Effect of Microstructures on Corrosion of X80 Pipeline Steel in an Alkaline Soil

2012 ◽  
Vol 476-478 ◽  
pp. 321-328
Author(s):  
Cong Min Xu ◽  
Rong Biao Li ◽  
Ji Long Wang ◽  
Gang Gang Zhang

The influence of microstructures with different heat treatments to stimulate the weld fusion zone and HAZ on corrosion properties of X80 pipeline steel was investigated in alkaline sand soil using electrochemical measurement and surface analysis(SEM, EDS and XRD). The results showed that the microstructure of X80 steel affected the properties of corrosion product layers. Generally, X80 steels with heat treatments had a higher corrosion rate than the as-received steel. The increase of pearlite content enhanced the corrosion of ferrite through a galvanic effect. The appearance of upper bainite and martenite increased further the activity of the steel. The corrosion product layer formed on as-received X80 steel was compact and complete, provided an effective protection to the underneath steel. However, the corrosion product layers on the heat-treated X80 steels were generally inhomogeneous, loose, porous and defective, and provided minor protectiveness. The cathodic/ anodic reactions of X80 steel are dominated by the oxygen reduction and formation of iron oxides that deposit on the steel surface which was through a physical block effect to afford the protection. We shall be able to publish your paper in electronic form on our web page http://www.scientific.net, if the paper format and the margins are correct. Your manuscript will be reduced by approximately 20% by the publisher. Please keep this in mind when designing your figures and tables etc.

2012 ◽  
Vol 476-478 ◽  
pp. 212-217 ◽  
Author(s):  
Jin Heng Luo ◽  
Cong Min Xu

The influence of microstructures with different heat treatments on corrosion properties of X80 pipeline steel was investigated in near-neutral pH soil using electrochemical measurement and surface analysis(SEM, EDS and XRD). The results showed that the microstructure of X80 steel affected the properties of corrosion product layers. Generally, X80 steels with heat treatments had a higher corrosion rate than the as-received steel. The increase of pearlite content enhanced the corrosion of ferrite through a galvanic effect. The appearance of upper bainite and martenite increased further the activity of the steel. The corrosion product layer formed on as-received X80 steel was compact and complete, provided an effective protection to the underneath steel. However, the corrosion product layers on the heat-treated X80 steels were generally inhomogeneous, loose, porous and defective, and provided minor protectiveness. The cathodic/anodic reactions of X80 steel are dominated by the oxygen reduction and formation of iron oxides that deposit on the steel surface which was through a physical block effect to afford the protection.


2017 ◽  
Vol 35 (6) ◽  
pp. 445-453 ◽  
Author(s):  
Dan Wang ◽  
Fei Xie ◽  
Xue Li ◽  
Xingfa Wang ◽  
Jiaqi Liu ◽  
...  

AbstractX80 pipeline steel is inevitably corroded by sulphate-reducing bacteria (SRB) in soil. Corrosion-induced damage to the pipeline steel could result in serious consequences. Studies have shown the critical role of interfacial film in SRB-induced corrosion. However, the specific effect of interfacial film was not examined. The effect of film on the corrosion of X80 steel in neutral soil environment was determined using scanning electron microscopy, energy-dispersive spectroscopy, and electrochemical impedance spectroscopy. The structure and electrochemical characteristics of the surface film of X80 steel were examined in the presence of SRB in Shenyang soil. The results showed that, at the beginning of immersion (14 h), the steel surface mainly adsorbed the SRB biofilm, and the biofilm slowed down the corrosion reaction. A small amount of the biofilm and corrosion product film was observed on the electrode surface after immersion for 14–48 h. The corrosion product film destroyed the protection of the biofilm, increasing corrosion. After immersion for 48 h, the corrosion product contents and polarisation resistance increased. After immersion for 240 h, a dense corrosion product film formed on the sample surface, showing the least corrosion. The protective effect of corrosion products on X80 steel was much greater than that of the biofilm.


2011 ◽  
Vol 189-193 ◽  
pp. 4261-4266 ◽  
Author(s):  
Ying Wang ◽  
Hong Ying Yu ◽  
Yuan Cheng ◽  
Hai Tao Shan ◽  
Li Xin Zhang ◽  
...  

Corrosion behaviors of X80 pipeline steel were investigated in different simulated alkaline soil solution using electrochemical test, EDS coupled to SEM and weight loss method. The results showed uniform corrosion was happened on X80 steel in Shanshan and Hami simulated solution, and local corrosion was the main failure mode for X80 steel in Yumen simulated solution. The ranking of corrosion rate of X80 steel from the biggest in simulated solution was Hami, Shanshan and Yumen. With the increasing of immersion time, a dense Ca2+ deposited layer was formed on the surface of X80 steel, which could inhibiting the Cl- effects on the corrosion of X80 steel in Shanshan and Hami solution. The SO42- competition absorbed effect could provide certain corrosion protection for X80 steel in Yumen solution at the early corrosion stage.


