Effects of Nano-Al2O3p on Hot Corrosion Resistance of NiCoCrAlY Cladded Coatings

2013 ◽  
Vol 670 ◽  
pp. 65-69 ◽  
Author(s):  
H.Y. Wang ◽  
Dun Wen Zuo ◽  
X.F. Li ◽  
M.D. Wang ◽  
Y.P. Yu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Laser Cladding ◽  
Hot Corrosion ◽  
Influencing Mechanism ◽  
The One ◽  
Super Alloy ◽  
Better Than

Three NiCoCrAlY cladded coatings reinforced by different contents of nano- Al2O3p and one without nano-Al2O3p were prepared on a Ni-base super alloy using laser cladding technique. Hot corrosion of the NiCoCrAlY coatings in Na2SO4/K2SO4 (75:25, wt. /wt.) mixture was performed at 1050 °C in static air. The effects and influencing mechanism of nano-Al2O3p on the hot corrosion behavior of the coatings were discussed. Results indicate that the hot corrosion resistance of the coatings with nano-Al2O3p is better than that of the one without nano-Al2O3p, among which the one with 1.0 wt. % nano-Al2O3p presented the best hot corrosion resistance. The improvement of the hot corrosion resistance is largely due to the refinement of the microstructure after adding nano-Al2O3p.

Hot Corrosion Behavior of Sputtered Fe-Y Alloy Coatings with Different Y Contents

2011 ◽  
Vol 391-392 ◽  
pp. 1263-1267
Author(s):  
Guang Yan Fu ◽  
Jing Yu Chen ◽  
Qun Liu ◽  
Yong Su
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Alloy Coating ◽  
Good Adhesion ◽  
Corrosion Scale ◽  
Measurement Results ◽  
The Matrix ◽  
Better Than

Three Fe-Y alloy coatings with differernt kinds of Y contents were prepared on stainless steel by magnetron sputtering. The hot corrosion behavior of sputtered alloy coatings with Na2SO4 deposits at 800 °C was investigated by discontinuous weigh measurement. Results show that the sputtered Fe-Y alloy coatings exhibit good adhesion with the matrix of stainless steel, and the hot corrosion kinetic curves of the specimens approximately follow the parabolic rate law. The Fe oxides are the main substances in the corrosion scale, and the hot corrosion rate of the three Fe-Y alloy coatings increases as the Y content increases. Therefore, the hot corrosion resistance of Fe-15Y alloy coating is better than that of Fe-20Y or Fe-30Y alloy coating.

Corrosion behavior of new type Co-based superalloys with different Ni contents

2017 ◽  
Vol 35 (6) ◽  
pp. 455-462 ◽  
Author(s):  
Bo Gao ◽  
Lei Wang ◽  
Yang Liu ◽  
Xiu Song ◽  
Shu-Yu Yang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Corrosion Layer ◽  
Corrosion Process ◽  
Corrosion Properties ◽  
Oxidation Processes ◽  
Ni Content ◽  
Ni Addition ◽  
New Type

AbstractThe corrosion properties of γ′-strengthened Co-xNi-Al-W-Cr (where x=15, 20, 25, and 30 at.%) superalloys were investigated in the mixture of 75 wt.% Na2SO4+25 wt.% NaCl at 900°C. The results showed that the corrosion behavior is associated with both sulfuration and oxidation processes. It was demonstrated that increasing the addition of Ni effectively promoted the formation of continuous Al2O3 scales, so that the hot corrosion resistance could be improved. When Ni content is more than 20 at.%, a large amount of Ni3S2 precipitates during the corrosion process. Sulfuration can destroy the integrity of the corrosion layer and increase the activity of oxygen. In this way, the internal oxidation of the alloys becomes more serious. Therefore, it is recommended that the optimum Ni addition is about 20 at.% for new type Co-Ni-Al-W-Cr superalloys.

Hot Corrosion of Co-based Alloys with 25%NaCl+75%Na2SO4 Coating at 1173 K

2013 ◽  
Vol 32 (3) ◽  
pp. 317-321 ◽  
Author(s):  
Guangyan Fu ◽  
Xingxing Guo ◽  
Qun Liu ◽  
Xin Zhao ◽  
Yong Su
Keyword(s):  
Corrosion Resistance ◽  
Hot Corrosion ◽  
Middle Layer ◽  
Mass Gain ◽  
Corrosion Products ◽  
Chromium Sulfide ◽  
Three Samples ◽  
Innermost Layer ◽  
Inside Layer ◽  
Better Than

AbstractHot corrosion behavior of pure Co, Co-10Cr and Co-10Cr-5Al alloys in the presence of a salt coat of Na2SO4+NaCl in air at 1173 K was studied. The results indicated that among the three samples, the mass gain of Co-10Cr-5Al alloy is the smallest, while that of Co-10Cr is biggest. The corrosion products of Co-10Cr-5Al can be divided into three layers, of which the outside layer is CoO, the middle layer consists of Cr2O3 and Al2O3, and the inside layer is a small amount of Chromium sulfide and aluminum sulfide. The corrosion products of Co-10Cr can also be divided into three layers, from the outermost to the innermost layer are CoO, Cr2O3, and small amount of Cr2S3. The corrosion resistance of Co-10Cr-5Al alloy is better than that of Co-10Cr alloy.

