Study on Factors Influencing the Viscosity of Polyacrylamide Solution

2012 ◽  
Vol 512-515 ◽  
pp. 2439-2442 ◽  
Author(s):  
Yan Wang ◽  
Bao Wei Su ◽  
Xue Li Gao
Keyword(s):  
Polymer Solution ◽  
Oil Recovery ◽  
Divalent Cation ◽  
Polymer Concentration ◽  
Polymer Flooding ◽  
Polyacrylamide Solution ◽  
Factors Influencing ◽  
Stirring Rate ◽  
Main Factors ◽  
Enhance Oil Recovery

Polyacrylamide (PAM) is an important polymer for oilfield flooding. The viscosity of PAM solution is very significant for polymer flooding to enhance oil recovery. The main factors which influence viscosity of PAM solution including polymer concentration, temperature, stirring rate, TDS and divalent cation ions were studied. The results showed that high stirring rate will reduce the viscosity of PAM solution; and the viscosity decreases gradually with temperature increasing; TDS and divalent cation ions also affect the viscosity of polymer solution greatly, the viscosity loss is more than 3% with the TDS increases by 1000 mg/L under the same concentration of divalent cation ions; the viscosity loss is around 20% with the concentration of divalent cation ions increase by 100 mg/L.

Temperature Dependence of the Shear-Thinning Behavior o Partially Hydrolyzed Polyacrylamide Solution for Enhanced Oil Recovery

2020 ◽  
Vol 143 (6) ◽  
Author(s):  
Pan-Sang Kang ◽  
Jong-Se Lim ◽  
Chun Huh
Keyword(s):  
Temperature Dependence ◽  
Polymer Solution ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Polymer Concentration ◽  
Shear Thinning ◽  
Temperature Model ◽  
Polyacrylamide Solution ◽  
Partially Hydrolyzed Polyacrylamide ◽  
Hydrolyzed Polyacrylamide

Abstract The viscosity of injection fluid is a critical parameter that should be considered for the design and evaluation of polymer flood, which is an effective and popular technique for enhanced oil recovery (EOR). It is known that the shear-thinning behavior of EOR polymer solutions is affected by temperature. In this study, temperature dependence (25–70 °C) of the viscosity of a partially hydrolyzed polyacrylamide solution, the most widely used EOR polymer for oil field applications, was measured under varying conditions of the polymer solution (polymer concentration: 500–3000 ppm, NaCl salinity: 1000–10,000 ppm). Under all conditions of the polymer solution, it was observed that the viscosity decreases with increasing temperature. The degree of temperature dependence, however, varies with the conditions of the polymer solution. Martin model and Lee correlations were used to estimate the dependence of the viscosity of the polymer solution on the polymer concentration and salinity. In this study, we proposed a new empirical model to better elucidate the temperature dependence of intrinsic viscosity. Analysis of the measured viscosities shows that the accuracy of the proposed temperature model is higher than that of the existing temperature model.

scholarly journals A New Empirical Model for Viscosity of Sulfonated Polyacrylamide Polymers

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1046 ◽  
Author(s):  
Saeed Akbari ◽  
Syed Mohammad Mahmood ◽  
Hosein Ghaedi ◽  
Sameer Al-Hajri
Keyword(s):  
Polymer Solution ◽  
Oil Recovery ◽  
Empirical Model ◽  
Linear Regression Analysis ◽  
Polymer Concentration ◽  
Polymer Flooding ◽  
Solution Viscosity ◽  
Operational Variables ◽  
Reservoir Conditions ◽  
Sulfonated Polyacrylamide

