Preparation of Double-Layer Crossed Silver Nanowire Film and Its Application to OLED

Ordered silver nanowire (AgNW) film can effectively reduce the density of nodes, reduce the roughness of the film, and increase its conductivity and transmittance. In this paper, a double-layer crossed AgNW grid film was prepared by the auxiliary stirring method. The average transmittance of the double-layer crossed AgNW grid film was found to be 80% in the 400–1000 nm band, with a square resistance of 35 Ω/sq. As a transparent conductive anode material, the ordered AgNW film was applied to fabricate a flexible green organic light-emitting diode (OLED). The experimental results showed that the threshold voltage of the OLED was only 5 V and the maximum luminance was 1500 cd/m2.

COT-13 Luminance analysis of 5-aminolevulinic acid using Image J for malignant brain tumor

Purpose: For malignant brain tumor surgery, photodynamic diagnosis (PDD) with 5-aminolevulinic acid (5-ALA) is useful for maximal removal of the tumor. Although it has the advantage of identifying the presence or absence of residual tumors during surgery, there are variations in positive rates, and the classification is limited, based on visual inspection such as Stummer’s classification (strong, vague, none). We analyzed the luminance of positive findings using software Image J for brain tumor surgery using 5-ALA, and we report the results. Materials and Methods: From April 2018 to March 2021, 31 patients with suspected malignant glioma before surgery were included. Intraoperative 5-ALA positive findings were analyzed by software Image J (Wayne Rasband: NIH), the luminance was measured with a histogram, and compared the maximum luminance titer. Results: Among the positive cases, the average maximum luminance value for malignant glioma was 101 (50–168), which consisted of 11 cases of Glioblastoma, 1 case of Oligodendroglioma, and 1 case of anaplastic astrocytoma. The average maximum brightness of metastatic brain tumors is lower than that of malignant gliomas, even if they are visually strong, 83.5 (28–121). Conclusions: Even if it is visually strong in the conventional Stummer classification, it may be possible to classify in detail by analyzing luminance with Image J. In addition, more objective index is necessary to classify the vague findings.

Fabrication and electroluminescence properties of alloyed CdSxSe1-x quantum dots-based LEDs

We report the facile synthesis of alloyed CdSxSe1-x QDs via one-pot method using simultaneous injection of Se and S source into a solution of the Cd precursor dissolved in a coordinating mixture of hexadecylamine and trioctylphosphine, during which the formation of CdSxSe1-x nanocrystals was controlled by growth time at a certain temperature of 260 oC. In particular, emission peak and full width at half maximum of photoluminescence (PL) of alloyed CdSxSe1-x QDs were tunable in a range of 588 - 604 nm and 36 - 38 nm, respectively, with a PL quantum yield up to 55 % by a reaction time of 60 min. Importantly, the structural advantage of alloyed CdSxSe1-x QDs based LEDs have been fabricated and their electroluminescence properties were characterized. A good performance device with a maximum luminance and luminous efficiency of 761 cd/m2 and 0.82 cd/A was obtained, respectively.

High Performance Top-Emission Quantum Dot Light-Emitting Diodes with Mg-Doped ZnO Nanoparticles Used as an Electron Transport Layer

In this paper, we reported superior performance of solution-processed top-emission quantum dot light-emitting diodes (TE-QLEDs) with Mg-doped ZnO nanoparticle (NP) electron transport layer (ETL). The Mg-doped ZnO NPs were synthesized by the sol-gel method. Transmission electron microscopy (TEM) analysis of the Mg-doped ZnO NPs with 0 wt%, 5 wt%, 10 wt%, and 15 wt% Mg-doping concentrations revealed average diameters of 5.86 nm, 5.33 nm, 4.52 nm, and 4.37 nm, respectively. The maximum luminance, the current efficiency, and external quantum efficiency (EQE) were 178,561.8 cd/m2, 56.0 cd/A, and 14.43%, respectively. However, for the best performance of TE-QLED without Mg-doping in the ZnO NPs, the maximum luminance was only 101,523.4 cd/m2, the luminous efficiency was 27.8 cd/A, and the EQE was 6.91%. The improvement of the performance is attributed to the suppression of electron transfer by an increase in the energy barrier between the cathode and Mg-doped ZnO NP ETL and the reduction in the Hall mobility of electron with increasing the Mg-doping in the ZnO NPs, resulting in the enhanced charge balance in the quantum dot (QD) emitting layer (EML).

