Hot Corrosion Behavior of Sputtered Fe-Y Alloy Coatings with Different Y Contents

2011 ◽  
Vol 391-392 ◽  
pp. 1263-1267
Author(s):  
Guang Yan Fu ◽  
Jing Yu Chen ◽  
Qun Liu ◽  
Yong Su
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Alloy Coating ◽  
Good Adhesion ◽  
Corrosion Scale ◽  
Measurement Results ◽  
The Matrix ◽  
Better Than

Three Fe-Y alloy coatings with differernt kinds of Y contents were prepared on stainless steel by magnetron sputtering. The hot corrosion behavior of sputtered alloy coatings with Na2SO4 deposits at 800 °C was investigated by discontinuous weigh measurement. Results show that the sputtered Fe-Y alloy coatings exhibit good adhesion with the matrix of stainless steel, and the hot corrosion kinetic curves of the specimens approximately follow the parabolic rate law. The Fe oxides are the main substances in the corrosion scale, and the hot corrosion rate of the three Fe-Y alloy coatings increases as the Y content increases. Therefore, the hot corrosion resistance of Fe-15Y alloy coating is better than that of Fe-20Y or Fe-30Y alloy coating.

Hot Corrosion of T122 and 347HFG Steels in Na2SO4 Salts at 800 and 900 °C

2013 ◽  
Vol 711 ◽  
pp. 128-133
Author(s):  
Chun Yu Xu ◽  
Dong Bok Lee
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Oxide Scales ◽  
Good Corrosion Resistance ◽  
Ni Alloy

The T122 steel (ferritic Fe-Cr-W alloy) and 347HFG stainless steel (austenitic Fe-Cr-Ni alloy) were corroded in the Na2SO4salt at 800 and at 900 °C, and their hot corrosion behavior was studied. They displayed good corrosion resistance owing to the formation of the protective Fe3O4and (Fe0.6Cr0.4)2O3scales. These oxides effectively suppressed sulfidation by the Na2SO4salt. The oxide scales that formed were thin and loosely adherent. The displayed good corrosion resistance was mainly attributed to the large amount of Cr in the alloys.

Hot Corrosion Behavior of Stainless Steel with Al-Si/Al-Si-Cr Coating

2017 ◽  
Vol 36 (3) ◽  
pp. 243-248 ◽  
Author(s):  
Guangyan Fu ◽  
Yongzhao Wu ◽  
Qun Liu ◽  
Rongguang Li ◽  
Yong Su
Keyword(s):  
Stainless Steel ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Mass Gain ◽  
Corrosion Products ◽  
Protective Films ◽  
The Matrix ◽  
Sulfide Corrosion ◽  
Cr Coating ◽  
Kinetics Of

AbstractThe 1Cr18Ni9Ti stainless steel with Al-Si/Al-Si-Cr coatings is prepared by slurry process and vacuum diffusion, and the hot corrosion behavior of the stainless steel with/without the coatings is studied under the condition of Na2SO4 film at 950 °C in air. Results show that the corrosion kinetics of stainless steel, the stainless steel with Al-Si coating and the stainless steel with Al-Si-Cr coating follow parabolic laws in several segments. After 24 h corrosion, the sequence of the mass gain for the three alloys is the stainless steel with Al-Si-Cr coating < the stainless steel with Al-Si coating < the stainless steel without any coating. The corrosion products of the three alloys are layered. Thereinto, the corrosion products of stainless steel without coating are divided into two layers, where the outside layer contains a composite of Fe2O3 and FeO, and the inner layer is Cr2O3. The corrosion products of the stainless steel with Al-Si coating are also divided into two layers, of which the outside layer mainly consists of Cr2O3, and the inner layer is mainly SiO2. The corrosion film of the stainless steel with Al-Si-Cr coating is thin and dense, which combines well with substrate. Thereinto, the outside layer is mainly Cr2O3, and the inside layer is Al2O3. In the matrix of all of the three alloys, there exist small amount of sulfides. Continuous and protective films of Cr2O3, SiO2 and Al2O3 form on the surface of the stainless steel with Al-Si and Al-Si-Cr coatings, which prevent further oxidation or sulfide corrosion of matrix metals, and this is the main reason for the much smaller mass gain of the two alloys than that of the stainless steel without any coatings in the 24 h hot corrosion process.

