The contradictory statements of Dr. Sutherland and Dr. Kane, with regard to the saltness of the ice formed from sea-water,—the former maintaining that sea-water ice contains about one-fourth of the salt of the original water; the latter, that if the cold be sufficiently intense, there will be formed from sea-water a fresh and purer element fit for domestic use,—induced the author to take advantage of his position, as naturalist to the expedition now in the northern seas, to reinvestigate the subject. The changes which he has observed sea-water to undergo in freezing are the following. When the temperature falls below + 28°⋅5, it becomes covered with a thin pellicle of ice; after some time this pellicle becomes thicker and presents a vertically striated structure, similar to that of the ordinary cakes of sal-ammoniac. As the ice further increases in thickness, it becomes more compact, but the lowest portion still retains the striated structure. On the surface of the ice, saline crystals, designated by the author “efflorescence,” soon begin to form, at first few in number and widely separated, but gradually forming into tufts and ultimately covering the whole surface. At first, the increase in thickness of the ice is rapid, but afterwards the rate of growth is much slower and more uniform. The ice formed yields, on being melted, a solution differing in specific gravity according to the temperature at the time of congelation, its density being less, the lower the temperature at which the process of congelation took place. Although the author’s observations extended from + 28°⋅5 to —42°, he was never able to obtain fresh-water from sea-ice, the purest specimen being of specific gravity 1⋅005, and affording abundant evidence of the presence of salts, especially of chloride of sodium, in such quantity as to render it unfit for domestic purposes.
Prediction of Material Behavior and Failure of Fresh Water Ice Based on Viscoplastic-Damage Model