Luminosity thresholds of colored surfaces are determined by their heuristic upper-limit luminances in the visual system

Some objects in the real world themselves emit a light, and we typically have a fairly good idea as to whether a given object is self-luminous or illuminated by a light source. However, it is not well understood how our visual system makes this judgement. This study aimed to identify determinants of luminosity threshold, a luminance level at which the surface begins to appear self-luminous. We specifically tested a hypothesis that our visual system knows a maximum luminance level that a surface can reach under the physical constraint that surface cannot reflect more lights that incident lights and apply this prior to determine the luminosity thresholds. Observers were presented a 2-degree circular test field surrounded by numerous overlapping color circles, and luminosity thresholds were measured as a function of (i) the chromaticity of the test field, (ii) the shape of surrounding color distribution and (iii) the color of illuminant lighting surrounding colors. We found that the luminosity thresholds strongly depended on test chromaticity and peaked around the chromaticity of test illuminants and decreased as the purity of the test chromaticity increased. However, the locus of luminosity thresholds over chromaticities were nearly invariant regardless of the shape of surrounding color distribution and generally well resembled the locus drawn from theoretical upper-limit luminance but also the locus drawn from the upper boundary of real objects. These trends were particularly evident for test illuminants on blue-yellow axis and curiously did not hold under atypical illuminants such as magenta or green. Based on these results, we propose a theory that our visual system empirically internalizes the gamut of surface colors under illuminants typically found in natural environments and a given surface appears self-luminous when its luminance exceeds this heuristic upper-limit luminance.

9-(10-phenylanthracen-9-yl)-7H-Fluoreno[4, 3-b]Benzofuran Derivatives for Blue Organic Light-Emitting Diodes

In this study, two blue fluorescent using phenylanthracene-substituted furan derivatives were synthesized for organic light-emitting diodes (OLEDs) and subsequently characterized. To study the electroluminescent properties of the materials, OLED devices were fabricated using these two materials as an emissive layer (EML). The device using 7,7-diphenyl-9-(10-phenylanthracen-9-yl)-7H-fluoreno[4,3-b]benzofuran in the emitting layer showed the highest external quantum efficiency (EQE) value, 3.10%. It also showed the maximum luminance efficiency of 2.41 cd/A and maximum power efficiency of 1.90 lm/W with CIE coordinates of (0.15, 0.08).

Non-Doped Deep-Blue OLEDs Based on Carbazole-π-Imidazole Derivatives

In this work, we designed and synthesized four bipolar blue-emitting materials with carbazole, imidazole, and biphenyl as donor, acceptor, and p bridge, respectively. The twisted phenylimidazole acceptor leads to a wider band-gap and hence deeper blue emission than the conjugated phenanthrimidazole acceptor. For the substituents on the carbazole donor, the t-butyl group could prevent the intramolecular charge transfer (ICT) process more effectively than the methoxy group. A non-doped deep-blue organic light-emitting diodes (OLED) is obtained with CIE coordinates of (0.159, 0.080), a maximum luminance of 11364 cd/m2, and a maximum EQE of 4.43%.

Organic light-emitting devices based on conducting polymer treated with benzoic acid

We report on the enhanced conductivity of the benzoic-acid-treated poly(3,4-ethlenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) electrode for use in highly flexible, organic light-emitting devices (OLEDs). The conductivity of the benzoic-acid-treated PEDOT:PSS electrode increased from 1 to 1583.2 S/cm, in comparison with that of the pristine PEDOT:PSS electrode, due to a complex factor of the H+ mole % and the dielectric constant of the benzoic solution. Among the post-treatment methods of the PEDOT:PSS electrodes, the operating voltage at 1000 cd/m2 of OLEDs fabricated utilizing the PEDOT:PSS electrode with the benzoic acid treatment has the lowest value, and its maximum luminance is 24,400 cd/m2, which are 1.54 and 2.15 times higher than those of OLEDs using PEDOT:PSS electrodes treated with dimethyl sulfoxide and methanol, respectively. The luminance of a flexible OLED with a benzoic-acid-treated PEDOT:PSS electrode after 1400 bending cycles decreased to 83% of the initial luminance, resulting in excellent mechanical stability.

Intrinsically stretchable organic light-emitting diodes

Soft and conformable optoelectronic devices for wearable and implantable electronics require mechanical stretchability. However, very few researches have been done for intrinsically stretchable light-emitting diodes. Here, we present an intrinsically stretchable organic light-emitting diode, whose constituent materials are all highly stretchable. The resulting intrinsically stretchable organic light-emitting diode can emit light when exposed to strains as large as 80%. The turn-on voltage is as low as 8 V, and the maximum luminance, which is a summation of the luminance values from both the anode and cathode sides, is 4400 cd m−2. It can also survive repeated stretching cycles up to 200 times, and small stretching to 50% is shown to substantially enhance its light-emitting efficiency.

Efficient white light-emitting polymers from dual thermally activated delayed fluorescence chromophores for non-doped solution processed white electroluminescent devices

Conjugated TADF copolymers comprised of two TADF molecules linked with carbazole exhibited stable pure white emission from non-doped OLEDs with CIE coordinates (0.32, 0.35), a maximum luminance efficiency of 9.13 cd A−1, and a maximum EQE of 4.17%.