Study on Corrosion Resistance of Cr-Containing P110 Steel

2013 ◽  
Vol 740 ◽  
pp. 608-611 ◽  
Author(s):  
Ming Hua Liang ◽  
Zhi Yong Pan ◽  
Xiang Zhang
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Product ◽  
Corrosion Behavior ◽  
Local Corrosion ◽  
Effect Of Temperature ◽  
Corrosion Rates ◽  
P110 Steel ◽  
Better Than

The influence of Cr on corrosion behavior of P110 steel was studied in the simulated CO2 environment. The result demonstrated that the Cr cant change the effect of temperature on P110 steel. The corrosion rates of the two kinds of materials reached the peak at 90°C. The temperature has dual effects on corrosion, which caused the adhesive and productivity of corrosion product formed up 90°C are better than that formed below 90°C; The adding of Cr in the P110 steel can prohibit the local corrosion to occur.

HOT-CORROSION BEHAVIOR OF THERMAL BARRIER COATED DZ125 SUPERALLOY EXPOSED TO ATOMIZED SEAWATER AND KEROSENE

2010 ◽  
Vol 24 (15n16) ◽  
pp. 3155-3160
Author(s):  
ZHIMING BAI ◽  
LE ZHOU ◽  
TIANQUAN LIANG ◽  
HONGBO GUO ◽  
SHENGKAI GONG
Keyword(s):  
Corrosion Resistance ◽  
Electron Beam ◽  
Thermal Barrier Coating ◽  
Corrosion Behavior ◽  
Bond Coat ◽  
Hot Corrosion ◽  
Thermal Barrier ◽  
Average Mass ◽  
Barrier Coating ◽  
Corrosion Behaviors

The bare superalloy DZ 125 alloy, the aluminide coated specimens and electron beam physical vapor deposited (EB-PVD) thermal barrier coating (TBC) consisting of yttria stabilizied zirconia (YSZ) topcoat and NiCoCrAlY bond coat specimens were exposed to atomized seawater and kerosene at 900°C and the cyclic hot-corrosion behaviors of the specimens were investigated. Disastrous spallation of the bare superalloy occurred within 50 h hot-corrosion. In contrast to this, after 100 h hot-corrosion, the average mass change for the aluminized and TBC coated specimens is 0.7 mg/cm2 and 0.63 mg/cm2, respectively, exhibiting excellent hot-corrosion resistance.

scholarly journals Effects of Laser Scanning Speed on Microstructure, Microhardness, and Corrosion Behavior of Laser Cladding Ni45 Coatings

2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Yanxin Qiao ◽  
Jie Huang ◽  
Ding Huang ◽  
Jian Chen ◽  
Wen Liu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Laser Scanning ◽  
Scanning Speed ◽  
Primary Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microhardness Distribution ◽  
Laser Scanning Speed ◽  
The One

The effects of laser scanning speed on the microstructure, microhardness, and corrosion behavior of Ni45 coatings were investigated by using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), microhardness, and electrochemical measurements. The results showed that increasing laser scanning speed promotes the transformation from planar crystals to dendrites and refines the grains concurrently. The γ-(Ni, Fe), FeNi3, and M23(C,B)6 are identified as the primary phase composition in the Ni45 coatings regardless of the laser scanning speed. Thereinto, the formation and growth of M23(C,B)6 precipitates can be inhibited with increasing laser scanning speed due to the higher cooling rate, which affects the microhardness distribution and corrosion resistance of the coating. On the one hand, the microhardness of the whole coating presents a downtrend with increasing laser scanning speed due to the reduction of M23(C,B)6 phase. On the other hand, the corrosion resistance in 0.5 M NaCl solution is improved to some extent at higher laser scanning speed because the less precipitation of M23(C,B)6 reduces the depletion of Cr around the precipitates. In contrast, all the coatings exhibit undifferentiated but poor corrosion resistance in the highly corrosive 0.5 M NaCl + 0.5 M H2SO4 solution.

scholarly journals Corrosion Resistance of Al/SiC Laser Cladding Coatings on AA6082

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 673
Author(s):  
Ainhoa Riquelme ◽  
Pilar Rodrigo ◽  
María Dolores Escalera-Rodríguez ◽  
Joaquín Rams
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Laser Cladding ◽  
Aluminum Matrix ◽  
Aluminum Matrix Composites ◽  
Matrix Composites ◽  
The Matrix ◽  
Corrosion Mechanisms ◽  
Silicon Carbide Particles ◽  
Carbide Particles

