Fabrication and Mechanical Characterization of Carbon Nanotubes-Enhanced Epoxy

2010 ◽  
Vol 168-170 ◽  
pp. 1102-1106
Author(s):  
Haydar Faleh ◽  
Lu Ming Shen ◽  
Riadh Al Mahaidi

Owing to its outstanding characteristics in good affinity to heterogeneous materials, corrosion resistance and on-the-spot processing capability, epoxy has been widely used as adhesives in retrofitting structures with carbon fibre reinforced polymer (CFRP). In this study, different weight fractions of multi-walled carbon nanotubes (MWCNTs) will be dispersed into epoxy to produce toughened adhesives that can improve the CFRP/structure bonding performance. The preliminary results indicate that adding 2% MWCNTs to Araldite-420 increase its ultimate strength by 17% and its elastic modulus by 14%. Ultrasonic mixing may increase Sikadur-30’s elastic modulus but reduce its strength and ductility regardless of the MWCNTs concentration. The mechanism of MWCNTs infusion effects on the mechanical properties of epoxy is also examined using SEM.

Author(s):  
Dhiraj Kumar ◽  
Kalyan Kumar Singh

Laser machining of carbon fibre reinforced polymer composites is a challenging task due to a significant difference between physical and thermal properties of the constituent materials, i.e. polymer matrix and carbon fibres. This results in extended heat-affected zone (HAZ), taper kerf and poor surface finishing. This paper focuses on an investigation, attempting to minimise the divergence in the decomposition temperature of carbon fibres and epoxy resin by adding multi-walled carbon nanotubes in polymer matrix as a secondary reinforcement. High thermal conductivity of multi-walled carbon nanotubes increases the thermal diffusivity of polymer matrix, which in turn reduces the matrix recession. In addition, laser power and scan speed was also considered as an input parameter and their influence on output responses such as HAZ, taper angle and surface roughness has been studied. To analyse the effect of multi-walled carbon nanotubes on the resultant thermal damage, an innovative technique, i.e. scanning acoustic microscopy was used. This technique provides a ply-by-ply damage analysis. C-scans of the top and bottom surface of the machined holes in the composite were also carried out. Further, micrographs of the holes were taken to analyse the quality of the holes using field-emission scanning electron microscope. The obtained results indicated that HAZ, taper angle and surface roughness of holes decreased by ∼30%, ∼47% and ∼43%, respectively, with 1.5 wt% multi-walled carbon nanotubes doped carbon fibre reinforced polymer laminates, when compared with the results obtained from experiments with neat carbon fibre reinforced polymer composite laminates.


2019 ◽  
Vol 827 ◽  
pp. 458-463
Author(s):  
Sotirios A. Grammatikos ◽  
Morten Melby Dahl ◽  
Vegar Salin Brøndbo ◽  
Angela Daniela La Rosa

This paper reports an experimental investigation on embedded polyurethane (PUR) electrodes into a carbon fibre reinforced polymer (CFRP) composite to enable the dependable use of composites as a piezoresistive sensors, among other uses, and pave the way towards advanced structural health monitoring (SHM). To be able to use polyurethane as electrodes, multi-walled carbon nanotubes (MWCNTs) were used as fillers in PUR to increase its electrical conductivity. Various concentrations of MWCNTs in PUR were tested to reveal the optimum synthesis. This was conducted by performing mechanical and electrical property tests of the electrodes, studying the adhesion capabilities between composite matrix and polyurethane electrode and carrying out load-unload testing where the composite acts as a strain sensor.


Author(s):  
KK Singh ◽  
Anand Gaurav

This study reports about the dispersibility of short, straight and pristine multi-walled carbon nanotubes (pCNTs) in epoxy and their effectiveness on the mechanical properties of three-phased GF/epoxy/pCNT laminates. These nanotubes were produced by arc discharge method and had an average aspect ratio (l/d) of 100. Glass fibre-reinforced polymer samples with four different weight fractions of these nanotubes (0.5, 1.0, 1.5 and 2.0 wt.% of the total matrix system) were fabricated and tested for their thermo-mechanical and mechanical properties. These carbon nanotubes with small aspect ratio contributed well to the strengthening mechanism due to their homogeneous dispersion. Fractography revealed that these nanotubes formed aligned arrays that minimized entanglements between the individual tubes, thus leading to lesser agglomerates up to 1.5 wt.% of carbon nanotube loading. However, the samples modified with 2.0 wt.% of nanotubes had lesser individual tubes and more of their aggregates. Unmodified glass fibre-reinforced polymer samples had a glass transition temperature (Tg) of 139.2℃, whereas addition of 1.5 wt.% of multi-walled carbon nanotubes increased the same to 160℃. Similarly, these specimens witnessed about 21% and 34% enhancement in tensile and flexure strength over the control samples, respectively. However, these trends dropped at 2.0 wt.% carbon nanotube loading owing to nanotubes aggregation but were higher than those of the neat epoxy composite. Samples containing carbon nanotubes witnessed higher fatigue life which proves that multi-walled carbon nanotubes with smaller aspect ratio are capable of obstructing fatigue crack growth.


2012 ◽  
Vol 18 (S2) ◽  
pp. 1316-1317
Author(s):  
M.J. Guinel ◽  
N. Brodusch ◽  
R. Gauvin ◽  
Y. Verde-Gomez ◽  
B. Escobar-Morales

Extended abstract of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.


Carbon ◽  
2011 ◽  
Vol 49 (1) ◽  
pp. 24-36 ◽  
Author(s):  
Kevin A. Wepasnick ◽  
Billy A. Smith ◽  
Kaitlin E. Schrote ◽  
Hannah K. Wilson ◽  
Stephen R. Diegelmann ◽  
...  

Author(s):  
Huynh Anh Hoang ◽  
Huynh Quyen

Since the end of the 20th century, nanomaterials such as carbon nanotubes (CNTs) have been considered as one of the greatest achievements in the field of material science. Nowadays, further research on CNTs is still being conducted to unfold the full potential of this material. Generally, CNTs production methods have been extensively studied, specifically on CNTs synthesis route via liquefied hydrocarbon gas in the presence of a catalyst. From the synthesized material, further investigation including characterization and investigation of this nano size system’s effects on the physics, chemical, mechanical rules applied to macroscopic (bulk materials) and microscopic systems (atoms, molecules). In this present work, we demonstrated the research results of the synthesis of nano-carbon materials from a liquefied hydrocarbon gas (Liquefied Petroleum Gas: LPG) and its application to red phenol absorption in the liquid phase. CNTs used in this study were synthesized by chemical vapor deposition (CVD) method with Fe /ℽ-Al2O3 as the catalyst. The research results demonstrated that CNTs synthesized from LPG in this work were reported to be multi-walled tubes (MWCNTs: Multi-Walled Carbon Nanotubes) with physical characteristics including average internal and external diameters were of 6 nm and 17 nm, respectively. The measured specific surface suggested by BET data was 200 m2/g. The experimental study of red phenol adsorption by MWCNTs showed that the adsorption process followed both Freundlich and Langmuir isotherm adsorption models with the maximum monolayer adsorption capacity of 47.2 mg/g. The research results again showed that it was possible to synthesize MWCNTs from hydrocarbon gas sources via the CVD method by utilizing catalysts. Additionally, red phenol absorption via such material had shown to follow both Freundlich and Langmuir isotherm model, which allow further characterization of this material using Raman, EDX, SEM, TEM, BET, in order to extend the library database on the characterization of the reported synthesized material.


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