scholarly journals Characterization of Alkanolamine Blends for Carbon Dioxide Absorption. Corrosion and Regeneration Studies

2021 ◽  
Vol 13 (7) ◽  
pp. 4011
Author(s):  
Alfredo Sánchez-Bautista ◽  
Ester M. Palmero ◽  
Alberto J. Moya ◽  
Diego Gómez-Díaz ◽  
M. Dolores La Rubia

There are a lot of research programs focusing on the development of new solvents for carbon dioxide capture. The most important priority should be reducing the energy consumption needed at the regeneration step, but minimizing solvent degradation and its corrosivity is also considered as a priority. In this research, the aqueous blends of 2-amino-2-methyl-1-propanol (AMP: 1 kmol·m−3) and 1-amino-2-propanol (MIPA: 0.1–0.5 kmol·m−3) are characterized in terms of density, viscosity, and surface tension. The carbon dioxide absorption rate and capacity, the regeneration capacity, and the corrosivity of these solvents are also evaluated.

2019 ◽  
Vol 801 ◽  
pp. 179-184
Author(s):  
John Andrew Kane P. Jovellana ◽  
B. Pajarito

Increasing carbon dioxide (CO2) levels in the atmosphere caused by excessive greenhouse gas emissions is strongly associated to global warming and climate change. This study aims to prove the feasibility of using pectin as the backbone for amine functionalization with application as coating on zeolites for carbon dioxide capture. Characterization of the solutions using FTIR and of the adsorbents using SEM demonstrated the successful modification of pectin using NH3 and TETA as alternative amine-functionalized coating for adsorbent. It has been reported for the first time that the polysaccharide pectin can be aminated and modified for CO2 capture upon coated on substrates such as zeolites. The adsorption capacities at 5% breakthrough of the adsorbents coated with the modified pectin are 2.24 mmol/CO2 g adsorbent and 2.28 mmol/CO2 g adsorbent, when coated with NH3-modified and TETA-modified pectin, respectively. It is recommended for further study to synthesize substrates with higher surface area, and optimize the formulations of the pectin modification.


2013 ◽  
Vol 34 (14) ◽  
pp. 1181-1185 ◽  
Author(s):  
Xianghui Chen ◽  
Shanlin Qiao ◽  
Zhengkun Du ◽  
Yuanhang Zhou ◽  
Renqiang Yang

2007 ◽  
Vol 62 (23) ◽  
pp. 6534-6547 ◽  
Author(s):  
A.F. Portugal ◽  
P.W.J. Derks ◽  
G.F. Versteeg ◽  
F.D. Magalhães ◽  
A. Mendes

2016 ◽  
Vol 14 (1) ◽  
pp. 533-537 ◽  
Author(s):  
Diego Gómez-Díaz

AbstractPresent work analyses the regeneration of aqueous solutions of glucosamine employed in carbon dioxide capture by gas–liquid absorption by using new methodologies. The aim of the development of these methods is to avoid the aggressiveness shown by the most common one: stripping (e.g. corrosion or degradation). This latest produces an important amine loss and also involves a high energetic cost. This research work has checked the behavior of two new regeneration processes when a thermolabile amine is employed in the chemical solvent for carbon dioxide absorption. These methods are based on the removal of bicarbonate ion and amine deprotonation showing suitable results in comparison with thermal treatment.


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