scholarly journals ANALISIS PENGARUH LAJU PUTAR TERHADAP KOROSI BAJA KARBON API 5LX65 MENGGUNAKAN METODE ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY

2012 ◽  
Vol 2 (1) ◽  
pp. 1
Author(s):  
Agus Solehudin ◽  
Asep Lukman
Keyword(s):  
Electron Microscope ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Scanning Electron Microscope ◽  
Energy Dispersive Spectroscopy ◽  
Electrochemical Impedance ◽  
Energy Dispersive ◽  
X Ray ◽  
Scanning Electron

Pada percobaan ini, telah dipelajari pengaruh laju putar terhadap laju korosi baja karbon API 5LX65 yang direndam selama 24 jam dalam larutan NaCl 3,5% + 500 mg/L H2S menggunakan metode EIS (Electrochemical Impedance Spectroscopy) pada suhu 50oC dan pH 4 dengan variasi laju putar 50 rpm, 150 rpm, dan 250 rpm. Hasil percobaan memperlihatkan pergeseran dan penyempitan kurva setengah lingkaran impedansi imaginer terhadap impedansi real, dengan meningkatnya laju putar dari 50 rpm sampai dengan 250 rpm. Hal ini mengindikasikan bahwa aktifitas pelarutan baja meningkat dengan percepatan laju putar. Nilai Cdl meningkat dengan meningkatnya laju putar. Nilai tahanan polarisasi (Rp) semakin menurun dengan meningkatnya laju putar, sementara nilai tahanan larutan (Rs) relatif tidak berubah. Potensial korosi pada laju putar 50 rpm, 150 rpm dan 250 rpm stabil  pada -517 mV hingga -508 mV terhadap Ag/AgCl. Gabungan pengamatan Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) dan X-Ray Diffractomer (XRD) menunjukkan terbentuknya lapisan produk korosi. Hasil analisis XRD spesimen uji yang dikorosikan pada suhu 50oC selama 24 jam menunjukkan bahwa lapisan produk korosi mengandung besi sulfida (FeS). Morfologi permukaan spesimen ini memperlihatkan adanya korosi sumuran.Kata kunci: laju putar, korosi, baja karbon, EIS, H2S

Epoxy Resin Modified with PEDOT/PSS and Corrosion Protection of Steel

2012 ◽  
Vol 560-561 ◽  
pp. 947-951
Author(s):  
Jian Hou ◽  
Guang Zhu ◽  
Jing Kun Xu ◽  
Jun Tao Wang ◽  
Yao Huang
Keyword(s):  
Electron Microscope ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Scanning Electron Microscope ◽  
Epoxy Resin ◽  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Protection Efficiency ◽  
Epoxy Paint ◽  
Scanning Electron

An epoxy paint containing PEDOT/PSS was described herein. The corrosion behavior of steel samples coated with the paint was investigated in seawater. For this purpose, electrochemical impedance spectroscopy was utilized and surface morphology of coatings after corrosion was observed using scanning electron microscope. It was found that the addition of small PEDOT/PSS to the epoxy resin increased its corrosion protection efficiency. Meanwhile, the possible mechanism was discussed.

scholarly journals Karakterisasi Membran ZSM-5 yang Disintensis dengan Variasi Jenis dan Ukuran Kasa Penyangga

2020 ◽  
Vol 16 (1) ◽  
pp. 1
Author(s):  
Ana Hidayati Mukaromah ◽  
Tulus Ariyadi ◽  
Inas Hasna Azizah ◽  
Mifbakhuddin Mifbakhuddin
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Energy Dispersive Spectroscopy ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Aisi 316 ◽  
Scanning Electron

