Chemical Vapour Deposition (CVD) Technique for Abatement of Volatile Organic Compounds (VOCs)

2020 ◽  
Vol 71 (7) ◽  
pp. 97-113
Author(s):  
Marius Stoian ◽  
Liliana Lazar ◽  
Florent Uny ◽  
Frederic Sanchette ◽  
Ioana Fechete

Chemical vapour deposition (CVD) is an important technique that uses volatile precursors to produce thin film deposits on an exposed substrate, having the capability to generate different types of nanostructures (e.g. nanoparticles, nanotubes, nanofibers or nanocomposites) as catalytic materials. The environmental hazard of volatile organic compounds (VOCs) requires efficient methods to reduce their emission into the atmosphere, due to their high potential to cause severe health issues, along with their extended spread in the environment. Catalytic combustion proves to be one of the most effective means for the abatement of VOCs, employing different catalysts, such as noble metals or non-noble metal oxides, to facilitate the oxidation process of the pollutants. These catalysts can be prepared through various methods as multiple steps wet processes or CVD techniques, indicating the superiority of the CVD-prepared catalysts compared to those prepared using the former type of process, due to the ability to achieve high dispersion of the active material, together with enhanced textural and morphological properties. This paper aims to present the various CVD techniques employed in the fabrication of different catalysts with the possibility of generating materials at nano-scale for use in numerous reactions, mostly in combustion process for VOCs decomposition.

2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Jiaqi Li ◽  
Hui Liu ◽  
Yuzhou Deng ◽  
Gang Liu ◽  
Yunfa Chen ◽  
...  

AbstractThe strong growing interest in using catalytic oxidation to remove volatile organic compounds (VOCs), which seriously threaten the health of human being, is rooted in its desirable features such as relative energy savings, low cost, operation safety and environmental friendliness. Within the last decades, the development of manufacturing processes, characterization techniques and testing methods has led to the blossom of research in synthesis and application of various nanostructured materials, which creates great opportunities and also a tremendous challenge to apply these materials for highly efficient catalytic removal of VOCs. We herein will systematically introduce the latest research developments of nanostructured materials for the catalytic degradation of VOCs so as to provide the readers a coherent picture of the field, mainly focusing on noble metals and metal oxides, which are currently two primary types of VOC catalysts. This review will focus on synthesis, fabrication and processing of nanostructured noble metals and metal oxides as well as the fundamentals and technical approaches in catalytic removal of VOCs, providing technical strategies for effectively developing novel nanostructured catalysts with low cost, enhanced activity and high stability for pollutant removal from surrounding environments.


2001 ◽  
Vol 35 (33) ◽  
pp. 5823-5831 ◽  
Author(s):  
G Fernández-Martı́nez ◽  
P López-Mahı́a ◽  
S Muniategui-Lorenzo ◽  
D Prada-Rodrı́guez ◽  
E Fernández-Fernández

2018 ◽  
Vol 44 (4) ◽  
Author(s):  
Anna Barbara Janicka ◽  
Maciej Zawiślak ◽  
Bartosz Gawron ◽  
Aleksander Górniak ◽  
Tomasz Białecki

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8462
Author(s):  
Bartosz Gawron ◽  
Aleksander Górniak ◽  
Tomasz Białecki ◽  
Anna Janicka ◽  
Radosław Włostowski ◽  
...  

This paper refers to the study of biofuel as an alternative power source for turbine aviation engines. Blends of Jet A-1 fuel and synthesized hydrocarbons from Hydrotreated Esters and Fatty Acids (HEFA) technology at different proportions, such as 25%, 50% and 75%, were used for tests. All the test results were compared with the neat Jet A-1 fuel. A miniature GTM series turbojet engine was used in the test rig studies. During the tests conducted at a specific rotational speed, selected engine operating parameters as well as the emission of volatile organic compounds were measured. In terms of engine performance, no significant differences were found between the test fuels. The results of volatile organic compound emissions indicate that among the most toxic compounds the highest concentrations were obtained for benzene. The addition of the HEFA synthetic component and increasing its proportion in the blend resulted in the obtained concentration values for benzene showing a decreasing trend. The plotted utility profile indicates that the most optimal blend, i.e., the least toxic, is the blend with the share (v/v) of 62.5% of Jet A-1 fuel and 37.5% of HEFA component.


2015 ◽  
Vol 818 ◽  
pp. 185-189
Author(s):  
Eva Ružinská ◽  
Vladimír Hagara ◽  
Peter Jakúbek ◽  
Krzysztof Krajewski

The paper deals with the design of quantitative evaluation resulting from the decomposition products of surface-treated wood in the combustion process. This proposal evaluation in addition to monitoring the quality characteristics of the surfactant treated wood will add information on fire protection and selected environmental characteristics (emission of volatile organic compounds).


2013 ◽  
Vol 10 (2) ◽  
pp. 217-225

A chemical vapour sensor working with a monochromatic light source and based on optical fibre coated with a thin siloxane polymer film has been developed for in situ monitoring of volatile organic compounds, such as ethylbenzene, xylene (o-xylene), heptane, octane, chloroform, carbon tetrachloride, ethanol and butanol in indoor atmosphere and confined areas of industrial environments. The sensor consists on a monomode optical fibre with an end surface coated with a thin polymeric film by dip-coating technique. The light source utilized was a stabilized laser diode at 1550 nm and the light power changes were measured with a photodiode. The sensor was tested for different VOCs and for different individual concentrations regarding stability, sensitivity, repeatability and reversibility of the analytical signal. The response and desorption time have been found to be 30 seconds and good reproducibility and accuracy have been also obtained. Finally, the analytical performance of the developed sensor was also evaluated and found adequate for actual monitoring on indoor atmospheres.


2012 ◽  
Vol 21 ◽  
pp. 117-123 ◽  
Author(s):  
G. Sakale ◽  
D. Jakovlevs ◽  
I. Aulika ◽  
Maris Knite

The main topic of this paper is the study of polyisoprene-multi wall carbon nanotubes (PiMWCNT) composites electrical conductivity and volatile organic compound sensing properties with respect to type of multi wall carbon nanotubes used. Electrical percolation parameters like percolation threshold and critical exponent of produced composites are determined and analyzed. PiMWCNT composites exhibit a promising sensitivity to the presence of volatile organic compounds. Therefore the composites sensing mechanism of volatile organic compounds are analyzed in more detail by applying an original measuring technique which enables simultaneous measurement of an electrical resistance, mass and length change measurement of the sample in the presence and subsequent absence of a vapour. Measurement results enabled the evaluation of both vapour diffusion behavior in the composite and electrical resistance change mechanism.


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