuang Zhi Sun ◽  
...  

Biomimetic robots borrow their structure, senses and behavior from animals, such as humans or insects, and plants. Biomimetic design is design ofa machine, a robot or a system in engineeringdomain thatmimics operational and/orbehavioral model of a biological system in nature. 3D printing technology has another name as rapid prototyping technology. Currently it is being developed fastly and widely and is applied in many fields like the jewelry, footwear, industrial design, architecture, engineering and construction, automotive, aerospace, dental and medical industry, education, geographic information system, civil engineering, guns. 3D printing technology is able to manufacture complicated, sophisticated details that the traditional processing method cannot manufacture. Therefore, 3D printing technology can be seen as an effective tool in biomimetic, which can accurately simulate most of the biological structure. Fused Deposition Modeling (FDM) is a technology of the typical rapid prototyping. The main content of the article is the focusing on tensile strength test of the ABS-Acrylonitrile Butadiene Styrene material after using Fused Deposition Modeling (FDM) technology, concretization after it’s printed by UP2! 3D printer. The article focuses on two basic features which are Tensile Strength and Determination of flexural properties.


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