Investigation of Coordination Interaction of Trigonal Schiff Base Compound with Zn(II) Ions in Organized Molecular Films

2012 ◽  
Vol 236-237 ◽  
pp. 815-818
Author(s):  
Ti Feng Jiao ◽  
Jing Xin Zhou
Keyword(s):  
Schiff Base ◽  
Water Surface ◽  
Supramolecular Assembly ◽  
Coordination Interaction ◽  
Molecular Films ◽  
Alkyl Chains ◽  
Schiff Base Compound ◽  
Base Compound

In order to investigate the supramolecular assembly and coordination interaction of special amphiphile, a trigonal Schiff base compound with long alkyl chains was designed and synthesized, and its supramolecular assembly and interaction properties were investigated by spectral and morphological measurements. It was found that the Schiff base compound can be spread on water surface to form stable monolayer. When on the Zn(II) ions subphase, an in situ coordination can occur for all ligands. As a result, a 1:2 complex was formed for the trigonal chain Schiff base with Zn(II) ions through the coordination interaction. Due to the directionality and strong matching of coordination, two Zn(II) ions can be encapsulated into intramolecular space of the trigonal Schiff base compound.

Research on LB Films of Two Schiff Base Compounds with Alkyl Chains and Different Azobenzene Substituted Groups

2012 ◽  
Vol 581-582 ◽  
pp. 668-671
Author(s):  
Jing Xin Zhou ◽  
Ti Feng Jiao ◽  
Xu Hui Li ◽  
Feng Yan Wang
Keyword(s):  
Schiff Base ◽  
Water Surface ◽  
Supramolecular Assembly ◽  
Molecular Films ◽  
Lb Films ◽  
Alkyl Chains ◽  
Spectral Changes ◽  
Coordination Process ◽  
Predominant Effect

In order to investigate the supramolecular assembly and interfacial coordination of special amphiphile, two Schiff Base compounds with alkyl chains and different azobenzene substituted groups were designed and synthesized, and their supramolecular assembly and interfacial properties were investigated by spectral and morphological measurements. It was found that the Schiff base compounds can be spread on water surface to form stable monolayer. When on the Cu(II) ions subphase, an in situ coordination can occur for all ligands. In addition, for the coordination process of C16SB-Me-Azo with Cu(II), there are obvious spectral changes for the alkyl chains. For all process, the headgroups in all amphiphiles have predominant effect in regulating the aggregation mode and spectral changes in organized molecular films.

Chiral Interfacial Assembly of a Trigonal Schiff Base Compound with TPPS in Organized Molecular Films

2012 ◽  
Vol 236-237 ◽  
pp. 810-814
Author(s):  
Ti Feng Jiao ◽  
Jing Xin Zhou
Keyword(s):  
Schiff Base ◽  
Pure Water ◽  
Supramolecular Assembly ◽  
Solid Substrate ◽  
Interfacial Assembly ◽  
Alkyl Chains ◽  
Schiff Base Compound ◽  
Uniform Domains ◽  
Base Compound

In order to investigate the chiral interfacial assembly of special amphiphile, a trigonal Schiff base compound with long alkyl chains was designed and synthesized, and its supramolecular assembly and interaction properties were investigated by spectral and morphological measurements. Condensed monolayers were obtained on pure water surface, in which flat and uniform domains were obtained for the monolayers. When an anionic tetrakis(4-sulfonatonphenyl)porphine (TPPS) was added into an acidic subphase, an in situ complex formation between the trigonal amphiphile and TPPS occurred. The complex monolayers were transferred onto solid substrate and TPPS existed as J-aggregate and J-aggregate in the complex films. Due to the multisited positive charges in the spacer on acidic subphase, the complex films of trigonal amphiphile with TPPS appeared as short nanorod structures and formed two-dimensional (2D) conglomerate chiral domains.