Effects of Nano-Al2O3p on Hot Corrosion Resistance of NiCoCrAlY Cladded Coatings

2013 ◽  
Vol 670 ◽  
pp. 65-69 ◽  
Author(s):  
H.Y. Wang ◽  
Dun Wen Zuo ◽  
X.F. Li ◽  
M.D. Wang ◽  
Y.P. Yu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Laser Cladding ◽  
Hot Corrosion ◽  
Influencing Mechanism ◽  
The One ◽  
Super Alloy ◽  
Better Than

Three NiCoCrAlY cladded coatings reinforced by different contents of nano- Al2O3p and one without nano-Al2O3p were prepared on a Ni-base super alloy using laser cladding technique. Hot corrosion of the NiCoCrAlY coatings in Na2SO4/K2SO4 (75:25, wt. /wt.) mixture was performed at 1050 °C in static air. The effects and influencing mechanism of nano-Al2O3p on the hot corrosion behavior of the coatings were discussed. Results indicate that the hot corrosion resistance of the coatings with nano-Al2O3p is better than that of the one without nano-Al2O3p, among which the one with 1.0 wt. % nano-Al2O3p presented the best hot corrosion resistance. The improvement of the hot corrosion resistance is largely due to the refinement of the microstructure after adding nano-Al2O3p.

CRUCIBLE CPM S30V

Alloy Digest ◽  
2003 ◽  
Vol 52 (9) ◽  
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Wear Resistance ◽  
Corrosion Resistance ◽  
Physical Properties ◽  
Martensitic Stainless Steel ◽  
Heat Treating ◽  
Corrosion And Wear ◽  
Better Than

Abstract Crucible CPM S30V is a martensitic stainless steel designed with a combination of toughness, wear resistance, and corrosion resistance equal to or better than 440C. This datasheet provides information on composition, physical properties, microstructure, hardness, and elasticity as well as fracture toughness. It also includes information on corrosion and wear resistance as well as heat treating and machining. Filing Code: SS-891. Producer or source: Crucible Service Centers.

URANUS 52N

Alloy Digest ◽  
1994 ◽  
Vol 43 (5) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Flue Gas ◽  
Crevice Corrosion ◽  
Heat Treating ◽  
Flue Gas Desulfurization ◽  
Temperature Performance ◽  
Aisi Type ◽  
Better Than

Abstract URANUS 52N is a nitrogen-alloyed duplex stainless steel improved in stress-corrosion cracking resistance and with pitting and crevice corrosion resistance better than AISI Type 317L. Applications include handling phosphoric acid contaminated with chlorides and in flue gas desulfurization scrubbers. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-566. Producer or source: Creusot-Marrel.

Effect of pre-oxidation on hot corrosion resistance of HR3C stainless steel in sulfate salt with or without Fe2O3

2021 ◽  
Vol 192 ◽  
pp. 109789
Author(s):  
Zheng Yu ◽  
Jintao Lu ◽  
Minghui Chen ◽  
Jinlong Wang ◽  
Fuhui Wang
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Hot Corrosion ◽  
Sulfate Salt

Corrosion behavior of new type Co-based superalloys with different Ni contents

2017 ◽  
Vol 35 (6) ◽  
pp. 455-462 ◽  
Author(s):  
Bo Gao ◽  
Lei Wang ◽  
Yang Liu ◽  
Xiu Song ◽  
Shu-Yu Yang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Corrosion Layer ◽  
Corrosion Process ◽  
Corrosion Properties ◽  
Oxidation Processes ◽  
Ni Content ◽  
Ni Addition ◽  
New Type

