scholarly journals Electrochemical Performances of the Sn-Cu Alloy Negative Electrode Materials through Simple Chemical Reduction Method

Author(s):  
Ji Seon Oh ◽  
Duri Kim ◽  
Seung Ho Chae ◽  
Seungjoo Oh ◽  
Seong Tae Yoo ◽  
...  
2011 ◽  
Vol 86 (1) ◽  
pp. 87-92 ◽  
Author(s):  
Zaheer Khan ◽  
Javed Ijaz Hussain ◽  
Sunil Kumar ◽  
Athar Adil Hashmi

NANO ◽  
2013 ◽  
Vol 08 (03) ◽  
pp. 1350030 ◽  
Author(s):  
ERIC FRIBOURG-BLANC ◽  
DUNG THI MY DANG ◽  
TUYET THI THU LE ◽  
CHINH DUNG TRINH ◽  
THANH THI NU THANH ◽  
...  

This paper discusses the function of hydrogen peroxide and trisodium citrate (TSC) in the synthesis of silver ( Ag ) nanoplates through a simple chemical reduction method in ambient conditions. By this method, high purity Ag nanoplates were successfully generated (up to 100%). It was found that the amounts of hydrogen peroxide and TSC added to the solution are key to controlling the shape of Ag nanoparticles from spherical nanoparticles to hexagonal nanoplates and triangular nanoplates, depending on the Ag -to-hydrogen peroxide ratio and the Ag -to-TSC ratio used. This unique shape evolution process was carefully followed by a combination of ultraviolet-visible (UV-Vis) spectroscopy and transmission electron microscopy (TEM). The mean edge length of the triangular nanoplates varies from 65 nm to 100 nm. Polyvinyl pyrrolidone (PVP) is shown to increase the in-plane dimensions of the nanoplates as its relative concentration to Ag increases.


RSC Advances ◽  
2015 ◽  
Vol 5 (71) ◽  
pp. 57804-57814 ◽  
Author(s):  
M. Ranjani ◽  
Y. Sathishkumar ◽  
Yang Soo Lee ◽  
Dong Jin Yoo ◽  
Ae Rhan Kim ◽  
...  

Uniform sized Ni–Co alloy nanoparticles were effectively confined over the active channels of mesoporous silica nanoparticles (MSN) using a simple chemical reduction method, and the resultant nanostructures exhibited a spherical configuration with a mean diameter of 5 nm.


2017 ◽  
Vol 727 ◽  
pp. 751-755 ◽  
Author(s):  
Wei Zhao ◽  
Yi Lin Liao ◽  
Jian Ling Huang ◽  
Hai Liang Chu ◽  
Shu Jun Qiu ◽  
...  

In order to enhance the electrochemical properties of Co-B alloys used as negative electrode materials of alkaline rechargeable batteries, Co-B alloy was successfully prepared by a chemical reduction method with the assistance of the sonication. The phase structure and the surface morphology of the as-prepared Co-B alloys were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen physisorption. Moreover, the electrochemical performance was characterized by galvonostatic charge-discharge tests, electrochemical impedance spectroscopy (EIS) and anodic polarization (AP). Co-B alloy prepared with the assistance of the sonication consists of small particles with a uniform distribution. The electrochemical measurements showed that at a discharge current density of 100 mA/g, the initial discharge capacity was 858.1 mAh/g and the discharge capacity was 322.6 mA/g even at the 100th cycle with the capacity retention of 37.6%.


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Latif-ur-Rahman ◽  
Afzal Shah ◽  
Rumana Qureshi ◽  
Sher Bahadar Khan ◽  
Abdullah M. Asiri ◽  
...  

