Influence of TiO2 on Selfclean Bio Coating

2013 ◽  
Vol 315 ◽  
pp. 399-403 ◽  
Author(s):  
Nurulsaidatulsyida Sulong ◽  
Anika Zafiah Mohd Rus
Keyword(s):  
Contact Angle ◽  
Organic Contaminants ◽  
Concrete Surface ◽  
Waste Cooking Oil ◽  
Water Repellent ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
The Difference ◽  
Micro Features ◽  
Coated Surfaces

Treatment on the exposed surface to the environmental attack was studied based on biopolymer coating from waste cooking oil doped with a superhydrophilic filler of Titanium Dioxide (TiO2), known as TOP. TOP was found to affect the physical properties of the coated concrete surface in a systematic way. Contact angle measurements are interpreted with respect to nanoand micro-features existing on the surface of the water repellent superhydrophilic filler filled bio-polymer composite coating. The smooth coated surfaces of polymer filled or doped with superhydrophobic filler shows the systematic increasing static Waste Contact Angle, WCA (θst) and revealed that polymer filled superhydrophobic fillers by only 2.0 % shows the ability to form superhydrophobicity property. Scanning Electron Microscope (SEM) pictures revealed the difference between the concrete surface roughness of concrete biopolymer with and without TOP coating is to provide self-cleaning concrete biopolymer coating based on two principal ways: (1) the development of surface coating of semiconducting photocatalytic superhydrophilic. (2) If such a superhydrophilic is illuminated by light, then grease, dirt and organic contaminants will be decomposed and can easily be swept away by rain.

Water Repellent Cellulose Nanofibers by Acetylation

2011 ◽  
Vol 332-334 ◽  
pp. 209-212 ◽  
Author(s):  
Alireza Shakeri ◽  
Mehdi Joonobi
Keyword(s):  
Contact Angle ◽  
Cellulose Nanofibers ◽  
Surface Characteristics ◽  
Water Repellent ◽  
High Pressure Homogenization ◽  
X Ray ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
Isolation Methods ◽  
Mechanical Isolation

Kenaf nanofibers (NF) were isolated from the kenaf pulp using mechanical isolation methods (refining with super grounding and high pressure homogenization). The kenaf NF were acetylated to produce hydrophobic NF. FTIR results displayed a successful acetylation of the NF. X-ray analysis exhibited that the acetylation process reduced the crystallinity of kenaf NF but also that isolation to NF leads to higher crystallinity than corresponding micro-sized fibers. The contact angle measurements indicated that the acetylation treatment changed the surface characteristics of the kenaf NF from hydrophilic to more hydrophobic.

scholarly journals Surface Free Energy Utilization to Evaluate Wettability of Hydrocolloid Suspension on Different Vegetable Epicarps

Coatings ◽  
2017 ◽  
Vol 8 (1) ◽  
pp. 16 ◽  
Author(s):  
Fernando Osorio ◽  
Gonzalo Valdés ◽  
Olivier Skurtys ◽  
Ricardo Andrade ◽  
Ricardo Villalobos-Carvajal ◽  
...  
Keyword(s):  
Contact Angle ◽  
Free Energy ◽  
Surface Free Energy ◽  
Hydroxypropyl Methylcellulose ◽  
Energy Utilization ◽  
Work Of Adhesion ◽  
Edible Coatings ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
The Difference

Surface free energy is an essential physicochemical property of a solid and it greatly influences the interactions between vegetable epicarps and coating suspensions. Wettability is the property of a solid surface to reduce the surface tension of a liquid in contact with it such that it spreads over the surface and wets it, resulting from intermolecular interactions when the two are brought together. The degree of wetting (wettability) is determined by an energy balance between adhesive and cohesive work. The spreading coefficient (Scf/food) is the difference between the work of adhesion and the work of cohesion. Surface wettability is measured by the contact angle, which is formed when a droplet of a liquid is placed on a surface. The objective of this work was to determine the effect of hydroxypropyl methylcellulose (HPMC), κ-carrageenan, glycerol, and cellulose nanofiber (CNF) concentrations on the wettability of edible coatings on banana and eggplant epicarps. Coating suspension wettability on both epicarps were evaluated by contact angle measurements. For the (Scf/food) values obtained, it can be concluded that the surfaces were partially wet by the suspensions. Scf/food on banana surface was influenced mainly by κ-carrageenan concentration, HPMC-glycerol, κ-carrageenan-CNF, and glycerol-CNF interactions. Thus, increasing κ-carrageenan concentrations within the working range led to a 17.7% decrease in Scf/banana values. Furthermore, a HPMC concentration of 3 g/100 g produced a 10.4% increase of the Scf/banana values. Finally, Scf/fruit values for banana epicarps were higher (~10%) than those obtained for eggplant epicarp, indicating that suspensions wetted more the banana than the eggplant surface.

