scholarly journals Origin and Maturity of Biomarker Aliphatic Hydrocarbon in Wondama Coal Indonesia

2020 ◽  
Vol 3 (2) ◽  
pp. 107
Author(s):  
Yulfi Zetra ◽  
R Y Perry Burhan ◽  
Arga D. Pratama ◽  
Agus Wahyudi
Keyword(s):  
Depositional Environment ◽  
Bituminous Coal ◽  
Higher Plants ◽  
Aliphatic Hydrocarbon ◽  
Carbon Preference Index ◽  
Hydrocarbon Biomarkers ◽  
Preference Index ◽  
R Ratio ◽  
Gas Chromatography Mass Spectroscopy

Organic geochemical characterization of Wondama coal samples from the Lengguru Folding Belt has been carried out through the study of its aliphatic hydrocarbon biomarkers. This study is to determine the origin, depositional environment and maturity of coal which is useful for determining the use of coal as an energy source. Aliphatic hydrocarbon biomarkers were identified by using gas chromatography-mass spectroscopy methods which showed the presence of n-alkane homologs (n-C15 - n-C33), which was dominated by n-C31. This indicates that the organic material originates from Angiosperms of terrestrial higher plants. The ratio of pristane to phytane (Pr/Ph) with value of 3.74 indicates that the Wondama coal is buried in an oxic depositional environment. The Carbon Preference Index (CPI) value of 7.82 and the C31αβS/(S + R) ratio of 0.27 indicate low maturity of Wondama coal and is classified into a sub-bituminous coal ranks.

scholarly journals Aliphatic hydrocarbon biomarkers of Sekar Kurung Gresik crude oil

2019 ◽  
Vol 15 (3) ◽  
pp. 426-431
Author(s):  
Dyah Nirmala ◽  
R.Y.Perry Burhan ◽  
Suprapto Suprapto ◽  
Yulfi Zetra
Keyword(s):  
Gas Chromatography ◽  
Crude Oil ◽  
Mass Spectrometer ◽  
Depositional Environment ◽  
Higher Plants ◽  
Aliphatic Hydrocarbon ◽  
Bacterial Activity ◽  
Organic Composition ◽  
Hydrocarbon Biomarkers

Characterization of petroleum biomarker from Sekar Kurung Gresik, was carried out to investigate its organic composition, depositional environment and oil maturity. The oil sample was extracted and fractionated using column chromatography to derive aliphatic hydrocarbon fraction.  The aliphatic hydrocarbon compounds were analyzed using gas chromatography-mass spectrometer (GC-MS). The GC-MS analysis shows that n-alkanes compound (C14-C28), isoprenoid alkanes (iC15 iC16 and iC18-iC20), a bicyclic sesquiterpene, eudesmane, cadinane, hopane, bicadinane, gammacerane and diasterane were observed. The identified compounds show that the crude oil compounds were derived from terrestrial higher plants, the contribution of bacterial activity and the oxic deposition environment (Pr/Ph = 5.3 (<1)). The oil analyzed is a mature oil. 

scholarly journals PALEOENVIRONMENTAL AND MATURITY INDICATOR OF CEPU BLOCK OIL, WONOCOLO FORMATION, EAST JAVA-INDONESIA

2020 ◽  
Vol 82 (5) ◽  
Author(s):  
R. Y. Perry Burhan ◽  
Yulfi Zetra ◽  
Yuanita Aisyah Amini
Keyword(s):  
Gas Chromatography ◽  
Organic Compound ◽  
Aromatic Hydrocarbon ◽  
Depositional Environment ◽  
Higher Plants ◽  
Terrestrial Environment ◽  
Hydrocarbon Biomarkers ◽  
High Maturity ◽  
Gas Chromatography Mass Spectroscopy ◽  
Aromatic Heterocyclic

