Polymer-Based Fluidic Devices Integrated with Perforated Conical Nanopores in Freestanding Polymer Membranes

2015 ◽  
Vol 752-753 ◽  
pp. 217-220
Author(s):  
Jun Seo Choi ◽  
Sung Gook Park

Although nanoimprint lithography (NIL) can successfully fabricate structures down to 10 nm [1], it is difficult to produce perforated pores with diameters less than 100 nm in freestanding polymer membranes. Since it requires molding using a stamp with extremely high aspect ratio to achieve high mechanical stability for the membrane fully released from a substrate. We utilized silicon microneedle structures as an imprinting mold that overcomes these issues. Also, pressed self-perfection (PSP) process was employed after nanoimprinting to further reduce the pore size. Additionally, the membranes were integrated with microfluidic devices to measure current-voltage curves in order to determine pore size indirectly.

Author(s):  
Junseo Choi ◽  
Sunggook Park

This study presents a stable and flexible method for fabricating a free-standing polymer membrane with perforated micro- and nanopores using an imprint lithography combined with a pressed self-perfection method and a sacrificial layer technique. For the fabrication, micropores were initially patterned on a double resist layer: the upper SU-8 resist layer as an active membrane layer and the lower life-off resist used as a sacrificial layer. The membrane with micropores was then pressed with a flat quartz wafer to reduce pore size down to sub-micrometer. Finally, a free-standing SU-8 membrane with perforated micro- and nanopores was successfully lifted-off from the substrate by dissolving the sacrificial layer.


MRS Advances ◽  
2016 ◽  
Vol 1 (28) ◽  
pp. 2085-2090 ◽  
Author(s):  
Khadija Yazda ◽  
Sophie Roman ◽  
Saïd Tahir ◽  
François Henn ◽  
Vincent Jourdain

ABSTRACTStudying the transport of ions through single-walled carbon nanotubes (SWCNTs) necessitate the fabrication of a fluidic setup integrating carbon nanotubes. In this article, we report on the development of a simple fabrication protocol of SWCNTs fluidic devices. This protocol allows an excellent control of the system features and of the experimental conditions compared with previously published protocols. Our protocol based on the use of the popular SU-8, the preferred photoresist for the fabrication of high-aspect-ratio patterns, allows one to prepare sealed microfluidic devices incorporating one or several tens of individual carbon nanotubes of length between 20 and 80 µm.


2021 ◽  
pp. 296-302
Author(s):  
Ryosuke Hirota ◽  
Makoto Emori ◽  
Yoshinori Terashima ◽  
Kousuke Iba ◽  
Noriyuki Iesato ◽  
...  

We present the case of a 15-year-old girl. Two months after becoming aware of pain, she was diagnosed with a sacral tumor and referred to our department. She was diagnosed with a sacral Ewing’s sarcoma; after chemotherapy, it was determined that the tumor could be resected, so surgical treatment was performed. The sacrum and ilium were partially resected at the lower end of S1, and the lumbar vertebrae and pelvis were fixed with a pedicle screw and two iliac screws on each side of L3, and the sacral resection was reconstructed with a tibial strut allograft. No tumor recurrence or metastasis has been observed 1 year postoperatively. She developed bladder and rectal dysfunction, but she remained independent in activities of daily living and her daily life was not limited. The bone fusion in the reconstructed area confirmed the lack of instrumentation looseness. Surgical treatment for sacral Ewing’s sarcoma was performed to cure the patient. We believe that the tibial allograft contributed to the patient’s ability to walk on her own due to its high mechanical stability. Postoperative bone healing was observed with the same material, suggesting that the tibial allograft is useful for similar procedures.


SPE Journal ◽  
2021 ◽  
pp. 1-18 ◽  
Author(s):  
Abdulrauf Rasheed Adebayo

Summary Lateral propagation of foam in heterogeneous reservoirs, where pore geometries vary laterally, depends on the roles of pore geometries on the foam properties. In this paper, the pore attributes of 12 different rock samples were characterized in terms of porosity, permeability, pore shape, pore size, throat size, aspect ratio, coordination number, and log mean of surface relaxation times (T2LM). These were measured from gas porosimeter and permeameter, X-ray microcomputed tomography (CT)-basedpore-network models, thin-section photomicrographs, and nuclear magnetic resonance (NMR) surface relaxometry. The samples have a wide range of porosity: 12 to 29%; permeability: 1 to 5,000 md; average pore size: 3.7 to 9 µm; average throat size: 2.4 to 8 µm; average aspect ratio: 1 to 1.7; average coordination number: 2.6 to 5.2; and T2LM: 9.4 to 740 ms. Nitrogen foam flow experiments (without oil) were then conducted on each rock sample using a specialized coreflood apparatus. A graphical analysis of the coreflood data was used to estimate the total saturation of trapped foam (10 to 66%), flowing foam (3 to 14%), and apparent viscosity of foam (3.2 to 73 cp). Trapped foam saturation and apparent viscosity values were then correlated with each of the measured pore attributes. The results revealed that all pore attributes, except aspect ratio, have positive correlations with foam trapping and apparent viscosity. The best correlation with trapped foam saturation was obtained when the most influential pore attributes (pore size, throat size, aspect ratio, and coordination number) were combined into a single mathematical function. Foam apparent viscosity also appears to be mostly influenced by trapped foam saturation, permeability, and coordination number of pore systems. Trapping is also likely enhanced by the presence of fenestral or channel pores. Furthermore, the shape and angularity of pores seem to facilitate snap-off and trapping of foam, because rock samples with angular pores trapped the highest foam saturation compared with other samples with rounded and subrounded pores. It was also shown that the correlation between trapped foam saturation (and foam apparent viscosity) and the absolute permeability of porous media may reverse at some high-permeability values (greater than several darcies), when one or both of the following conditions exist: (1) The aspect ratio of a lower-permeability porous medium is lower than that of a higher-permeability porous medium, and (2) the coordination number of a lower-permeability porous medium is higher than that of a higher-permeability porous medium. Finally, T2LM showed a good correlation with foam trapping, making NMR logging a prospective tool for pre-evaluating foam performance in targeted reservoir sections.


2007 ◽  
Vol 7 (2) ◽  
pp. 668-672 ◽  
Author(s):  
Bo Chi ◽  
Erick S. Victorio ◽  
Tetsuro Jin

TiO2-based titanate nanotube film was directly synthesized by hydrothermal treatment of Ti substrate in NaOH solution. The prepared high aspect ratio nanotubes have diameter of 10nm and pore size of 5 nm with length of several microns. The nanotubes show the same structure and component characteristics as the nanotubes prepared through hydrothermal treatment of TiO2. Other nanostructured titanate as oriented nanofiber film and translucent film were also prepared by adjusting the hydrothermal conditions. The formation mechanism of nanostructured titanate was discussed.


2018 ◽  
Vol 20 (35) ◽  
pp. 22674-22680 ◽  
Author(s):  
Melissabye Gunnoo ◽  
Pierre-André Cazade ◽  
Adam Orlowski ◽  
Mateusz Chwastyk ◽  
Haipei Liu ◽  
...  

Cellulosome nanomachines utilise binding specificity and high mechanical stability in breaking down cellulose.


Sign in / Sign up

Export Citation Format

Share Document