Au-Cu alloy nanoparticles were synthesized by a chemical reduction method. Five samples having different compositions of Au and Cu (Au-Cu 3 : 1, Au-Cu 2 : 1, Au-Cu 1 : 1, Au-Cu 1 : 2, and Au-Cu 1 : 3) were prepared. The newly synthesized nanoparticles were characterized by electronic absorption, fluorescence, and X-ray diffraction spectroscopy (XRD). These alloy nanoparticles were also analyzed by SEM and TEM. The particle size was determined by SEM and TEM and calculated by Debye Scherrer’s equation as well. The results revealed that the average diameter of nanoparticles gets lowered from 80 to 65 nm as the amount of Cu is increased in alloy nanoparticles. Some physical properties were found to change with change in molar composition of Au and Cu. Most of the properties showed optimum values for Au-Cu alloy nanoparticles of 1 : 3. Cu in Au-Cu alloy caused decrease in the intensity of the emission peak and acted as a quencher. The fluorescence data was utilized for the evaluation of number of binding sites, total number of atoms in alloy nanoparticle, binding constant, and free energy of binding while morphology was deduced from SEM and TEM.


2013 ◽  
Vol 328 ◽  
pp. 729-733
Author(s):  
Kun Xiang ◽  
Mei Juan Li ◽  
Dao Ren Gong ◽  
Qiang Guo Luo ◽  
Qiang Shen

Three-dimensional (3D) flowerlike CuO structures were prepared successfully by reducing copper chloride (CuCl2·2H2O) aqueous solution in the presence of cetyltrimethylammonium bromide (CTAB). The as-prepared CuO structures were characterized by UV-Vis, X-ray powder diffraction (XRD), FESEM and EDS techniques. The flowerlike CuO structures consisted of Salix leaf-like nanostructures. A possible growth mechanism for the formation of 3D flowerlike CuO structure was proposed. The processes of ripening and directed growing of nanoparticles were most important factors to obtain the 3D flowerlike CuO structures.


2017 ◽  
Vol 4 (3) ◽  
pp. 565-576 ◽  
Author(s):  
Rama Shanker Sahu ◽  
Kartick Bindumadhavan ◽  
Ruey-an Doong

In this study, a simple chemical reduction method for the synthesis of novel and efficient graphene-based bimetallic Fe/Ni nanoparticles was developed for the rapid and effective dechlorination of trichloroethylene (TCE).


Author(s):  
Umadevi M ◽  
Rani T ◽  
Balakrishnan T ◽  
Ramanibai R

Nanotechnology has great promise for improving the therapeutic potential of medicinal molecules and related agents. In this study, silver nanoparticles of different sizes were synthesized in an ultrasonic field using the chemical reduction method with sodium borohydride as a reducing agent. The size effect of silver nanoparticles on antimicrobial activity were tested against the microorganisms Staphylococcus aureus (MTCC No. 96), Bacillus subtilis (MTCC No. 441), Streptococcus mutans (MTCC No. 497), Escherichia coli (MTCC No. 739) and Pseudomonas aeruginosa (MTCC No. 1934). The results shows that B. subtilis, and E. coli were more sensitive to silver nanoparticles and its size, indicating the superior antimicrobial efficacy of silver nanoparticles. 


Electrochem ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 236-250
Author(s):  
Arjun Prasad Tiwari ◽  
Tanka Mukhiya ◽  
Alagan Muthurasu ◽  
Kisan Chhetri ◽  
Minju Lee ◽  
...  

The development of smart negative electrode materials with high capacitance for the uses in supercapacitors remains challenging. Although several types of electrode materials with high capacitance in energy storage have been reported, carbon-based materials are the most reliable electrodes due to their high conductivity, high power density, and excellent stability. The most common complaint about general carbon materials is that these electrode materials can hardly ever be used as free-standing electrodes. Free-standing carbon-based electrodes are in high demand and are a passionate topic of energy storage research. Electrospun nanofibers are a potential candidate to fill this gap. However, the as-spun carbon nanofibers (ECNFs) have low capacitance and low energy density on their own. To overcome the limitations of pure CNFs, increasing surface area, heteroatom doping and metal doping have been chosen. In this review, we introduce the negative electrode materials that have been developed so far. Moreover, this review focuses on the advances of electrospun nanofiber-based negative electrode materials and their limitations. We put forth a future perspective on how these limitations can be overcome to meet the demands of next-generation smart devices.


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