Biomarkers identification of aromatic hydrocarbon fraction of Cepu oil samples was carried out to determine the ancient depositional environment, the source of origin and indicators of the maturity of the old well of the Cepu Block oil, Wonocolo Formation, East Java Indonesia. Biomarkers was identified through the Gas Chromatography-Mass Spectroscopy (GC-MS) method. The distribution of aromatic hydrocarbon biomarkers indicates the presence of naphthalene compounds and their derivatives, sesquiterpenoids, diterpenoids and heterocyclic aromatic groups. The presence of identified biomarkers indicates the source of the oil organic compound coming from higher plants Angiosperms. The presence of methyl phenanthrene and aromatic heterocyclic biomarkers such as dibenzothiophene and dibenzofuran , as well as fluorene shows that Cepu Block oil was deposited not only in the terrestrial environment, but also lacustrine and marin under oxidic precipitation conditions. The presence of methyl phenanthrene with MPI value of 0.86 and isocadalene abundance higher than cadalene indicates moderate to high maturity of the Cepu Block oil analyzed. Keywords: Cepu Block oil, aromatic hydrocarbon, biomarker, paleoenvironment, GC-MS analysis.

Holocene vegetation signals in the Alashan Desert of northwest China revealed by lipid molecular proxies from calcareous root tubes

2017 ◽  
Vol 88 (1) ◽  
pp. 60-70 ◽  
Author(s):  
Zhuolun Li ◽  
Youhong Gao ◽  
Lang Han
Keyword(s):  
Higher Plants ◽  
Relative Concentration ◽  
Northwest China ◽  
Pollen Concentration ◽  
Carbon Preference Index ◽  
Effective Moisture ◽  
Preference Index ◽  
Desert Regions ◽  
Root Tube ◽  
Long Chain

AbstractIn the hinterland of deserts, it is difficult to reconstruct paleovegetation using fossil pollen because of the low pollen concentration. Therefore, an efficient method is needed to reconstruct the paleovegetation of desert regions. In this study, 34 Holocene calcareous root tube (CRT) samples were collected from the Alashan Desert in northwest China, and lipid molecular proxies from CRTs were selected to address this deficiency. The results show that n-alkanes mainly maximized at C27, C29, and C16, and that the carbon preference index is close to 1. Thus, the sources of n-alkanes from CRTs were the roots of higher plants and microorganisms, and thus changes in n-alkanes from CRTs could reveal variations in vegetation cover. The n-alkane Cmax of long-chain n-alkanes (C>25) in CRTs, maximizing at C27, indicated that vegetation in the Alashan Desert was characterized by shrub vegetation during the Holocene. Changes in the ratio of (C27+C29)/(C31+C33) indicated that the biomass of shrub vegetation increased during the period 7–2 cal ka BP. Moreover, the relative concentration of short-chain to long-chain n-alkanes decreased from 7 to 2 cal ka BP, suggesting that the effective moisture decreased during that period.

scholarly journals Syngenetic rapid growth of ellipsoidal silica concretions with bitumen cores

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hidekazu Yoshida ◽  
Ryusei Kuma ◽  
Hitoshi Hasegawa ◽  
Nagayoshi Katsuta ◽  
Sin-iti Sirono ◽  
...  
Keyword(s):  
Organic Matter ◽  
Early Diagenesis ◽  
Ph Change ◽  
Carbon Preference Index ◽  
Diffusion Growth ◽  
Silica Precipitation ◽  
Precipitated Silica ◽  
Preference Index ◽  
Decomposition Of Organic Matter ◽  
Growth Diagram

AbstractIsolated silica concretions in calcareous sediments have unique shapes and distinct sharp boundaries and are considered to form by diagenesis of biogenic siliceous grains. However, the details and rates of syngenetic formation of these spherical concretions are still not fully clear. Here we present a model for concretion growth by diffusion, with chemical buffering involving decomposition of organic matter leading to a pH change in the pore-water and preservation of residual bitumen cores in the concretions. The model is compatible with some pervasive silica precipitation. Based on the observed elemental distributions, C, N, S, bulk carbon isotope and carbon preference index (CPI) measurements of the silica-enriched concretions, bitumen cores and surrounding calcareous rocks, the rate of diffusive concretion growth during early diagenesis is shown using a diffusion-growth diagram. This approach reveals that ellipsoidal SiO2 concretions with a diameter of a few cm formed rapidly and the precipitated silica preserved the bitumen cores. Our work provides a generalized chemical buffering model involving organic matter that can explain the rapid syngenetic growth of other types of silica accumulation in calcareous sediments.