2011 ◽  
Vol 308-310 ◽  
pp. 762-766
Author(s):  
Yong Jie Ma ◽  
Xi Lu Liu ◽  
Guang Liang Zhang

The state study on mechanical properties’ changes of X80 steel at different quenching temperature. The results showed that the quenching temperature is 1000 °C, X80 Austenite grain coarsening is serious, leading to the production of coarse lath bainite ferrite, resulting in increased strength of X80 steel, toughness and hardness of a serious reduction; When the quenching temperature is 930 °C, and assisted by the appropriate temperatures, can make the X80 steel the small needle-like ferrite-based organizations, to obtain good hardness, strength, ductility and toughness of the match.


2021 ◽  
Vol 68 (5) ◽  
pp. 438-448
Author(s):  
Haoping Peng ◽  
Zhaolin Luan ◽  
Jun Liu ◽  
Yun Lei ◽  
Junxiu Chen ◽  
...  

Purpose This paper aims to under the laboratory environment, the corrosion behavior of X80 pipeline steel in oilfield injection water in eastern China was studied by immersion test. Design/methodology/approach First, the corrosion product film was immersed in oilfield injection water and the effect on the corrosion behavior and the corrosion reaction mechanism were constantly observed during this period. The effect was displayed by potentiodynamic polarization curve and electrochemical impedance spectrums (EIS) measurements. Second, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used to observe and test the corrosion product film immersed in the oilfield water for 30 days. Findings The results indicate that the tendency of metal corrosion becomes weaker at an early stage, but strengthened later, which means the corrosion rate is accelerating. Besides, it is indicated by impedance spectroscopy that with the decreasing of the capacitance arc radius, the reaction resistance is reducing in this progress. Meanwhile, the character of Warburg impedance could be found in EIS, which means that the erosional components are more likely to penetrate the product film to reach the matrix. The corrosion product is mainly composed of the inner Fe3O4 layer and outer shell layer, which contains a large number of calcium carbonate granular deposits. It is this corrosion under fouling that produces severe localized corrosion, forming many etch pits on the metal substrate. Originality/value The experiment chose the X80 steel, the highest-grade pipeline steel used in China, to conduct the static immersion test in the injection water coming from an oilfield in eastern China. Accordingly, the corrosion mechanism and the effect of corrosion product film on the corrosion of pipeline steel were analyzed and discussed.


Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 949 ◽  
Author(s):  
Wei Wu ◽  
Hailong Yin ◽  
Hao Zhang ◽  
Jia Kang ◽  
Yun Li ◽  
...  

An investigation into the electrochemical corrosion behavior of X80 pipeline steel under different elastic and plastic tensile stress in a CO2-saturated NaCl solution has been carried out by using open-circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, and surface analysis techniques. The results show that the corrosion rate of X80 steel first increases and then slightly decreases with the increase of elastic tensile stress, whereas the corrosion rate sharply increases with the increase of plastic tensile stress. Both elastic and plastic tensile stress can enhance steel corrosion by improving the electrochemical activity of both anodic and cathodic reactions. Moreover, compared with elastic tensile stress, plastic tensile stress has a more significant effect. Furthermore, electrochemical reactions for CO2 corrosion and mechanoelectrochemical effect are used to reasonably explain the corrosion behavior of stressed X80 steel in CO2 environment.


2011 ◽  
Vol 335-336 ◽  
pp. 468-473 ◽  
Author(s):  
Chuan He ◽  
Xu Chen ◽  
Yang Xu ◽  
Zhi Yong Liu

X80 pipeline steel specimens were treated by electrochemical hydrogen charging under various current density and charging time. The polarization resistance and corrosion rate of X80 steel were analyzed in Yingtan simulated soil solution under the different hydrogen charging conditions. The results showed that hydrogen accelerated anodic dissolution and enhanced corrosion sensitivity. With hydrogen in the steel, the charge transfer resistance and polarization resistance decreased, double electric layer capacitor and corrosion current increased. The effects were enhanced with the increase of hydrogen charging time and current density.


2010 ◽  
Vol 146-147 ◽  
pp. 920-925 ◽  
Author(s):  
Yuan Cheng ◽  
Hong Ying Yu ◽  
Li Xin Zhang ◽  
Ying Wang ◽  
Xu Meng ◽  
...  

The stress corrosion cracking susceptibility of X80 pipeline steel was investigated in a simulated soil solution using slow strain rate tensile (SSRT) tests. The different potentials were applied in the tests. The fracture surfaces were observed using scanning electron microscopy (SEM). The X80 steel was susceptible to SCC in simulated solution. The SCC susceptibility had no apparent change with the anodic potentials applied. The fracture mechanism was anodic dissolution. However, the SCC susceptibility increased with the decrease of the cathodic potentials obviously. The cracking was induced by the Hydrogen diffusing into the metal.


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