<p>Telah dilakukan sintesis dan karakterisasi membran ZSM-5 dengan penyangga kasa jenis 304 ukuran 200 dan 400 mesh dan jenis kasa AISI 316 ukuran 180 mesh. Tujuan penelitian ini adalah mensintesis membran ZSM-5 dengan penyangga kasa jenis 304 ukuran 200 dan 400 mesh dan jenis kasa AISI 316 ukuran 180 mesh dan mengkarakterisasi membran ZSM-5 hasil sintesis. Sintesis membran dilakukan dengan cara melapiskan prekursor ZSM-5 (<em>coating)</em> pada penyangga kasa yang telah diberi perlakuan dan dipanaskan pada suhu 90 °C selama 4 hari. Selanjutnya, membran yang dihasilkan dikarakterisasi engan metoda <em>X-ray diffraction</em> (XRD), <em>scanning electron microscope-energy dispersive spectroscopy</em> (SEM-EDS) dan <em>Fourier-transform infrared</em> (FTIR). Hasil citra SEM-EDS menunjukkan bahwa ukuran membran ZSM-5 yang semakin besar, menghasilkan jumlah lubang atau pori semakin banyak dengan luasan pori yang semakin kecil. Pola difraksi XRD menunjukkan bahwa membran yang dihasilkan mempunyai intensitas tertinggi pada 2 8º dan 23º yang merupakan karakteristik dari ZSM-5. Hasil spektra FTIR menunjukkan adanya serapan pada bilangan gelombang 450 cm<sup>-</sup><sup>1</sup>yang merupakan ciri khas membran ZSM-5.</p><p class="Text"><strong>Characterization of ZSM-5 Membranes Synthesized by Variation of Support Types and Sizes.</strong> Synthesis and characterization of ZSM-5 membrane were carried out with 304 type 200 and 400 mesh gauze supports and 180 mesh AISI 316 gauze types. The purpose of this study was to synthesize ZSM-5 membrane with 304 type 200 and 400 mesh gauze support and AISI 316 type 180 mesh size 180 mesh and characterize the synthesized ZSM-5 membrane. Membrane synthesis was carried out by coating the pre-treated gauze support with the ZSM-5 precursor and was heated at 90 °C for 4 days. Furthermore, the resulting membrane was characterized by X-ray diffraction (XRD), scanning electron microscope-energy dispersive spectroscopy (SEM-EDS) dan Fourier-transform infrared (FTIR). The SEM-EDX analysis shows that the increasing of ZSM-5 membrane size allowed pores number to increase with smaller pore surface area. The X-ray Diffraction pattern (XRD) shows that the resulting membrane has the highest intensity at 2  of 8º and 23º as the characteristics of ZSM-5. The FTIR spectra results show absorption at wavenumbers 450 cm<sup>-1</sup> which is a characteristic of ZSM-5 membranes.</p>

Microporous Chitosan-Succinonitrile Membrane for Lithium Rechargeable Batteries

2016 ◽  
Vol 1133 ◽  
pp. 8-12 ◽  
Author(s):  
Nur Umira Taib ◽  
Nurul Hayati Idris
Keyword(s):  
Electron Microscope ◽  
Phase Separation ◽  
Electrochemical Impedance Spectroscopy ◽  
Ionic Conductivity ◽  
Impedance Spectroscopy ◽  
Scanning Electron Microscope ◽  
Electrochemical Impedance ◽  
Rechargeable Batteries ◽  
Lithium Rechargeable Batteries ◽  
Scanning Electron

In this work, microporous chitosan-succinonitrile membranes were prepared by phase separation method. The membranes were characterized using electrochemical impedance spectroscopy and scanning electron microscope. It was found that the addition of succinonitrile increased the pore size, which in turn increased the ionic conductivity of the chitosan-succinonitrile membrane.

scholarly journals Continuidad en la técnica de elaboración de moldes para el vaciado de plata en el área centro andina desde la época precolombina hasta la actualidad

2019 ◽  
pp. 54-61
Keyword(s):  
Electron Microscope ◽  
Technology Transfer ◽  
Scanning Electron Microscope ◽  
Energy Dispersive Spectroscopy ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

