Biodegradable Oph-POSS/Poly(Lactic Acid) Nanocomposites: Morphology, Thermal Stability and Degradation Property

2015 ◽  
Vol 1120-1121 ◽  
pp. 352-356 ◽  
Author(s):  
Jie Sun ◽  
Qiang Qiang Zhao ◽  
Zheng Yan Cao ◽  
Hai Ning Lv ◽  
Cheng Qun Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Degradation Mechanism ◽  
Poly Lactic Acid ◽  
Surface Erosion ◽  
Solution Casting ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Biodegradation Rate ◽  
Casting Method ◽  
Mass Fractions ◽  
Solution Casting Method

The purpose of this work was to produce nanocomposites of polylactic acid with oph-POSS (octaphenyl-Polyhedral Oligomeric Silsesquioxanes)-based biodegradable polyester and study morphology, thermal stability and degradation property. Oph-POSS was synthesized via limited-hydrolytic condensation of phenyl trimethoxysilane catalyzed by tetramethylammonium hydroxide. By adding different mass fractions of oph-POSS into the PLA matrix, oph-POSS/PLA nanocomposites were successfully prepared by the solution casting method using chloroform as solvent. SEM(scanning electron microscopy) observations indicated that oph-POSS were homogeneously dispersed in the PLA matrix. The biodegradation rate of oph-POSS/PLA composites was higher than that of neat PLA, moreover, the degradations of neat PLA and oph-POSS/PLA composites underwent the surface erosion mechanism. It was found that the existence of oph-POSS enhanced thermal stability slightly of nanocomposites relative to neat PLA; however, the thermal degradation mechanism of PLA remained unchanged.

Ternary hybrid (SPEEK/SPVdF-HFP/GO) based membrane electrolyte for the applications of fuel cells: profile of improved mechanical strength, thermal stability and proton conductivity

RSC Advances ◽  
2016 ◽  
Vol 6 (110) ◽  
pp. 108851-108863 ◽  
Author(s):  
Mohanraj Vinothkannan ◽  
Ae Rhan Kim ◽  
Kee Suk Nahm ◽  
Dong Jin Yoo
Keyword(s):  
Thermal Stability ◽  
Polyvinylidene Fluoride ◽  
Hybrid Membranes ◽  
Solution Casting ◽  
Casting Method ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Solution Casting Method ◽  
Ether Ketone ◽  
Sulfonated Poly

Ternary hybrid membranes composed of sulfonated (poly ether ether ketone) (SPEEK), sulfonated polyvinylidene fluoride-co-hexafluoropropylene (SPVdF-HFP) and 1, 3, 5 or 7 wt% graphene oxide (GO) were fabricated using a facile solution casting method.

scholarly journals Enhanced mechanical, thermal, and UV-shielding properties of poly(vinyl alcohol)/metal–organic framework nanocomposites

RSC Advances ◽  
2018 ◽  
Vol 8 (67) ◽  
pp. 38681-38688 ◽  
Author(s):  
Yibo Dai ◽  
Qun Tang ◽  
Ziang Zhang ◽  
Caili Yu ◽  
Heping Li ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Vinyl Alcohol ◽  
Metal Organic Framework ◽  
Poly Vinyl Alcohol ◽  
Solution Casting ◽  
Casting Method ◽  
Uv Shielding ◽  
Metal Organic ◽  
Solution Casting Method ◽  
Shielding Properties

PVA/HKUST-1 nanocomposites prepared by a simple solution casting method displayed significantly enhanced thermal stability, mechanical and UV-shielding properties.

Thermal degradation kinetics of Opuntia Ficus Indica flour and talc-filled poly (lactic acid) hybrid biocomposites by TGA analysis

2021 ◽  
pp. 002199832110082
Author(s):  
Azzeddine Gharsallah ◽  
Abdelheq Layachi ◽  
Ali Louaer ◽  
Hamid Satha
Keyword(s):  
Thermal Stability ◽  
Lactic Acid ◽  
Thermal Degradation ◽  
Degradation Kinetics ◽  
Degradation Mechanism ◽  
Melt Processing ◽  
Thermal Degradation Kinetics ◽  
Poly Lactic Acid ◽  
Opuntia Ficus Indica ◽  
Model Free

