Structural Characteristics and Dielectric Properties of Nd-Doped SrTiO3 Ceramics by Introducing Ti Vacancies for Valence Compensation

2011 ◽  
Vol 284-286 ◽  
pp. 1435-1441 ◽  
Author(s):  
Zong Yang Shen ◽  
Yue Ming Li ◽  
Zhu Mei Wang ◽  
Yan Hong ◽  
Run Hua Liao

By introducing Ti vacancies for valence compensation, Nd-doped SrTiO3 ceramics yielding the formula NdxSr1-xTi1-x/4O3 (0≤x≤0.200) were successfully prepared by solid state reaction route in air. All the ceramics had single perovskite structure indexed by XRD profiles, while the symmetry changed from cubic to tetragonal with increasing x value. The grain size markedly decreased from ~30 μm for un-doped SrTiO3 ceramics to ~1 μm for NdxSr1-xTi1-x/4O3 ceramics with x=0.024, which was observed by scanning electron microscopy (SEM). The dielectric properties were measured at 1 kHz in ambient temperature. The dielectric constant was found to be leading to a maximum value of 5410 for as-sintered sample with x=0.104. The breakdown strength of all NdxSr1-xTi1-x/4O3 samples was examined to be higher than 10 kV/mm. These results indicated that Nd-doped SrTiO3 ceramics could be used to fabricate high voltage capacitors with enhanced energy storage density.

2010 ◽  
Vol 654-656 ◽  
pp. 2045-2048 ◽  
Author(s):  
Yi Qiu Li ◽  
Han Xing Liu ◽  
Zhong Hua Yao ◽  
Jing Xu ◽  
Yun Jiang Cui ◽  
...  

The energy storage density of (1-x) BaTiO3 – x Ba(Mg1/3Nb2/3)O3 (x = 0, 0.1, 0.2, 0.3) ceramics was investigated. The microstructure of samples was characterized by scanning electron microscopy (SEM). The energy storage density was calculated from the P-E hysteresis loops measured at room temperature. Experimental results show that the energy storage density of 0.9 BaTiO3 – 0.1 Ba(Mg1/3Nb2/3)O3 ceramics is highest among all compositions. At 15.8kV/mm electric field, the energy storage density of the sample can reach up to 1.07J/cm3, which is about 1.5 times higher than pure BaTiO3. The improvement of the energy density can be due to two factors: one is the improved breakdown strength caused by the optimized microstructure, the other is the decreased remnant polarization. This result indicates that bulk 0.9 BaTiO3 – 0.1 Ba(Mg1/3Nb2/3)O3 ceramic has advantages compared with pure BaTiO3 ceramic for energy storage applications, and with further improvements in microstructure and reduction of sintering temperature, could be a good candidate for energy storage capacitors.


2016 ◽  
Vol 45 (29) ◽  
pp. 11807-11816 ◽  
Author(s):  
Yonggui Zhao ◽  
Ping Zhang

Zn3(Nb1−xTax)2O8 (x = 0.02–0.10) ceramics were prepared via a solid-state reaction route and the dependence of their microwave dielectric properties on their structural characteristics were investigated.


2021 ◽  
Author(s):  
Mehak Arora ◽  
Shubhpreet Kaur ◽  
Kanika aggarwal ◽  
Sunil Kumar ◽  
Parambir Singh Malhi ◽  
...  

Abstract Present work investigates the detailed multiferroic properties of Pb1 − xSmxTi1−xFexO3, (x = 0.21, 0.22, 0.23, 0.24 and 0.25) synthesize through solid state reaction route. The structural, dielectric, ferroelectric and magnetic properties were measured. A sincere study is carried out to detect the magneto-electric coupling in all the samples through magneto-dielectric, magnetization after electric poling and magneto-pe response. The maximum value of coupling coefficient (γ) and magneto-dielectric response (MDR) of sample x = 0.24 has shown by magneto-dielectric properties and magnetization after electric poling whereas magneto-pe has shown that all the samples possess multiferroic nature.


Author(s):  
Muhammad Qusyairie Saari ◽  
Julie Juliewatty Mohamed ◽  
Muhammad Azwadi Sulaiman ◽  
Mohd Fariz Abd Rahman ◽  
Zainal Arifin Ahmad ◽  
...  

2021 ◽  
pp. 2100116
Author(s):  
Qi‐Kun Feng ◽  
Jiang‐Bo Ping ◽  
Jing Zhu ◽  
Jia‐Yao Pei ◽  
Lei Huang ◽  
...  

2010 ◽  
Vol 24 (12) ◽  
pp. 1267-1273 ◽  
Author(s):  
RAMAN KASHYAP ◽  
TANUJ DHAWAN ◽  
PRIKSHIT GAUTAM ◽  
O. P. THAKUR ◽  
N. C. MEHRA ◽  
...  

CaCu 3 Ti 4 O 12 ( CCTO ) ceramics were prepared by the solid-state reaction route. Effect of sintering time was studied on the polarization (P) versus electric field (E) behavior. Unlike conventional ferroelectric hysteresis loop, PE hysteresis behavior in CCTO ceramics was observed to exhibit ferroelectric-like loop where polarization does not saturate but gives a maximum value. Remnant polarization and maximum polarization was observed to increase with sintering time. Current (I)–voltage (V) characteristics shows a nonlinear behavior making them useful for varistor applications. Coefficient of non-linearity (α) is also found to depend on sintering duration.


RSC Advances ◽  
2017 ◽  
Vol 7 (47) ◽  
pp. 29306-29311 ◽  
Author(s):  
Yong You ◽  
Weihua Han ◽  
Ling Tu ◽  
Yajie Wang ◽  
Renbo Wei ◽  
...  

The surface of BaTiO3 was modified with CPEN and NH2-CuPc, and the obtained CPEN-f-BT@CuPc reinforced the performance of PEN. The fabricated PEN-based nanocomposite shows stable dielectric properties and energy storage density from RT to 160 °C.


2015 ◽  
Vol 41 (10) ◽  
pp. 13582-13588 ◽  
Author(s):  
M. Wang ◽  
W.L. Li ◽  
Y. Feng ◽  
Y.F. Hou ◽  
T.D. Zhang ◽  
...  

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