scholarly journals Source Apportionment and Risk Assessment of Polycyclic Aromatic Hydrocarbons in Black Carbon Monitored in Port Harcourt, Rivers State, Nigeria

Author(s):  
Muhyideen Oloyede ◽  
Precious Nwobidi Ede

The purpose of this study was to determine concentrations of polycyclic aromatic hydrocarbons (PAHs) in air samples in Port Harcourt metropolis, Rivers State, Nigeria, evaluate their potential risks to human health and identify pollution sources by characterizing the PAHs. Sixteen polycyclic aromatic hydrocarbons were measured with a total concentration range of 0 to 9,589 mg/kg in the rainy season and 0.46 to 131mg/kg range in the dry season. High molecular weight PAHs dominated the PAH profiles accounting for 91% in dry season and 45% in the wet season. The overall assessment of the ratios of LMW to HMW of minimum, maximum and mean concentrations indicated pyrogenic sources. Benzo (a) pyrene equivalent (BaPeq) analysis showed that benzo (a) pyrene, DiBenzo (a,h) antracene and Indeno (1.2.3-cd) pyrene contributed the highest cancer toxicity with 94% and 85% in wet and dry seasons, respectively. The total incremental lifetime cancer risks of PAHs ranged from 0 to 4.90 with a median value of 3.37 x10-2 in wet season; while in the dry season, ILCR of PAHs ranged from 1.62 x10-5 to 7.42x10-3 with a median value of 1.15 x 10-3 . These values showed pervasive pollution indicating a major carcinogenic risk of PAHs. Mean ILCR in wet season was 3.37 x10-2 (33,700 x10-6 ) meaning 1 in every 30 persons in the study area is estimated to develop cancer. In the dry season, mean ILCR was 1.15 x10-3 (1,150 x10-6 ) meaning 1 in every 870 persons in the study area is estimated to develop cancer.

Author(s):  
Chinedu Jude Ossai ◽  
Chukwujndu Maxwell Azubuike Iwegbue ◽  
Godswill O Tesi ◽  
Chijioke Olisah ◽  
Francis E Egobueze ◽  
...  

In this study, we evaluated the concentrations, composition, sources, and potential risks of polycyclic aromatic hydrocarbons (PAHs) in soils, and indoor and outdoor dust from Port Harcourt city in Nigeria....


2021 ◽  
Vol 20 (1) ◽  
pp. 65-74
Author(s):  
Virginia I.P. Nitonye ◽  
Michael Horsfall Jnr ◽  
Mark O. Onyema

United State Environmental Protection Agency (USEPA) priority polycyclic aromatic hydrocarbons (PAHs) were investigated in electric grilled (EG) foods: plantain (EG-PN), meat (EG-MT), yam (EG-YM) and fish (EG-FH), commonly consumed in Port Harcourt, Rivers State, southern Nigeria. Distribution and concentrations of PAHs in the EG food samples were obtained by gas chromatography (GC)   nalyses, after extraction using hexane/dichloromethane (1:3 v/v) and clean up by column chromatography. GC analyses identified 13 to 16 PAHs in the food samples with 10 observed to occur in all. Fluoranthene, pyrene (4-ring PAHs) and benzo(a)pyrene (5-ring PAH) were the most abundant, while the 2- and 3-ring PAHs were generally minor constituents or absent. Concentrations of PAHs in the EG foods ranged from 15.73 to 67.13 µg/kg and was observed to decrease in the order EG-PN>EG-MT > EG-YM > EG-FH with increase in grilling time. Ratios used as diagnostic indices of PAH formation processes indicate a combustion source for PAHs in the food samples  and revealed electric grilling generated PAHs which contaminated the foods. Benzo(a)pyrene (BaP), used as a marker for PAH  contamination in foods, had concentrations of 7.51 μg/kg, 2.68 μg/kg, 2.33 μg/kg and 1.85 μg/kg in EG-PN, EG-MT, EG-YM and EG-FH  respectively. These values were above the maximum limit of 2 μg/kg set by the European Union, except for EG-FH which was slightly lower. Keywords: Food, Polycyclic aromatic hydrocarbons, Electric grill, Concentration, Diagnostic ratio, Nigeria.


Toxics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 65
Author(s):  
Bazoin Sylvain Raoul Bazié ◽  
Caroline Douny ◽  
Thomas Judicaël Ouilly ◽  
Djidjoho Joseph Hounhouigan ◽  
Aly Savadogo ◽  
...  

Charcoal- or wood-cooked chicken is a street-vended food in Burkina Faso. In this study, 15 samples of flamed chicken and 13 samples of braised chicken were analyzed for 15 priority polycyclic aromatic hydrocarbons (PAHs) with a high-performance liquid chromatography-fluorescence detector. A face-to-face survey was conducted to assess the consumption profiles of 300 men and 300 women. The health risk was assessed based on the margin of exposure (MOE) principle. BaP (14.95–1.75 μg/kg) and 4PAHs (BaP + Chr + BaA + BbF) (78.46–15.14 μg/kg) were eight and five times more abundant at the median level in flamed chickens than in braised ones, respectively. The contents of BaP and 4PAHs in all flamed chicken samples were above the limits set by the European Commission against 23% for both in braised chickens. Women had the highest maximum daily consumption of both braised (39.65 g/day) and flamed chickens (105.06 g/day). At the estimated maximum level of consumption, women were respectively 3.64 (flamed chicken) and 1.62 (braised chicken) times more exposed to BaP and 4PAHs than men. MOE values ranged between 8140 and 9591 for men and between 2232 and 2629 for women at the maximum level of consumption of flamed chickens, indicating a slight potential carcinogenic risk.


2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Minmin Wu ◽  
Zhonghuan Xia ◽  
Qianqian Zhang ◽  
Jing Yin ◽  
Yanchi Zhou ◽  
...  

In a market basket study made in Nanjing, China, in which the most common consumed nine kinds of vegetables foodstuffs were sampled, the contents of 16 polycyclic aromatic hydrocarbons (PAHs) were analyzed using gas chromatography with mass spectrometer detector (GC-MS). The results showed that the total amount of 16 PAHs was within the range of 60.5~312 ng g−1 (wet weight). The ranking of total concentrations for different types of vegetables in decreasing order was leafy vegetable, fruit vegetable, and rhizome vegetable. Source analysis suggested that coal, oil, or other incomplete combustion of biomass mainly contributed to the concentration of PAHs. The margin of exposure (MOE) approach with age/gender group-specific daily dietary exposure level was used to estimate the carcinogenic risk. The calculated total mean MOE in the case of BaP and PAH4 (sum of BaA, CHR, BbF, and BaP) was 14960 and 7723, respectively, for local residents. In addition, the MOEs in PAH4 for some groups of both male and female were below the critical limit of 10 000 proposed by EFSA. Therefore, health effect owing to the consumption of vegetables on local residents needs high concern.


2013 ◽  
Vol 864-867 ◽  
pp. 1364-1368
Author(s):  
Yakup Parida ◽  
Eslamjan Diwani

Based on the principle of solid phase extraction and the purification method using Florida silica, sixteen various kinds of polycyclic aromatic hydrocarbons such as naphthalene, acenaphthene and fluorene were measured in Urumqi snow by means of HPLC. The results showed that the concentration of PAHs was different in different sampling sites in Urumqi. The total concentration of PAHs was in the range of 0.2883 ~ 8.814 µg/mL and the content of PAHs snow was higher than that in water, which indicated that the snow was polluted by organic matters to a certain degree and the pollution was not so serious compared with the groundwater. So the snow has a certain application value for life.


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