Treatments on CDW Recycled Aggregates Surface Using Silane-Based Water Repellent

2015 ◽  
Vol 668 ◽  
pp. 197-206 ◽  
Author(s):  
Winnie Franco Santos ◽  
Marco Quattrone ◽  
Sergio Cirelli Angulo
Keyword(s):  
Contact Angle ◽  
Water Absorption ◽  
Apparent Contact Angle ◽  
Recycled Aggregates ◽  
Water Repellent ◽  
High Porosity ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
Different Types

This study aims to investigate the properties of CDW recycled aggregates using silane-based water repellent agent in three different types of treatments: (a) immersion; (b) sprinkling; and (c) dripping; in order to improve the reduces quality of the material due to the high porosity. Wettability and water absorption were determined by apparent contact angle measurements, water absorption after 24h of saturation (standard method) and recording the variation of submerged mass during 24 hs. All treatment allowed reducing the water absorption and its kinetic. The contact angle measurements confirmed the effectiveness of the treatment: the surface resulted always hydrophobic. Comparing the treatments, immersion gave the best result in terms of absolute results and in terms of variability of measurements.

scholarly journals EFFECT OF CHITOSAN FILM SURFACE STRUCTURE ON THE CONTACT ANGLE

2021 ◽  
Vol 26 ◽  
pp. 89-100
Author(s):  
Sylwia Jagodzińska ◽  
◽  
Beata Pałys ◽  
Dariusz Wawro ◽  
Keyword(s):  
Contact Angle ◽  
Sessile Drop ◽  
Chitosan Film ◽  
Film Surface ◽  
European Pharmacopoeia ◽  
Cellulose Films ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
Chitosan Films ◽  
The Difference

The aim of this study was to evaluate the influence of the surface microstructure of chitosan films on the contact angle. Films without plasticising additives made of chitosan or regenerated chitosan were selected for the tests. A sessile drop method based on the European Pharmacopoeia was used to determine the contact angle. Due to the method of film production, the contact angle measurements were made on both the top and bottom surfaces of the film. For chitosan or regenerated chitosan films, the method of preparation slightly affected the difference in wettability between the top and bottom of the films, as confirmed by scanning electron microscopy. On the other hand, the wettability of the top and bottom of cellulose films varied greatly depending on the side of the film. Both chitosan and cellulose films had a homogeneous structure. There were differences in the microstructure between the top and the bottom of the sample in the cellulose film, a factor that affected the contact angle and thus the wettability of the surface.

Wettability Determination by Equilibrium Contact Angle Measurements: Reservoir Rock- Connate Water System With Injection of CO2

2012 ◽  
Author(s):  
Narjes Shojaikaveh ◽  
Cas Berentsen ◽  
Susanne Eva Johanne Rudolph-Floter ◽  
Karl Heinz Wolf ◽  
William Richard Rossen
Keyword(s):  
Contact Angle ◽  
Water System ◽  
Reservoir Rock ◽  
Equilibrium Contact Angle ◽  
Connate Water ◽  
Angle Measurements ◽  
Contact Angle Measurements

Surface Wettability Enhances Osteoblast Adhesion on Silicon-Substituted Hydroxyapatite Thin Films

2007 ◽  
Vol 330-332 ◽  
pp. 877-880 ◽  
Author(s):  
E.S. Thian ◽  
J. Huang ◽  
Serena Best ◽  
Zoe H. Barber ◽  
William Bonfield
Keyword(s):  
Thin Films ◽  
Contact Angle ◽  
Actin Filaments ◽  
Culture Study ◽  
Cell Culture Study ◽  
Angle Measurements ◽  
Contact Angle Measurements ◽  
Osteoblast Adhesion ◽  
Lower Contact

Crystalline hydroxyapatite (HA) and 0.8 wt.% silicon-substituted HA (SiHA) thin films were produced using magnetron co-sputtering. These films were subjected to contact angle measurements and in vitro cell culture study using human osteoblast-like (HOB) cells. A wettability study showed that SiHA has a lower contact angle, and thus is more hydrophilic in nature, as compared to HA. Consequently, enhanced cell growth was observed on SiHA at all time-points. Furthermore, distinct and well-developed actin filaments could be seen within HOB cells on SiHA. Thus, this work demonstrated that the surface properties of the coating may be modified by the substitution of Si into the HA structure.

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