scholarly journals Characterization of Volatile Compounds and Flavor in Spirits of Old Apple and Pear Cultivars from the Balkan Region

Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1258
Author(s):  
Nermina Spaho ◽  
Fuad Gaši ◽  
Erich Leitner ◽  
Milenko Blesić ◽  
Asima Akagić ◽  
...  
Keyword(s):  
Volatile Compounds ◽  
Solid Phase ◽  
Sensory Attributes ◽  
Apple Cultivar ◽  
Brand Development ◽  
Balkan Region ◽  
Apple Cultivars ◽  
Gas Chromatography Mass Spectroscopy ◽  
Fruit Spirits

This study was conducted with the aim of developing fruit spirits by utilizing old (autochthonous) apple and pear cultivars that can be attractive to both consumers and producers. Consumers of spirits could enjoy the unique flavor, and producers could gain an opportunity for brand development. In total, eight old apple cultivars (Sarija, Žuja, Samoniklica, Prijedorska zelenika, Bobovec, Masnjača, Lijepocvjetka, and Šarenika) and three pear cultivars (Budaljača, Krakača, and Kalićanka) from Bosnia and Herzegovina were used for the spirits production and for characterizing the flavor of distillates. Golden Delicious was used as a representative of commercial apple cultivar. The aroma profile was conducted through the identification of minor volatile organic compounds (VOCs) and the sensory perception of spirits. Analysis of the VOCs was performed by gas chromatography mass spectroscopy (GC/MS) techniques after enrichment via solid-phase microextraction (SPME). Sensory evaluation was performed by 12 trained panelists. Overall, 35 minor volatile compounds were found in spirits: 13 esters, 7 alcohols, 6 acids, 5 terpenes, and 4 aldehydes. Significant differences were detected in the distribution and quantity of the VOCs, which were fruit cultivar-dependent. Spirits made from Šarenika apple cultivar showed the largest amount of all acids, especially short- and medium-chain fatty acids; however, this richness was not correlated with pleasant sensory attributes. Spirits obtained from Prijedorska zelenika and Masnjača apple cultivars had the best sensory attributes. Budeljača and Krakača pears are promising cultivars as flavoring in spirits production.

CHARACTERIZATION OF LIQUEFACTION RESISTANCE OF SAND: EFFECT OF INITIAL FABRIC

2014 ◽  
Vol 08 (01) ◽  
pp. 1450001 ◽  
Author(s):  
BO LI ◽  
XIANGWU ZENG ◽  
HAO YU
Keyword(s):  
Depositional Environment ◽  
Design Method ◽  
Free Field ◽  
Recent Experience ◽  
Permeability Test ◽  
Fabric Anisotropy ◽  
Liquefaction Resistance ◽  
Liquefaction Potential ◽  
Centrifuge Tests

The micro-fabric of deposition reflects the imprints of its geologic and stress history, its depositional environment, and its weathering history. Recent experience shows that the fabric anisotropy does influence the static and dynamic behavior of granular materials. In this study, a series of centrifuge tests are conducted to investigate the effects of fabric anisotropy on the dynamic response in the free field. The results show the acceleration, pore pressure, and residual settlement is significantly affected by the fabric anisotropy of the ground, which shows the liquefaction resistance of the ground. Meanwhile, the response of acceleration is analyzed in frequency domain, which shows that the model prepared by 90° absorbs more energy than that of 0°. To verify the effects induced by the initial fabric, permeability test are conducted and related to the liquefaction potential. The results indicate the fabric anisotropy should be incorporated into the design method.

Sign in / Sign up

Export Citation Format

Share Document