scholarly journals Enhancing Anti-Static Performance of Fibers by Construction of the Hybrid Conductive Network Structure on the Fiber Surface

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2248
Author(s):  
Congcong Xu ◽  
Lin Fang ◽  
Mingming Yu ◽  
Musu Ren ◽  
Jinliang Sun ◽  
...  
Keyword(s):  
Sulfonic Acid ◽  
Chemical Structure ◽  
Fiber Surface ◽  
Conductive Network ◽  
Simple Method ◽  
Structure And Morphology ◽  
Static Performance ◽  
Treated Fiber ◽  
Sulfonic Acid Groups ◽  
Addition Amount

The hybrid antistatic agent SCNTs/OAA composed of sulfonated carbon nanotubes (SCNTs) and organic antistatic agent (OAA) was treated on the fiber surface to construct the hybrid conductive layer. Among them, SCNTs were synthesized through a simple method, and their chemical structure and morphology were characterized. SCNTs had good dispersibility due to the presence of sulfonic acid groups, which made SCNTs uniformly dispersed on the fiber surface. The SCNTs/OAA-treated fiber was hardly affected by relative humidity, because SCNTs form a continuous and uniform physical conductive network on the fiber surface. When the addition amount of SCNTs/OAA was 0.5~2 wt%, the fiber had excellent antistatic ability. Under the synergistic effect of SCNTs and OAA, the resistivity of SCNTs/OAA-treated fiber was almost not affected by fiber stretching.

Synthesis and Characterization of Quaternary Ammonium Polyether Blocked Polysiloxane

2013 ◽  
Vol 631-632 ◽  
pp. 562-567
Author(s):  
Qiu Feng An ◽  
Bo Xiao ◽  
Xia Meng Xv ◽  
Li Fen Hao
Keyword(s):  
Quaternary Ammonium ◽  
Chemical Structure ◽  
Fiber Surface ◽  
Synthesis And Characterization ◽  
Bending Rigidity ◽  
H Nmr ◽  
Film Forming ◽  
Treated Fiber ◽  
Scanning Electron

In this research, a new quaternary ammonium polyether blocked polysiloxane (QBPEAS) was synthesized by reaction of epoxy polyether terminated polydimethylsiloxane with tetramethylethylenediamine. The chemical structure of QBPEAS was characterized by IR and 1H-NMR. And then the film morphology on fiber substrates was investigated by scanning electron microscope (SEM). The results showed that QBPEAS has a good film-forming ability and can form a macro-smooth Sloane film on the treated fiber surface. In addition, QBPEAS could obviously decrease the bending rigidity and improve the hydrophilicity of the treated fabrics, but has little influence on the fabric whiteness.

scholarly journals Methoxylation of α-pinene over poly(vinyl alcohol) containing sulfonic acid groups

2009 ◽  
Vol 147 (2-3) ◽  
pp. 302-306 ◽  
Author(s):  
D.S. Pito ◽  
I.M. Fonseca ◽  
A.M. Ramos ◽  
J. Vital ◽  
J.E. Castanheiro
Keyword(s):  
Vinyl Alcohol ◽  
Sulfonic Acid ◽  
Poly Vinyl Alcohol ◽  
Sulfonic Acid Groups

Superprotonic Conductivity of a UiO-66 Framework Functionalized with Sulfonic Acid Groups by Facile Postsynthetic Oxidation

2015 ◽  
Vol 127 (17) ◽  
pp. 5231-5235 ◽  
Author(s):  
Won Ju Phang ◽  
Hyuna Jo ◽  
Woo Ram Lee ◽  
Jeong Hwa Song ◽  
Kicheon Yoo ◽  
...  
Keyword(s):  
Sulfonic Acid ◽  
Sulfonic Acid Groups

Do acid–base interactions really improve the ion conduction in a proton exchange membrane? – a study on the effect of basic groups

2019 ◽  
Vol 7 (34) ◽  
pp. 19820-19830 ◽  
Author(s):  
Yuqian Sui ◽  
Yexin Du ◽  
Huayuan Hu ◽  
Jieshu Qian ◽  
Xuan Zhang
Keyword(s):  
Physicochemical Properties ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Acid Base ◽  
Ion Conduction ◽  
Exchange Membrane ◽  
Sulfonic Acid Groups

Generating acid–base interactions between sulfonic acid groups in a proton exchange membrane (PEM) and the incorporation of basic groups are effective approaches to improving the physicochemical properties of a membrane.

Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups

2008 ◽  
Vol 44 (2) ◽  
pp. 475-482 ◽  
Author(s):  
Yi Zheng ◽  
Li Pan ◽  
Yan-Guo Li ◽  
Yue-Sheng Li
Keyword(s):  
Sulfonic Acid ◽  
Sulfonic Acid Groups

Synthesis of soluble sulfonated polybenzimidazoles derived from 2-sulfonate terephthalic acid

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Qunying Wu ◽  
Guyu Xiao ◽  
Deyue Yan
Keyword(s):  
Terephthalic Acid ◽  
Sulfonic Acid ◽  
Strong Acid ◽  
High Thermal Stability ◽  
Swelling Ratio ◽  
Solution Casting ◽  
Direct Polycondensation ◽  
Acid Base ◽  
Resistance To Oxidation ◽  
Sulfonic Acid Groups

Abstract2-Sulfonate p-terephthalic acid (sTA) was synthesized, and sulfonated polybenzimidazoles (sPBI) were prepared by direct polycondensation of 3,3’- diaminobenzidine (DAB) and sTA with 4,4’-oxybis(benzoic acid) (OBBA) or 2,2’- bis(4-carboxylphenyl)-hexafluoropropane (BCHFP). Thus the ether groups and hexafluoroisopropylidene units were incorporated into the backbone of the sPBI in order to improve the flexibility and solubility. The sPBI based on OBBA showed poor solubility, while the sPBI containing hexafluoroisopropylidene units were soluble in common solvents. sPBI-20 ~ sPBI-60 could form tough and transparent membranes by solution casting. sPBI indicated high thermal stability, the 5% weight loss temperature (T5%) which was higher than 520°C, decreased with the increase of degree of sulfonation. sPBI-20 ~ sPBI-60 showed no glass transition at temperatures lower than 380°C. In addition, sPBI showed low water uptake, low swelling ratio as well as excellent resistance to oxidation. But sPBI exhibited low proton conductivity because of the strong acid-base interactions between basic benzimidazole and sulfonic acid groups.

A Simple Method for the Characteristic Differentiation of Antibiotics by TLC-Bioautography in Graded Concentration of Ammonium Chloride

1988 ◽  
Vol 51 (10) ◽  
pp. 786-789 ◽  
Author(s):  
FUSAO KONDO
Keyword(s):  
Laboratory Test ◽  
Ammonium Chloride ◽  
Chloride Solution ◽  
Chemical Structure ◽  
Characteristic Change ◽  
Routine Laboratory ◽  
Simple Method ◽  
Tetracycline Antibiotics ◽  
Tlc Bioautography ◽  
Rf Values

A simple classification method for 24 known antibiotics by TLC-bioautographic procedure was developed. The approach used was to change the Rf values in seven TLC systems with an ammonium chloride solution in a graded concentration range (0.5, 1, 2, 3, 5, 10 and 20%). The antibiotics were divided into four groups (A to D) showing the characteristic behavior of Rf values corresponding to similarities in chemical structure: β-lactam, aminoglycoside, macrolide and tetracycline antibiotics. TLC-bioautography helps to estimate the character of antibiotics and the characteristic change of Rf values may be very useful for classifying unknown residual antibiotics in animal samples as a routine laboratory test.

Surface Treatment of PMIA Fibers with Sub-Atmospheric Pressure Dielectric Barrier Glow Discharge Plasma

2014 ◽  
Vol 1048 ◽  
pp. 72-76
Author(s):  
Huan Da Zheng ◽  
Juan Zhang ◽  
Bing Du ◽  
Qu Fu Wei ◽  
Lai Jiu Zheng
Keyword(s):  
Glow Discharge ◽  
Atmospheric Pressure ◽  
Chemical Structure ◽  
Surface Characterization ◽  
Discharge Plasma ◽  
Treatment Time ◽  
Fiber Surface ◽  
Glow Discharge Plasma ◽  
Dielectric Barrier ◽  
Ft Ir

Meta-aramid fibers were treated by sub-atmospheric pressure dielectric barrier glow discharge plasma. The effect of plasma treatment time on the fiber surface physical and chemical properties was studied by using surface characterization techniques. Scanning electron microscopy (SEM) was performed to determine the surface morphology changes. FT-IR spectroscopy measurements were performed to investigate the change of chemical structure. Dynamic contact angle analysis (DCAA) was used to examine the changes of the fiber surface wettability. SEM analysis showed that there was obvious crack along the fibers’ axial direction present on the fiber surface, which resulted in the better wetting behavior of the plasma-treated PMIA fiber. FT-IR analysis showed that plasma had little effect on the chemical structure of PMIA fibers. DCAA analysis showed that the wettability of the samples could be improved with the treatment time increasing. In addition, a slight decrease in breaking strength was observed at the treatment time ranging from 60 to 180 s in comparison with the untreated sample.

Sign in / Sign up

Export Citation Format

Share Document