Aluminum matrix composites reinforced with silicon carbide particles (SiCp) were deposited by laser cladding on AA6082 aluminum alloy. Different compositions of the matrix of the composites coating were used and different amounts of Si and Ti were added to a base of Al-12Si in order to control the reactivity between molten aluminum and SiCp during laser cladding. The corrosion behavior of the coatings deposited was evaluated in 3.5 wt.% NaCl solution using gravimetric analyses and electrochemical polarization tests. The corrosion products observed were Al(OH)3 and Al2O3, and they formed a layer that limited the evolution of corrosion. However, the presence of discontinuities in it reduced the corrosion resistance of the coating. The corrosion mechanisms were different depending on the coating composition. The addiction of Ti to the alloy allowed for better corrosion behavior for the composite coating than that of the aluminum substrate.

Characterization and hot corrosion behavior of D-gun sprayed Cr2O3-75% Al2O3 coated ASTM-SA210-A1 boiler steel in molten salt environment

2017 ◽  
Vol 64 (5) ◽  
pp. 515-528 ◽  
Author(s):  
Amita Rani ◽  
Niraj Bala ◽  
C.M. Gupta
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Molten Salt ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Degradation Mechanism ◽  
Effective Diffusion ◽  
Boiler Steel ◽  
Content Type ◽  
Scanning Electron

Purpose Hot corrosion is the major degradation mechanism of failure of boiler and gas turbine components. The present work aims to investigate the hot corrosion resistance of detonation gun sprayed (D-gun) Cr2O3-75 per cent Al2O3 ceramic coating on ASTM-SA210-A1 boiler steel. Design/methodology/approach The coating exhibits nearly uniform, adherent and dense microstructure with porosity less than 0.8 per cent. Thermogravimetry technique is used to study the high temperature hot corrosion behavior of bare and coated boiler steel in molten salt environment (Na2SO4-60 per cent V2O5) at high temperature 900°C for 50 cycles. The corrosion products are analyzed by using X-ray diffraction, scanning electron microscopy (SEM) and field emission scanning electron microscope/energy-dispersive analysis (EDAX) to reveal their microstructural and compositional features for elucidating the corrosion mechanisms. Findings During investigations, it was found that the Cr2O3-75 per cent Al2O3 coating on Grade A-1 boiler steel is found to be very effective in decreasing the corrosion rate in the molten salt environment at 900°C. The coating has shown lesser weight gains along with better adhesiveness of the oxide scales with the substrate till the end of the experiment. Thus, coatings serve as an effective diffusion barrier to preclude the diffusion of oxygen from the environment into the substrate boiler steel. Research limitations/implications Therefore, it is concluded that the better hot corrosion resistance of the coating is due to the formation of desirable microstructural features such as very low porosity, uniform fine grains and the flat splat structures in the coating; as compared to the bare substrate under cyclic conditions. Practical implications This research is useful for coal-fired boilers and other power plant boilers. Social implications This research is useful for power generation plants. Originality/value There is no reported literature on hot corrosion behavior of Cr2O3-75 per cent Al2O3 coating deposited on the selected substrates by D-gun spray technique. The present work has been focused to study the influence of the Cr2O3-75 per cent Al2O3 coating developed with D-gun spraying technique on high temperature corrosion behavior of ASTM-SA210-A-1 boiler steel in an aggressive environment of Na2SO4-60 per cent V2O5 molten salt at 900°C under cyclic conditions.

Microstructure and Corrosion Behavior of Laser Cladding Al3Ti-Based Composite Coatings on AA6063 Aluminum Alloy

2013 ◽  
Vol 634-638 ◽  
pp. 2973-2978 ◽  
Author(s):  
Huan He ◽  
Yue Chun Fu ◽  
Wei Hua Guo ◽  
Min Xiao ◽  
Xing Zhi Pang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Intermetallic Compound ◽  
Uniform Distribution ◽  
Laser Irradiation ◽  
Corrosion Behavior ◽  
Laser Cladding ◽  
Composite Coatings ◽  
Nacl Solution ◽  
Aa6063 Aluminum Alloy

Intermetallic compound Al3Ti-based IMC coatings were formed on AA6063 aluminum alloy by laser cladding. The microstructure and corrosion characteristics in 3.5% NaCl solution were investigated. The results show that, the laser cladding coating is made up of Al3Ti dendrites, interdendritic α-Al and uniform distribution of TiC which hardly melted during laser irradiation, and shows good bonding to the substrate. The cross distribution of Al3Ti and α-Al helps to avoid the generation of cracks in the coating. The corrosion resistance of the laser cladding coatings is greatly increased as compared with the substrate, which owes mainly to the existence of hard Al3Ti and TiC. And with the increasing of TiC content in the coating, the corrosion resistance is improved simultaneously.

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