Continuidad en la técnica de elaboración de moldes para el vaciado de plata en el área centro andina desde la época precolombina hasta la actualidad Continuity of the technique of manufacturing molds for casting silver at the Center Andean Area, from Precolumbian times Luisa Vetter Parodi Museo Nacional Sicán; Programa de Estudios Andinos-PUCP Av. Manuel Villarán 192, Dpto. 302, Urbanización Aurora, Miraflores DOI: https://doi.org/10.33017/RevECIPeru2011.0010/ RESUMEN En la época precolombina, los orfebres del área centro andina manejaban distintas técnicas de vaciado para elaborar piezas de metal. Una de estas técnicas era el vaciado en moldes bivalvos elaborados en arcilla y con temperantes orgánicos. Esta misma técnica de elaboración de moldes la podemos apreciar hoy en día en San Pablo de Canchis, donde los plateros cusqueños elaboran sus piezas vaciadas de plata en moldes elaborados con técnicas muy parecidas a la de los orfebres precolombinos. Para poder determinar si hubo transferencia de tecnología entre los orfebres precolombinos y los sanpablinos, hemos analizado moldes procedentes del cementerio inca de Rinconada Alta en La Molina en Lima y moldes de San Pablo de Canchis por microscopia electrónica de barrido con espectroscopia de energía dispersa (MEB-EED), fluorescencia de rayos X (FRX) y difracción de rayos X (DRX). Descriptores: Plata, moldes, vaciado, época precolombina, San Pablo de Canchis, arqueometría. ABSTRACT In Precolumbian times, silversmiths used different casting techniques to make their metal works. One of them was casting with bivalve molds made with clay and organic temper. The same technique can be seen nowadays at San Pablo de Canchis, where Cuzco silversmiths made their works with similar techniques to those of Precolumbian times. In order to determine if there was a technology transfer between Precolumbian silversmiths and San Pablo's, we have analized molds from the Inca cemetery of Rinconada Alta, La Molina, in Lima, and also molds from San Plablo de Canchis, using scanning electron microscope and energy dispersive spectroscopy (SEM-EDAX), X ray fluorescence (XRF) and X ray diffraction (XRD). Keywords: Silver, molds, casting, Precolumbian times, San Pablo de Canchis, archeometry.

PHAX-SCAN: Functional integration of a Scanning Electron Microscope and an energy-dispersive x-ray analyser

1989 ◽  
Vol 47 ◽  
pp. 56-57
Author(s):  
Marc H. Peeters ◽  
Max T. Otten
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
High Speed ◽  
High Performance ◽  
Functional Integration ◽  
Energy Dispersive ◽  
X Rays ◽  
X Ray ◽  
High Speed Analysis ◽  
Scanning Electron

Over the past decades, the combination of energy-dispersive analysis of X-rays and scanning electron microscopy has proved to be a powerful tool for fast and reliable elemental characterization of a large variety of specimens. The technique has evolved rapidly from a purely qualitative characterization method to a reliable quantitative way of analysis. In the last 5 years, an increasing need for automation is observed, whereby energy-dispersive analysers control the beam and stage movement of the scanning electron microscope in order to collect digital X-ray images and perform unattended point analysis over multiple locations.The Philips High-speed Analysis of X-rays system (PHAX-Scan) makes use of the high performance dual-processor structure of the EDAX PV9900 analyser and the databus structure of the Philips series 500 scanning electron microscope to provide a highly automated, user-friendly and extremely fast microanalysis system. The software that runs on the hardware described above was specifically designed to provide the ultimate attainable speed on the system.

scholarly journals Characterizing Severely Plastically Deformed Materials Using Transmission Kikuchi Diffraction and Energy Dispersive X-ray Spectroscopy in the Scanning Electron Microscope

2013 ◽  
Vol 19 (S2) ◽  
pp. 692-693
Author(s):  
P. Trimby
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Energy Dispersive ◽  
X Ray ◽  
Scanning Electron

Extended abstract of a paper presented at Microscopy and Microanalysis 2013 in Indianapolis, Indiana, USA, August 4 – August 8, 2013.

Karakteristik Hasil Proses Nitridisasi Besi Tuang Nodular Temperatur 5500C pada Waktu Penahanan 2 Jam, 4 Jam, 6 Jam

2021 ◽  
Vol 12 (1) ◽  
pp. 13-18
Author(s):  
Wayan Sujana
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Energy Dispersive ◽  
Fluidised Bed ◽  
X Ray ◽  
Scanning Electron