This paper reports the effect of lignocellulosic flour and talc powder on the thermal degradation behavior of poly (lactic acid) (PLA) by thermogravimetric analysis (TGA). Lignocellulosic flour was obtained by grinding Opuntia Ficus Indica cladodes. PLA/talc/ Opuntia Ficus Indica flour (OFI-F) biocomposites were prepared by melt processing and characterized using Wide-angle X-ray scattering (WAXS) and Scanning Electron Microscope (SEM). The thermal degradation of neat PLA and its biocomposites can be identified quantitatively by solid-state kinetics models. Thermal degradation results on biocomposites compared to neat PLA show that talc particles at 10 wt % into the PLA matrix have a minor impact on the thermal stability of biocomposites. Loading OFI-F and Talc/OFI-F mixture into the PLA matrix results in a decrease in the maximum degradation temperature, which means that the biocomposites have lower thermal stability. The activation energies (Ea) calculated by the Flynn Wall Ozawa (FWO) and Kissinger Akahira Sunose (KAS) model-free approaches and by model-fitting (Kissinger method and Coats-Redfern method) are in good agreement with one another. In addition, in this work, the degradation mechanism of biocomposites is proposed using Coats-Redfern and Criado methods.

scholarly journals Fabrication and characterization of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) modified with nano-montmorillonite biocomposite

e-Polymers ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 038-046
Author(s):  
Xu Yan ◽  
Wanru Zhou ◽  
Xiaojun Ma ◽  
Binqing Sun
Keyword(s):  
Thermal Stability ◽  
Oxygen Permeability ◽  
Water Vapor Permeability ◽  
Barrier Properties ◽  
Nucleating Agent ◽  
Vapor Permeability ◽  
Casting Method ◽  
Increasing Trend ◽  
Solution Casting Method

Abstract In this study, a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) modified with nano-montmorillonite biocomposite (MMT/PHBH) was fabricated by solution-casting method. The results showed that the addition of MMT increased the crystallinity and the number of spherulites, which indicated that MMT was an effective nucleating agent for PHBH. The maximum decomposition peak of the biocomposites moved to a high temperature and residue presented an increasing trend. The biocomposites showed the best thermal stability at 1 wt% MMT. Compared with PHBH, 182.5% and 111.2% improvement in elastic modulus and tensile strength were obtained, respectively. Moreover, the oxygen permeability coefficient and the water vapor permeability of MMT/PHBH biocomposites decreased by 43.9% and 6.9%, respectively. It was also found that the simultaneous enhancements on the crystallizing, thermal stability, mechanical, and barrier properties of biocomposites were mainly caused by the formation of intercalated structure between PHBH and MMT.

scholarly journals The Effect of Stereocomplex Polylactide Particles on the Stereocomplexation of High Molecular Weight Polylactide Blends

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 2018
Author(s):  
Muhammad Samsuri ◽  
Ihsan Iswaldi ◽  
Purba Purnama
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
High Molecular Weight ◽  
Nucleating Agent ◽  
Solution Casting ◽  
Casting Method ◽  
Crystalline Fraction ◽  
Crystalline Structures ◽  
Solution Casting Method

Stereocomplexation is one of several approaches for improving polylactide (PLA) properties. The high molecular weight of poly L-lactide (PLLA) and poly D-lactide (PDLA) homopolymers are a constraint during the formation of stereocomplex PLAs (s-PLAs). The presence of s-PLA particles in PLA PLLA/PDLA blends can initiate the formation of s-PLA crystalline structures. We used the solution casting method to study the utilization of s-PLA materials from high molecular weight PLLA/PDLA blends for increasing s-PLA formation. The s-PLA particles initiated the formation of high molecular weight PLLA/PDLA blends, obtaining 49.13% s-PLA and 44.34% of the total crystalline fraction. In addition, the mechanical properties were enhanced through s-PLA crystalline formation and the increasing of total crystallinity of the PLLA/PDLA blends. The s-PLA particles supported initiation for s-PLA formation and acted as a nucleating agent for PLA homopolymers. These unique characteristics of s-PLA particles show potential to overcome the molecular weight limitation for stereocomplexation of PLLA/PDLA blends.

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