AbstractThe corrosion properties of γ′-strengthened Co-xNi-Al-W-Cr (where x=15, 20, 25, and 30 at.%) superalloys were investigated in the mixture of 75 wt.% Na2SO4+25 wt.% NaCl at 900°C. The results showed that the corrosion behavior is associated with both sulfuration and oxidation processes. It was demonstrated that increasing the addition of Ni effectively promoted the formation of continuous Al2O3 scales, so that the hot corrosion resistance could be improved. When Ni content is more than 20 at.%, a large amount of Ni3S2 precipitates during the corrosion process. Sulfuration can destroy the integrity of the corrosion layer and increase the activity of oxygen. In this way, the internal oxidation of the alloys becomes more serious. Therefore, it is recommended that the optimum Ni addition is about 20 at.% for new type Co-Ni-Al-W-Cr superalloys.

Investigation of mechanical and corrosion behavior of laser hybrid weld joint of 2205 duplex stainless steel

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chuanbo Zheng ◽  
Cheng Zhang ◽  
Xiao Yong Wang ◽  
Jie Gu
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Base Metal ◽  
Corrosion Behavior ◽  
Welded Joints ◽  
Two Phase ◽  
Content Type ◽  
2205 Duplex Stainless Steel ◽  
Laser Hybrid

Purpose Duplex stainless steel is composed of equal amounts of austenite and ferrite, which has excellent corrosion resistance and strength. However, after the metal was welded, the ratio of austenite and ferrite in the joint is unbalanced, and secondary phase precipitates are produced, which is also an important cause of pitting corrosion in the joint. Design/methodology/approach This paper aims to study the mechanical and corrosion behavior of welded joints, by adjusting the welding parameters of laser hybrid welding, dual heat sources are used to weld 2205 duplex stainless steel. The two-phase content of different parts of the welded joint is measured to study the influence of the ratio of the two-phase on the mechanical and corrosion properties of the joint. Findings The ratio of austenite and ferrite in different welded joints has an obvious difference, and from top to bottom, the austenite content decreased gradually, and the ferrite content increased gradually. The harmful phases are precipitated in the middle and lower part of the joint. The strength of welded joints is slightly lower than that of base metal. At the same time, the fracture analysis shows that some ferrite phases are affected by the precipitate in the grain and produce quasi-cleavage fracture. The corrosion results show that the corrosion resistance of the welded joints is lower than that of the base metal, and the concentration of chloride ions affects the corrosion resistance. Originality/value In this paper, the authors use the influence of different welding processes on the two-phase ratio of the joint to further study the influence of the microstructure on the corrosion resistance and mechanical properties of the weld.

Corrosion Resistance Evaluation of a Stainless-Steel Brazed Joint in HCl Solution

2021 ◽  
Vol 1016 ◽  
pp. 997-1002
Author(s):  
Hikaru Nagata ◽  
Masa Ono ◽  
Yasuyuki Miyazawa ◽  
Yuji Hayashi ◽  
Yoshio Bizen
Keyword(s):  
Aqueous Solution ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Base Metal ◽  
Corrosion Behavior ◽  
Anodic Polarization ◽  
Filler Metal ◽  
Brazed Joint ◽  
In Situ Observations

To clarify the effect of the acid solution type on corrosion resistance, the corrosion behavior of stainless steel brazed joints in HCl aqueous solution was evaluated through electrochemical measurements. Anodic polarization curves of a ferritic stainless-steel base metal, Ni-based brazing filler metals, and a brazed joint were recorded. In addition, in situ observations were conducted to observe the corrosion behavior of each structure of the brazed joint. Corrosion potentials of the brazing filler metal were lower than that of the base metal. In situ observations of the brazed joint revealed the order of corrosion in aqueous hydrochloric acid. According to the electrochemical measurements, under an actual corrosive environment, the brazing filler metal can function as an anode and selectively corrode. In addition, the anodic polarization curve of the brazed joint showed values between those of the polarization curves of the brazing filler metal and the base metal, indicating that the corrosion resistance could be electrochemically evaluated in HCl aqueous solution.

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