Copolymers of acrylamide with the sodium salt of 2-acrylamido-2-methylpropane sulfonic acid—known as sulfonated polyacrylamide polymers—had been shown to produce very promising results in the enhancement of oil recovery, particularly in polymer flooding. The aim of this work is to develop an empirical model through the use of a design of experiments (DOE) approach for bulk viscosity of these copolymers as a function of polymer characteristics (i.e., sulfonation degree and molecular weight), oil reservoir conditions (i.e., temperature, formation brine salinity and hardness) and field operational variables (i.e., polymer concentration, shear rate and aging time). The data required for the non-linear regression analysis were generated from 120 planned experimental runs, which had used the Box-Behnken construct from the typical Response Surface Methodology (RSM) design. The data were collected during rheological experiments and the model that was constructed had been proven to be acceptable with the Adjusted R-Squared value of 0.9624. Apart from showing the polymer concentration as being the most important factor in the determination of polymer solution viscosity, the evaluation of the model terms as well as the Sobol sensitivity analysis had also shown a considerable interaction between the process parameters. As such, the proposed viscosity model can be suitably applied to the optimization of the polymer solution properties for the polymer flooding process and the prediction of the rheological data required for polymer flood simulators.

scholarly journals Effect of Polymer Degradation on Polymer Flooding in Heterogeneous Reservoirs

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 857 ◽  
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Zhangxin Chen ◽  
Keliu Wu ◽  
Xiaohu Dong ◽  
...  
Keyword(s):  
Polymer Solution ◽  
Oil Recovery ◽  
Degradation Rate ◽  
Polymer Concentration ◽  
Polymer Degradation ◽  
Polymer Flooding ◽  
First Order ◽  
Heterogeneous Reservoirs ◽  
Physical Experiments ◽  
Dynamic Degradation

Polymer degradation is critical for polymer flooding because it can significantly influence the viscosity of a polymer solution, which is a dominant property for polymer enhanced oil recovery (EOR). In this work, physical experiments and numerical simulations were both used to study partially hydrolyzed polyacrylamide (HPAM) degradation and its effect on polymer flooding in heterogeneous reservoirs. First, physical experiments were conducted to determine basic physicochemical properties of the polymer, including viscosity and degradation. Notably, a novel polymer dynamic degradation experiment was recommended in the evaluation process. Then, a new mathematical model was proposed and an in-house three-dimensional (3D) two-phase polymer flooding simulator was designed to examine both polymer static and dynamic degradation. The designed simulator was validated by comparison with the simulation results obtained from commercial software and the results from the polymer flooding experiments. This simulator further investigated and validated polymer degradation and its effect. The results of the physical experiments showed that the viscosity of a polymer solution increases with an increase in polymer concentration, demonstrating their underlying power law relationship. Moreover, the viscosity of a polymer solution with the same polymer concentration decreases with an increase in the shear rate, demonstrating shear thinning. Furthermore, the viscosity of a polymer solution decreased with an increase in time due to polymer degradation, exhibiting an exponential relationship. The first-order dynamic degradation rate constant of 0.0022 day−1 was greater than the first-order static degradation rate constant of 0.0017 day−1. According to the simulation results for the designed simulator, a 7.7% decrease in oil recovery, after a cumulative injection volume of 1.67 pore volume (PV) was observed between the first-order dynamic degradation rate constants of 0 and 0.1 day−1, which indicates that polymer degradation has a detrimental effect on polymer flooding efficiency.

scholarly journals Effect of Polymer Degradation on Polymer Flooding in Homogeneous Reservoirs

2018 ◽  
Vol 187 ◽  
pp. 01006
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Ruicheng Ma ◽  
Keliu Wu ◽  
Zhangxin Chen
Keyword(s):  
Polymer Solution ◽  
Oil Recovery ◽  
Polymer Concentration ◽  
Polymer Degradation ◽  
Polymer Flooding ◽  
Solution Viscosity ◽  
Physical Experiments ◽  
Simulation Results ◽  
The Difference ◽  
The Relationship

