Ash Composition Influence on Fusibility of Coal Ash

2013 ◽  
Vol 448-453 ◽  
pp. 3009-3012
Author(s):  
Na Gao ◽  
Sheng Hua Liu ◽  
Yan Hong Guo

The coal of Zichang was selected as the sample coal, the physical properties of the ash is analyzed with ICP-AES. The ash fusion temperature was researched by adding different basic oxide contents. The results show that the general trend is decrease firstly, and then increase when adding basic oxides. Blended ash fusion temperatures do not change linearly with blending ratios and ash fusion will decrease when adding the contents of CaO, Na2O and MgO, but the effect is different. Na2O is best and CaO is second. Mineral composition and type at addition oxides were determined by XRD analysis. Some combinations of component coals mineral produce eutectic minerals at high temperature;It can explain the reason of oxides decrease the ash fusion. Vitreous minerals are formed to explain increase the fusion temperature.

1987 ◽  
Vol 109 (3) ◽  
pp. 124-128 ◽  
Author(s):  
R. R. Rhinehart ◽  
A. A. Attar

This paper describes a thermodynamically based correlation between coal ash fusion temperatures and ash composition. A wide range of data from the literature was used to obtain the values of model parameters. A seven-parameter correlation is proposed which permits predicting the ash fusion temperature with a standard error ± 65°C or better.


2013 ◽  
Vol 295-298 ◽  
pp. 3094-3097 ◽  
Author(s):  
Han Xu Li ◽  
Zi Li Zhang ◽  
Yong Xin Tang

High-efficiency flux was developed to lower the ash fusion temperature of coal LQ and reduce the addition content in coal gasification process. The effect of high-efficiency flux on the coal ash melting temperature and mineral transformation were studied by ash fusion temperature detector and XRD (X-ray diffractometer) respectively in reducing atmosphere. Compared with limestone flux, the high-efficiency flux can decrease the coal ash melting temperature effectively with half addition content. The ash flow temperature (FT) of coal LQ can be lowered to less than 1350°C with the addition of 3% high-efficiency flux ,while limestone flux need to add more than 8% to reach to this temperature. With the high-efficiency flux added, cordierite, anorthite and Mg-Fe-Al oxide were formed at high temperature, which is the main reason to sharply decrease the ash fusion temperature.


2012 ◽  
Vol 260-261 ◽  
pp. 217-223 ◽  
Author(s):  
Wen Ni Li ◽  
Qing Hai Li ◽  
Yan Guo Zhang ◽  
Ai Hong Meng

Currently, GB(T212—1996), the coal industrial analysis standard, and ASTM(E870-82) , the American Society for Testing Material, are two main methods of studying basic characteristics of biomass in China. In this work, nine kinds of biomass are burned to ash under two standard temperatures, 815°C(GB) and 590°C(ASTM), whose contents are then measured , composition analysed through XRF(X-ray fluorescence)and fusion temperatures tested by 5E-AFⅢ intelligent ash fusion temperature tester. As can be seen in the tests, biomass produced under different ashing temperatures differs in ash content and composition, and the variation of ash composition further contributes to the variation of ash fusion temperatures. The results of the experiments indicate that, ashing temperatures have a significant influence on ash content. The effect of ashing temperatures on ash composition tends to be higher in biomass with higher content of the element K. As with biomass with high contents of K and Ca, ash fusion temperatures are sensitive to the variation of ashing temperatures. As a result, when dealing with biomass of this kind, lower ashing temperatures should be chosen.


2012 ◽  
Vol 512-515 ◽  
pp. 2147-2151
Author(s):  
Feng Hai Li ◽  
Jie Jie Huang ◽  
Yi Tian Fang ◽  
Ming Jie Ma ◽  
Yang Wang

Fusion characteristics of ash residues from Xiaolongtan lignite pressurized fluidized-bed gasification were investigated with ash fusion point detector and sintering temperature analyzer. The results show that the sintering temperature (Ts) and ash fusion temperature (AFT) of three ashes residues decrease from gangue ashes to agglomerate to slag, which result from the differences of mineral type and content in three ash residues, and the decrease of the total basic constituents increases the AFT. The formations of three ash residues during gasification are the interactions among mineral matter and their transformations under high temperature.


2016 ◽  
Vol 40 ◽  
pp. 05010 ◽  
Author(s):  
Suzhen Miao ◽  
Qingyin Jiang ◽  
Hua Zhou ◽  
Jia Shi ◽  
Zhikai Cao

1975 ◽  
Vol 97 (3) ◽  
pp. 395-403 ◽  
Author(s):  
E. C. Winegartner ◽  
B. T. Rhodes

Regression analysis is used to develop equations for calculating fusion temperatures of coal ash from chemical composition, based on 1250 analyses of ash from both eastern and western coal. Standard errors for the equations are generally less than 50°F (27°C), which is the analytical tolerance of the ash fusion temperature measurements. Equations are given for eastern, western, and combined eastern and western coals. These equations: (1) provide a technique for calculating ash fusion temperatures from the chemical composition of the ash; (2) provide a method for calculating the ash fusion properties of coal blends; and (3) provide an improved understanding of the effect, significance, and interactions of ash elements with respect to the thermal properties of coal ash.


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