Study on Sulfur Compounds in the Gasoline

2013 ◽  
Vol 423-426 ◽  
pp. 2367-2371
Author(s):  
Shu Jun Liu ◽  
Hao Nan Xu ◽  
Kun Feng ◽  
Ying Wang
Keyword(s):  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Sulfur Compounds ◽  
Organic Sulfur Compounds ◽  
Volatile Organic ◽  
Effects Of Temperature ◽  
Chemiluminescence Detector ◽  
Temperature Time ◽  
Optimum Extraction ◽  
Sulfur Chemiluminescence Detector

A procedure to quantify volatile, organic sulfur compounds in gasoline was developed using solid-phase microextraction to preconcentrate the analyses followed by GC and detection with a sulfur chemiluminescence detector (SCD). The effects of temperature, time and PDMS fibers types on the extraction of gasoline has been investigated. The results show that a range of sulfur compounds were identified in gasoline. 75um PDMS, 30min, and 50°C were the optimum extraction conditions. Using the developed method can be used to identify gasoline residues in the fire.

scholarly journals Pollution status of volatile organic sulfur compounds causing odor in Xi River and factors influencing spatial distribution

2020 ◽  
Vol 20 (4) ◽  
pp. 1264-1270
Author(s):  
Xiang Tu ◽  
Shaohua Chen ◽  
Siyu Wang ◽  
Haiqing Liao ◽  
Xuejiao Deng
Keyword(s):  
Spatial Distribution ◽  
Sulfur Compounds ◽  
Organic Sulfur ◽  
Industrial Emissions ◽  
Diethyl Sulfide ◽  
Organic Sulfur Compounds ◽  
Factors Influencing ◽  
Pollution Status ◽  
Volatile Organic ◽  
Volatile Organic Sulfur Compounds

Abstract This study investigated the pollution status of volatile organic sulfur compounds (VOSCs) and the factors influencing their spatial distribution in the Xi River in Shenyang, China. A method for simultaneous determination of 14 VOSCs that cause odor in water samples was developed by using purge and trap coupled with gas chromatography and a flame photometric detector. The results indicated that each target compound could be identified from 15 sampling sites, and the total concentration of 14 VOSCs ranged from 2.575 to 52.981 μg L−1. Dimethyl sulfide (DMS) was the most important contaminant with an average concentration of 4.029 μg L−1, a detection rate of 93.33% and a variation coefficient of 0.72. The VOSCs were primarily distributed in suburban and rural sections, and the suburban section was the worst in regard to pollution by VOSCs. Dimethyl trisulfide was primarily distributed in urban and suburban sections of the Xi River due to industrial emissions. Ethanethiol, DMS, and ethyl methyl sulfide, which are typical by-products of microbial anaerobic decomposition from domestic wastewater, were found in abundance in the suburban section. Diethyl sulfide, diethyl disulfide, methyl propyl disulfide, and 1-propyl disulfide representing agricultural nonpoint source pollution were mostly distributed in the rural section.

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