Deep and crustal factors of thorium-uranium mineralization of the Golovanevskaya zone of Ukrainian Shield

The article discusses the features of the deep and crustal structure of the Golovanevskaya zone, the geochronological sequence of the main stages of its formation. The characteristic of thorium-uranium ore occurrences and deposits is given; and the main stages of their formation. The stages of successive concentrations of uranium and thorium in connection with the processes of sedimentation, volcanism, metamorphism, ultrametamorphism, and tectonic-magmatic activation are determined. The concentration of uranium and thorium was multi-stage and increased with each subsequent geological process. The deep and crustal sources of uranium and thorium, their ratio in the pre-ore main ore-generating stages of deposit formation are considered. It is shown that the formation of deposits became possible in the Proterozoic when neutral and alkaline water-potassium fluids replaced the deep acidic Archean fluids, and the formation of thorium-uranium rock complexes became possible in the crust. The totality of the data obtained is the basis for classifying the thorium-uranium mineralization as the metamorphogenic type. The presence in the Golovanevskaya zone of Lozovatsky, Yuzhny, Kalinovsky deposits, and numerous thorium-uranium ore occurrences determine this zone as promising for developing the thorium-uranium raw material base of the nuclear energy of Ukraine. Thorium-uranium mineralization is also genetically typical for the Kryvyi Rih-Inguletskaya, Orekhovo-Pavlograd interblock suture zones; detailed research is needed to determine their prospects. The confinement of thorium-uranium mineralization specifically to interblock zones is due to a combination of the following main regional features: the presence of Neoarchean thorium-uranium-bearing rock complexes; their metamorphism under conditions of granulite facies; intense ultrametamorphism; development of deep fluid-conducting faults; deep level of the erosional section, in which the products of the rare-metal and pyrite stages of thorium-uranium mineralization were exposed.

An assessment of uranium in groundwater in the Grand Canyon region

The Grand Canyon region in northern Arizona is a home or sacred place of origin for many Native Americans and is visited by over 6 million tourists each year. Most communities in the area depend upon groundwater for all water uses. Some of the highest-grade uranium ore in the United States also is found in the Grand Canyon region. A withdrawal of over 4000 km2 of Federal land in the Grand Canyon region from new uranium mining activities for 20 years was instituted in 2012, owing in part to a lack of scientific data on potential effects from uranium mining on water resources in the area. The U.S. Geological Survey has collected groundwater chemistry samples since 1981 in the Grand Canyon region to better understand the current state of groundwater quality, to monitor for changes in groundwater quality that may be the result of mining activities, and to identify "hot spots" with elevated metal concentrations and investigate the causes. This manuscript presents results for the assessment of uranium in groundwater in the Grand Canyon region. Analytical results for uranium in groundwater in the Grand Canyon region were available for 573 samples collected from 180 spring sites and 26 wells from September 1, 1981 to October 7, 2020. Samples were collected from springs issuing from stratigraphic units above, within, and below the Permian strata that host uranium ore in breccia pipes in the area. Maximum uranium concentrations at groundwater sites in the region ranged from less than 1 µg/L at 23 sites (11%) to 100 µg/L or more at 4 sites (2%). Of the 206 groundwater sites sampled, 195 sites (95%) had maximum observed uranium concentrations less than the U.S. Environmental Protection Agency’s Maximum Contaminant Level of 30 µg/L for drinking water and 177 sites (86%) had uranium concentrations less than the 15 µg/L Canadian benchmark for protection of aquatic life in freshwater. The establishment of baseline groundwater quality is an important first step in monitoring for change in water chemistry throughout mining lifecycles and beyond to ensure the health of these critical groundwater resources.

Uranium carbonate complexes demonstrate drastic decrease in stability at elevated temperatures

Quantitative understanding of uranium transport by high temperature fluids is crucial for confident assessment of its migration in a number of natural and artificially induced contexts, such as hydrothermal uranium ore deposits and nuclear waste stored in geological repositories. An additional recent and atypical context would be the seawater inundated fuel of the Fukushima Daiichi Nuclear Power Plant. Given its wide applicability, understanding uranium transport will be useful regardless of whether nuclear power finds increased or decreased adoption in the future. The amount of uranium that can be carried by geofluids is enhanced by the formation of complexes with inorganic ligands. Carbonate has long been touted as a critical transporting ligand for uranium in both ore deposit and waste repository contexts. However, this paradigm has only been supported by experiments conducted at ambient conditions. We have experimentally evaluated the ability of carbonate-bearing fluids to dissolve (and therefore transport) uranium at high temperature, and discovered that in fact, at temperatures above 100 °C, carbonate becomes almost completely irrelevant as a transporting ligand. This demands a re-evaluation of a number of hydrothermal uranium transport models, as carbonate can no longer be considered key to the formation of uranium ore deposits or as an enabler of uranium transport from nuclear waste repositories at elevated temperatures.