Polyaniline Nanocomposites

Author(s):  
Dipanwita Majumdar

Polyaniline in various forms has been widely explored as an electrode material for supercapacitors due to its high theoretical charge storage capacity, facile-cost-effective synthesis, good mechanical strength and ultrafast charge transport. However, commercialization of such pristine forms is very much restricted by low solubilities, rapid agglomeration during device design accompanied by poor electrochemical life and fast environmental decomposition. The blending with nano-carbon materials, metal oxides and other competent materials, may result in high quality materials– “nanocomposites” with superior features is ideally fit for future generation energy storage devices. The present chapter deals with detailed discussions on designing, the fabrication of such binary and ternary nanocomposites, correlating their morphology with electrochemical behavior, so as to optimize their supercapacitive performances. Such an attempt would help to outline the present status and future aspects of these materials which will be of first-hand assistance especially to the beginners to this field of research.

Author(s):  
Dipanwita Majumdar

Polyaniline in various forms has been widely explored as an electrode material for supercapacitors due to its high theoretical charge storage capacity, facile-cost-effective synthesis, good mechanical strength and ultrafast charge transport. However, commercialization of such pristine forms is very much restricted by low solubilities, rapid agglomeration during device design accompanied by poor electrochemical life and fast environmental decomposition. The blending with nano-carbon materials, metal oxides and other competent materials, may result in high quality materials– “nanocomposites” with superior features is ideally fit for future generation energy storage devices. The present chapter deals with detailed discussions on designing, the fabrication of such binary and ternary nanocomposites, correlating their morphology with electrochemical behavior, so as to optimize their supercapacitive performances. Such an attempt would help to outline the present status and future aspects of these materials which will be of first-hand assistance especially to the beginners to this field of research.


2018 ◽  
Vol 18 (12) ◽  
pp. 8352-8359 ◽  
Author(s):  
Xibin Liu ◽  
Gaohua liao ◽  
Xiang Qi ◽  
Xiaoan Mei ◽  
Jifei Wang ◽  
...  

Hybrid fibers based on MnO2/reduced graphene oxide have been fabricated for flexible energy storage devices. Graphene oxide nanoflakes were reduced in a polytetrafluoroethylene (PTFE) pipeline under the appropriate condition to develop a fiber current collector, which also provides the possibility of weaving. The RGO fiber with the radius of about 35 μm has a resistance of 150 Ω · cm. MnO2 nanoflakes directly grow on the RGO fiber surface acting as the electrode material of the device. The MnO2/RGO hybrid fibers provide excellent energy storage performances. The as-fabricated SC exhibits a high areal capacitance of 1.37 F·cm−2 at the scan rate of 1 mV·s−1, and outstanding long-term cycling stability of 93.75% retention after 5000 cycles. This work demonstrates a cost-effective and versatile strategy for wearable energy storage devices.


RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64395-64403 ◽  
Author(s):  
Pawan Kumar Srivastava ◽  
Premlata Yadav ◽  
Subhasis Ghosh

High yield production of high quality graphene is essential for its application in electronics, optoelectronics and energy storage devices.


2018 ◽  
Vol 54 (28) ◽  
pp. 3500-3503 ◽  
Author(s):  
C. V. Manohar ◽  
Tiago Correia Mendes ◽  
Mega Kar ◽  
Dabin wang ◽  
Changlong Xiao ◽  
...  

Sodium ion batteries (SIBs) are widely considered as alternative, sustainable, and cost-effective energy storage devices for large-scale energy storage applications.


2022 ◽  
Author(s):  
Xiaohong Ding ◽  
Ruilai Liu ◽  
Jiapeng Hu ◽  
Jingyun Zhao ◽  
Jinjin Wu ◽  
...  

The cost-effective synthesis of flexible energy storage devices with high energy and power densities is a challenge in wearable electronics. Here, we report a facile, efficient, and scalable approach for...


Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 3
Author(s):  
Azadeh Mirabedini ◽  
Zan Lu ◽  
Saber Mostafavian ◽  
Javad Foroughi

The ubiquity of wearables, coupled with the increasing demand for power, presents a unique opportunity for nanostructured fiber-based mobile energy storage systems. When designing wearable electronic textiles, there is a need for mechanically flexible, low-cost and light-weight components. To meet this demand, we have developed an all-in-one fiber supercapacitor with a total thickness of less than 100 μm using a novel facile coaxial wet-spinning approach followed by a fiber wrapping step. The formed triaxial fiber nanostructure consisted of an inner poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) core coated with an ionically conducting chitosan sheath, subsequently wrapped with a carbon nanotube (CNT) fiber. The resulting supercapacitor is highly flexible, delivers a maximum energy density 5.83 Wh kg−1 and an extremely high power of 1399 W kg−1 along with remarkable cyclic stability and specific capacitance. This asymmetric all-in-one fiber supercapacitor may pave the way to a future generation of wearable energy storage devices.


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