Nitridisasi merupakan suatu proses perlakuan panas termokimia yang dimana nitrogen dan amonia didifusikan kepermukaan material (ferro and non-ferro) pada temperatur 500-6000C sehingga membentuk pengerasan kulit akibat terbentuknya lapisan nitrida paduan pada permukaan. Namun pengerasan permukaan ditentukan oleh paduan dari material yang dilakukan proses nitridisasi.Tujuan Nitridisasi adalah untuk memperbaiki ketahanan aus, meningkatkan ketahanan lelah, dan memperbaiki ketahanan tehadap korosi. Proses nitidisasi ini juga dapat mengganti jenis perlakuan panas lain yang menekankan performance yang baik. Pada penelitian ini akan memanfaatkan besi cor nodular yanga akan diproses nitridisasi menggunakan fluidised bed furnace. Pada penelitian ini menggunakan pengujian distribusi kekerasan (metode vickers) untuk mengamati sejauh mana nitrogen berdifusi pada permukaan spesimen, dan pengamatan struktur mikro dengan scanning electron microscope, energy dispersive X-Ray spectroscopy (SEM-EDS).Penelitian ini akan memberikan informasi fenonema proses nitridisasi pada besi cor nodular sehingga mendapatkan suatu analisis yang sesuai dengan metode sehingga menghasilkan kualitas kekerasan permukaan yang baik.

scholarly journals Pengaruh Suhu Kalsinasi terhadap Karakteristik Komposit Forsterit-Karbon Tersintesis dalam Medium Gas Argon

2020 ◽  
Vol 16 (2) ◽  
pp. 12
Author(s):  
Solihudin Solihudin ◽  
Haryono Haryono ◽  
Atiek Rostika Noviyanti ◽  
Muhammad Rizky Ridwansyah
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Rice Husk ◽  
Energy Dispersive Spectroscopy ◽  
Carbon Composite ◽  
X Ray Diffraction ◽  
Argon Gas ◽  
X Ray ◽  
Scanning Electron

<p>Komposit forsterit-karbon merupakan salah satu material modifikasi dari forsterit yang berpotensi memiliki sifat isolator panas baik. Karbon dalam komposit dapat mengisi cacat titik pada kristal forsterit. Arang sekam padi (residu gasifikasi) mengandung SiO2 amorf dan karbon yang tinggi. Penelitian ini bertujuan menentukan pengaruh suhu kalsinasi dalam medium gas inert (dengan pengaliran gas argon) terhadap karakteristik komposit forsterit-karbon dari arang sekam padi dan magnesium karbonat. Metode penelitian meliputi preparasi arang sekam padi hasil gasifikasi, dan sintesis forsterit-karbon. Proses sintesis komposit forsterit karbon dilakukan dengan cara mencampurkan arang sekam padi dengan kalium karbonat pada rasio mol magmesium terhadap silikon sebesar 2 : 1 kemudian dikalsinasi dengan suhu divariasikan (700, 800, 900, dan 1000 oC). Selanjutnya sampel hasil sintesis dikarakterisasi dengan Fourier-transform infrared (FTIR), X-ray diffraction (XRD), dan scanning electron microscope-energy dispersive spectroscopy (SEM-EDS). Hasil karakterisasi dengan FTIR dan XRD diperoleh kesimpulan bahwa forsterit mulai terbentuk pada suhu kalisiasi 800 oC dan sempurna pada suhu 1000 oC, karenanya komposit yang terbentuk pada 1000 oC dimungkinkan sebagai forsterit-karbon, di mana unsur-unsur yang terkandung ditunjukkan oleh SEM-EDS.</p><p> </p><p><strong>The Effect of Calcination Temperature on the Characteristics of Forsterite-Carbon Composites Synthesized in Argon Gas Medium</strong>. Forsterite-carbon composite is one of the material modifications of forsterite, which potentially has a good heat insulation property. Carbon in composites can fill point defects in forsterite crystals. Rice husk charcoal, as gasification residues, contains high amorphous SiO2 and carbon. This study aims to determine the effect of temperature on the calcination of a mixture of rice husk charcoal and magnesium carbonate under an inert gas (argon gas) on the characteristics of the forsterite-carbon composite produced. The experimental research performed includes the preparation of gasified rice husk charcoal and the synthesis of the carbon-forsterite composite. The synthesis process of the carbon-forsterite composites was carried out by mixing rice husk charcoal with potassium carbonate at a mole ratio of magnesium to silicon of 2 : 1. The mixture was then calcined with varying temperatures (700, 800, 900, and 1000 °C). Furthermore, the synthesized sample was characterized by Fourier-transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscope-energy dispersive spectroscopy (SEM-EDS). The FTIR and XRD analysis show that the forsterites began to form at a calcination temperature of 800 °C and perfectly formed at a temperature of 1000 °C; therefore, the composite formed at 1000 °C is possible as forsterite-carbon, in which the contained elements were indicated by SEM-EDS.</p>

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