Synthesis and Light-Emtting Diodes Properties of Two New Fluorene Based Copolymers

2011 ◽  
Vol 295-297 ◽  
pp. 274-277 ◽  
Author(s):  
Jian Hua Huang ◽  
Xiang Hui Ye ◽  
Chuan Lang Zhan ◽  
Gui Yu ◽  
Yun Qi Liu ◽  
...  

Two new conjugated copolymers, PFPh and PFTDP, comprised of alternating 9,9-dioctylfluorene and phthalimide (Ph) or thieno [3, 4-c] pyrrole-4,6-dione (TPD) have been synthesized via Suzuki coupling reaction. Polymeric light-emitting diodes (PLED) were fabricated with an ITO/PEDOT: PSS/PVK/Polymer/BCP/Alq/Ca:Ag configuration. The maximum brightness and maximum current efficiency of PLED are 2600cd/m2and 2.52 cd/A for PFPh, and 2300cd/m2and 1.13 cd/A for PFTDP, respectively, which are significantly improved compared with the reported alternating fluorene-unsubstituted phenylene/thiophene systems.

Micromachines ◽  
2019 ◽  
Vol 10 (7) ◽  
pp. 459 ◽  
Author(s):  
Yuanming Zhou ◽  
Sijiong Mei ◽  
Dongwei Sun ◽  
Neng Liu ◽  
Wuxing Shi ◽  
...  

High efficiency perovskite light-emitting diodes (PeLEDs) using PEDOT:PSS/MoO3-ammonia composite hole transport layers (HTLs) with different MoO3-ammonia ratios were prepared and characterized. For PeLEDs with one-step spin-coated CH3NH3PbBr3 emitter, an optimal MoO3-ammonia volume ratio (0.02) in PEDOT:PSS/MoO3-ammonia composite HTL presented a maximum luminance of 1082 cd/m2 and maximum current efficiency of 0.7 cd/A, which are 82% and 94% higher than those of the control device using pure PEDOT:PSS HTL respectively. It can be explained by that the optimized amount of MoO3-ammonia in the composite HTLs cannot only facilitate hole injection into CH3NH3PbBr3 through reducing the contact barrier, but also suppress the exciton quenching at the HTL/CH3NH3PbBr3 interface. Three-step spin coating method was further used to obtain uniform and dense CH3NH3PbBr3 films, which lead to a maximum luminance of 5044 cd/m2 and maximum current efficiency of 3.12 cd/A, showing enhancement of 750% and 767% compared with the control device respectively. The significantly improved efficiency of PeLEDs using three-step spin-coated CH3NH3PbBr3 film and an optimum PEDOT:PSS/MoO3-ammonia composite HTL can be explained by the enhanced carrier recombination through better hole injection and film morphology optimization, as well as the reduced exciton quenching at HTL/CH3NH3PbBr3 interface. These results present a promising strategy for the device engineering of high efficiency PeLEDs.


2019 ◽  
Vol 3 (5) ◽  
pp. 867-873 ◽  
Author(s):  
Yihan Chen ◽  
Xiaojing Li ◽  
Nengquan Li ◽  
Yiwu Quan ◽  
Yixiang Cheng ◽  
...  

Circularly polarized organic light-emitting diodes were fabricated by using salen-Zn(ii) complex enantiomers (R-/S-ZnL) as the emitting layer, obtaining 1000 cd m−2, 0.181 cd A−1 and 0.074 lm W−1 for the maximum brightness, current efficiency and power efficiency. With an electroluminescence dissymmetry factor of up to +0.05/−0.05.


2020 ◽  
Vol 20 (8) ◽  
pp. 4652-4656
Author(s):  
Junyoung Moon ◽  
Jinho Lee ◽  
Ki Ju Kim ◽  
Hakjun Lee ◽  
Young Kwan Kim ◽  
...  

In this study, we designed and synthesized two blue fluorescence materials using phenylanthracenesubstituted-indenoquinoline derivatives by Suzuki coupling reaction for organic light-emitting diodes (OLEDs). In order to study their electroluminescent properties, we fabricated the OLED devices using these two materials as emissive layer (EML) with the following sequence: indium-tin-oxide (ITO, 180 nm)/4,4′,4″-tris[2-naphthyl(phenyl)-amino]triphenylamine (2-TNATA, 30 nm)/N,N′-diphenyl-N,N′-(2-napthyl)-(1,1′-phenyl)-4,4′-diamine (NPB, 20 nm)/Blue emitting materials (20 nm)/4,7-Diphenyl-1,10-phenanthroline (Bphen, 30 nm)/lithium quinolate (Liq, 2 nm)/Al (100 nm). In particular, a device using 11,11-dimethyl-3-(10-phenylanthracen-9-yl)-11H-Indeno[1,2-b]quinoline in emitting layer showed luminous efficiency, power efficiency, and external quantum efficiency of 2.18 cd/A, 1.10 lm/W, 2.20% at 20 mA/cm2, respectively, with Commission Internationale d’Énclairage (CIE) coordinates of (0.15, 0.11) at 8.0 V.


RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 51575-51582 ◽  
Author(s):  
Guojian Tian ◽  
Xiang Wei ◽  
Ning Xiang ◽  
Jinhai Huang ◽  
Jin Cao ◽  
...  

Four small organic host materials based on oxazole/thiazole have been synthesized and fully characterized. The best performance of compound 2d was a maximum current efficiency of 50.7 cd A−1 for green device and a maximum current efficiency of 18.7 cd A−1 for red device.


2020 ◽  
Vol 8 (3) ◽  
pp. 1002-1009 ◽  
Author(s):  
Liwen Hu ◽  
Siyang Liu ◽  
Guohua Xie ◽  
Wei Yang ◽  
Bin Zhang

A series of solution-processible blue small molecules based on bis(benzothiophene-S,S-dioxide) fused polycyclic aromatics (FBTO) are synthesized, which show the high EL performance with the maximum current efficiency of 6.37 cd A−1.


2011 ◽  
Vol 197-198 ◽  
pp. 1221-1224
Author(s):  
Qiong Hou ◽  
Dan Dan Ruan ◽  
Lin Tao Hou ◽  
Hong Zhu

Novel soluble three-component conjugated copolymers are synthesized by palladium- catalyzed Suzuki coupling reaction from 9,9-dioctylfluorene (DOF), 9-ethylhexylcarbazole (Cz) and 4,7-dithien-2-yl-2,1,3-benzothiadiazole (DBT) with Cz composition varying from 1-15 mol% in the copolymer. All of the polymers are soluble in common organic solvents and are highly photoluminescent. The electrochemical, optical, photoluminescent (PL) and electroluminescent (EL) properties of the copolymers were studied. When the hole transmitting material carbazole is introduced into the copolymer PFO-DBT, the hole mobility of the luminescent layer material is improved. The three-component copolymers compared with copolymer PFO-DBT15, Devices made up of these copolymers still emit saturated red light. The highest external quantum efficiency achieved in the device configuration ITO/PEDT/PFO-Cz-DBT15/Ba/Al is 1.81% for the copolymer for 10% Cz content, higher than that of the device made from PFO-DBT15.


RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 2615-2620 ◽  
Author(s):  
Yi-Ming Jing ◽  
You-Xuan Zheng ◽  
Jing-Lin Zuo

Organic light-emitting diodes based on an iridium complex using different device structure show high performances with a maximum current efficiency of 86.5 cd A−1and a maximum power efficiency of 52.2 lm W−1, respectively.


2016 ◽  
Vol 4 (27) ◽  
pp. 6570-6574 ◽  
Author(s):  
Bo Wang ◽  
Lei Zhang ◽  
Yun Hu ◽  
Xiao-Bo Shi ◽  
Zhao-Kui Wang ◽  
...  

A hole injection bilayer was developed for solution processed blue phosphorescent OLEDs with a maximum current efficiency of 16.7 cd A−1.


2020 ◽  
Vol 8 (29) ◽  
pp. 9845-9853
Author(s):  
Run Wang ◽  
Yue Zhang ◽  
Xing-Juan Ma ◽  
Yan-Hong Deng ◽  
Jun-Wei Shi ◽  
...  

High performance quasi-2D PeLEDs with maximum current efficiency of 35.5 cd A−1, by introducing α-cyclodextrin (α-CD) with a cage-type structure as an additive and TFB/PVK bilayer as a hole transport layer, are demonstrated.


Author(s):  
Hirokazu Seto ◽  
Takumi Tono ◽  
Akiko Nagaoka ◽  
Mai Yamamoto ◽  
Yumiko Hirohashi ◽  
...  

Poly(vinylbiphenyl)s bearing glycoside ligands at the side chains were prepared using the Suzuku coupling reaction. Effects of glycoside reactant concentration, halide species, glycoside species, and catalyst species on the incorporation...


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