Organic Matter of Bazhenov Formation: Chemical and Isotope Composition, Microstructure, Thermal Maturation, Generation Potential and the Effect on Rock Properties

Author(s):  
M. Spasennykh ◽  
A. Voropaev ◽  
E. Kozlova ◽  
E. Leushina ◽  
V. Polyakov ◽  
...  
2021 ◽  
Vol 204 ◽  
pp. 108751
Author(s):  
Evgeniya Leushina ◽  
Polina Mikhaylova ◽  
Elena Kozlova ◽  
Veniamin Polyakov ◽  
Nikita Morozov ◽  
...  

We present an overview of geochemical data from pore waters and solid phases that clarify earliest diagenetic processes affecting modern, shallow marine carbonate sediments. Acids produced by organic matter decomposition react rapidly with metastable carbonate minerals in pore waters to produce extensive syndepositional dissolution and recrystallization. Stoichiometric relations among pore water solutes suggest that dissolution is related to oxidation of H 2 S which can accumulate in these low-Fe sediments. Sulphide oxidation likely occurs by enhanced diffusion of O 2 mediated by sulphide-oxidizing bacteria which colonize oxic/anoxic interfaces invaginating these intensely bioturbated sediments. Buffering of pore water stable isotopic compositions towards values of bulk sediment and rapid 45 Ca exchange rates during sediment incubations demonstrate that carbonate recrystallization is a significant process. Comparison of average biogenic carbonate production rates with estimated rates of dissolution and recrystallization suggests that over half the gross production is dissolved and/or recrystallized. Thus isotopic and elemental composition of carbonate minerals can experience significant alteration during earliest burial driven by chemical exchange among carbonate minerals and decomposing organic matter. Temporal shifts in palaeo-ocean carbon isotope composition inferred from bulk-rocks may be seriously compromised by facies-dependent differences in dissolution and recrystallization rates.


Author(s):  
A. S. Roslyakova ◽  
A. G. Kalmykov ◽  
G. A. Kalmykov ◽  
R. A. Khamidullin ◽  
N. I. Korobova ◽  
...  

The paper presents a study of the structure and reservoir properties of rocks of the Bazhenov formation in the sections of three wells located in different structural zones of the Priobskoye field. It is shown that the porosity of the samples varies from 0.02% to 6.95%, the absolute gas permeability of the rocks reaches 1.364 mD. It is established that the collectors in the Bazhenov formation are confined to silicite-radiolarites (possessing porosity associated with the leaching of radiolarian shells) and kerogen-clay-siliceous rock and kerogen-clay silicite (porosity is associated with the release of space between the clay-siliceous matrix and kerogen by ripening organic matter). The following secondary processes influenced the formation of voids in these lithotypes: recrystallization of radiolarians and local warming up.


Author(s):  
M. S. Topchii ◽  
N. V. Pronina ◽  
A. G. Kalmykov ◽  
G. A. Kalmykov ◽  
M. M. Fomina ◽  
...  

One of the most famous and promising shale formations in Russia is the Bazhenov formation. The ambiguity of ideas about its geological features, caused by the complex, heterogeneous structure of the strata, attracts the attention of many researchers. In this work, the Bazhenov formation is singled out in conjunction with its stratigraphic counterparts in the Bazhenov high-carbon formation (BVCHF). In this were considered the main characteristics of its allotment and distribution over the area, as well as the geological structure. Being an unconventional reservoir of hydrocarbons, BVCHF has properties of a petroleum-bearing rock, one of the main characteristics of which is organic matter, its type and maturity. The paper presents the results of the study of organic matter by various methods at the micro level, as well as their integration with larger-scale studies. The need for detailed consideration of the organic matter of the BVCHF is justified by the fact that it has a mixed composition and, as a consequence, a different degree of transformation and spatial distribution.


2021 ◽  
Author(s):  
Yair Gordin ◽  
Thomas Bradley ◽  
Yoav O. Rosenberg ◽  
Anat Canning ◽  
Yossef H. Hatzor ◽  
...  

Abstract The mechanical and petrophysical behavior of organic-rich carbonates (ORC) is affected significantly by burial diagenesis and the thermal maturation of their organic matter. Therefore, establishing Rock Physics (RP) relations and appropriate models can be valuable in delineating the spatial distribution of key rock properties such as the total organic carbon (TOC), porosity, water saturation, and thermal maturity in the petroleum system. These key rock properties are of most importance to evaluate during hydrocarbon exploration and production operations when establishing a detailed subsurface model is critical. High-resolution reservoir models are typically based on the inversion of seismic data to calculate the seismic layer properties such as P- and S-wave impedances (or velocities), density, Poisson's ratio, Vp/Vs ratio, etc. If velocity anisotropy data are also available, then another layer of data can be used as input for the subsurface model leading to a better understanding of the geological section. The challenge is to establish reliable geostatistical relations between these seismic layer measurements and petrophysical/geomechanical properties using well logs and laboratory measurements. In this study, we developed RP models to predict the organic richness (TOC of 1-15 wt%), porosity (7-35 %), water saturation, and thermal maturity (Tmax of 420-435⁰C) of the organic-rich carbonate sections using well logs and laboratory core measurements derived from the Ness 5 well drilled in the Golan Basin (950-1350 m). The RP models are based primarily on the modified lower Hashin-Shtrikman bounds (MLHS) and Gassmann's fluid substitution equations. These organic-rich carbonate sections are unique in their relatively low burial diagenetic stage characterized by a wide range of porosity which decreases with depth, and thermal maturation which increases with depth (from immature up to the oil window). As confirmation of the method, the levels of organic content and maturity were confirmed using Rock-Eval pyrolysis data. Following the RP analysis, horizontal (HTI) and vertical (VTI) S-wave velocity anisotropy were analyzed using cross-dipole shear well logs (based on Stoneley waves response). It was found that anisotropy, in addition to the RP analysis, can assist in delineating the organic-rich sections, microfractures, and changes in gas saturation due to thermal maturation. Specifically, increasing thermal maturation enhances VTI and azimuthal HTI S-wave velocity anisotropies, in the ductile and brittle sections, respectively. The observed relationships are quite robust based on the high-quality laboratory and log data. However, our conclusions may be limited to the early stages of maturation and burial diagenesis, as at higher maturation and diagenesis the changes in physical properties can vary significantly.


2018 ◽  
Vol 480 (1) ◽  
pp. 611-614
Author(s):  
D. A. Bushnev ◽  
N. S. Burdelnaya ◽  
I. V. Goncharov ◽  
V. V. Samoylenko ◽  
M. A. Veklich

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