Research on Hydrogen Bonding Interaction of Trigonal Schiff Base Compound with Barbituric Acid in Organized Molecular Films

2011 ◽  
Vol 694 ◽  
pp. 528-532
Author(s):  
Ti Feng Jiao ◽  
Jing Xin Zhou
Keyword(s):  
Hydrogen Bonding ◽  
Schiff Base ◽  
Water Surface ◽  
Barbituric Acid ◽  
Supramolecular Assembly ◽  
Hydrogen Bonding Interaction ◽  
Spectral Measurements ◽  
Bonding Interaction ◽  
Schiff Base Compound ◽  
Base Compound

In order to investigate the supramolecular assembly and intermolecular hydrogen bonding of special amphiphile, a trigonal Schiff base compound was designed and synthesized, and it supramolecular assembly and interaction properties were investigated by spectral measurements. It was found that the Schiff base compound can be spread on water surface to form stable monolayer. When it was spread on the subphase containing barbituric acid, it can show hydrogen bonding interaction with barbituric acid. Due to the directionality and strong matching of hydrogen bond, two barbituric acid molecules can be encapsulated into intramolecular space of the trigonal Schiff base compound through intermolecular H-bonding to form a 1:2 complex. A rational complex mode was proposed.

Azido bridged binuclear copper(ii) Schiff base compound: synthesis, structure and electrical properties

2019 ◽  
Vol 43 (41) ◽  
pp. 16255-16263
Author(s):  
Mrinmoy Ghosh ◽  
Sandip Saha ◽  
Abhijit Banerjee ◽  
Dieter Schollmeyer ◽  
Ananda Sarkar ◽  
...  
Keyword(s):  
Schiff Base ◽  
Electrical Properties ◽  
Binuclear Copper ◽  
Current Voltage ◽  
Compound Synthesis ◽  
Current Voltage Characteristics ◽  
Schiff Base Compound ◽  
Base Compound

The structure, FESEM, Al/complex/ITO microstructure and the current–voltage characteristics of the copper(ii) azido bridged dimer.

Synthesis, crystal structure, and magnetic properties of a new tetranuclear Cu(II) Schiff base compound

2009 ◽  
Vol 362 (8) ◽  
pp. 2915-2920 ◽  
Author(s):  
Moumita Biswas ◽  
Guillaume Pilet ◽  
Javier Tercero ◽  
M. Salah El Fallah ◽  
Samiran Mitra
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Schiff Base ◽  
Schiff Base Compound ◽  
Base Compound

Electrical property and Schottky behavior of a flexible Schiff-base compound: X-ray structure and stabilization of 1D water chain

2018 ◽  
Vol 20 (38) ◽  
pp. 24744-24749 ◽  
Author(s):  
Basudeb Dutta ◽  
Joydeep Datta ◽  
Suvendu Maity ◽  
Chittaranjan Sinha ◽  
Di Sun ◽  
...  
Keyword(s):  
Schiff Base ◽  
Electrical Property ◽  
Impedance Spectroscopy ◽  
Schottky Diode ◽  
X Ray ◽  
X Ray Crystallography ◽  
Water Chain ◽  
Schiff Base Compound ◽  
Base Compound

A flexible Schiff-base compound has been synthesized and structurally confirmed by X-ray crystallography. The compound behaves as a Schottky diode, as supported by the impedance spectroscopy.

scholarly journals 4-Chloro-2-[(4-chlorobenzylidene)amino]phenol

2012 ◽  
Vol 68 (6) ◽  
pp. o1696-o1696 ◽  
Author(s):  
Kürşat Efil ◽  
Fatih Şen ◽  
Yunus Bekdemir ◽  
Orhan Büyükgüngör
Keyword(s):  
Hydrogen Bond ◽  
Schiff Base ◽  
Double Bond ◽  
Dihedral Angle ◽  
One Dimensional ◽  
Compound C ◽  
Benzene Rings ◽  
Amino Phenol ◽  
Schiff Base Compound ◽  
Base Compound

In the title Schiff base compound, C13H9Cl2NO, the molecule displays an E conformation about the imine C=N double bond, with a dihedral angle of 8.09 (11)° between the two benzene rings. In the crystal, molecules are linked by a single O—H...O hydrogen bond, giving one-dimensional chains which extend along (100).

Synthesis, characterization, crystal structure, and theoretical studies on Schiff-base compound 6-[(5-Bromopyridin-2-yl)iminomethyl]phenol

2009 ◽  
Vol 21 (1) ◽  
pp. 153-157 ◽  
Author(s):  
Aliakbar Dehno Khalaji ◽  
Alireza Najafi Chermahini ◽  
Karla Fejfarova ◽  
Michal Dusek
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Theoretical Studies ◽  
Schiff Base Compound ◽  
Base Compound
Sign in / Sign up

Export Citation Format

Share Document