In this paper, physical and numerical simulations were applied to investigate the polymer degradation performance and its effect on polymer enhanced oil recovery (EOR) efficiency in homogeneous reservoirs. Physical experiments were conducted to determine basic physicochemical properties of the polymer, including viscosity, rheology, and degradation. A new mathematical model was proposed, and an in-house simulator was designed to further explore polymer degradation. The results of the physical experiments illustrated that polymer could increase polymer solution viscosity significantly, and the relationship between polymer solution viscosity and polymer concentration exhibited a clear power law relationship. However, the viscosity of a polymer solution with the same polymer concentration decreased with an increase in the shear rate, showing shear thinning performance. Moreover, the viscosity decreased with an increase in time, which was caused by polymer degradation. The validation of the designed simulator was improved when compared to the simulation results using ECLIPSE V2013.1 software. The difference between 0 and 0.1 day-1 in the polymer degradation rate showed a decrease of 6% in oil recovery after 2,000 days, according to simulation results, which demonstrated that polymer degradation had an adverse effect on polymer flooding efficiency.

scholarly journals Effect of Non-Newtonian Flow on Polymer Flooding in Heavy Oil Reservoirs

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1225 ◽  
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Zhangxin Chen ◽  
Keliu Wu ◽  
Xiaohu Dong ◽  
...  
Keyword(s):  
Porous Media ◽  
Polymer Solution ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Flow Behavior ◽  
Polymer Flooding ◽  
Oil Reservoirs ◽  
Flow In Porous Media ◽  
Newtonian Flow ◽  
Heavy Oil Reservoirs

The flow of polymer solution and heavy oil in porous media is critical for polymer flooding in heavy oil reservoirs because it significantly determines the polymer enhanced oil recovery (EOR) and polymer flooding efficiency in heavy oil reservoirs. In this paper, physical experiments and numerical simulations were both applied to investigate the flow of partially hydrolyzed polyacrylamide (HPAM) solution and heavy oil, and their effects on polymer flooding in heavy oil reservoirs. First, physical experiments determined the rheology of the polymer solution and heavy oil and their flow in porous media. Then, a new mathematical model was proposed, and an in-house three-dimensional (3D) two-phase polymer flooding simulator was designed considering the non-Newtonian flow. The designed simulator was validated by comparing its results with those obtained from commercial software and typical polymer flooding experiments. The developed simulator was further applied to investigate the non-Newtonian flow in polymer flooding. The experimental results demonstrated that the flow behavior index of the polymer solution is 0.3655, showing a shear thinning; and heavy oil is a type of Bingham fluid that overcomes a threshold pressure gradient (TPG) to flow in porous media. Furthermore, the validation of the designed simulator was confirmed to possess high accuracy and reliability. According to its simulation results, the decreases of 1.66% and 2.49% in oil recovery are caused by the difference between 0.18 and 1 in the polymer solution flow behavior indexes of the pure polymer flooding (PPF) and typical polymer flooding (TPF), respectively. Moreover, for heavy oil, considering a TPG of 20 times greater than its original value, the oil recoveries of PPF and TPF are reduced by 0.01% and 5.77%, respectively. Furthermore, the combined effect of shear thinning and a threshold pressure gradient results in a greater decrease in oil recovery, with 1.74% and 8.35% for PPF and TPF, respectively. Thus, the non-Newtonian flow has a hugely adverse impact on the performance of polymer flooding in heavy oil reservoirs.

scholarly journals Differences of microscopic seepage mechanisms of water flooding and polymer flooding and prediction models of final oil recovery for conglomerate reservoir

2019 ◽  
Vol 74 ◽  
pp. 13
Author(s):  
Fengqi Tan ◽  
Changfu Xu ◽  
Yuliang Zhang ◽  
Gang Luo ◽  
Yukun Chen ◽  
...  
Keyword(s):  
Pore Structure ◽  
Polymer Solution ◽  
Oil Recovery ◽  
Particle Surface ◽  
Polymer Flooding ◽  
Water Flooding ◽  
Residual Oil ◽  
Displacement Efficiency ◽  
Oil Saturation ◽  
Oil Displacement Efficiency

The special sedimentary environments of conglomerate reservoir lead to pore structure characteristics of complex modal, and the reservoir seepage system is mainly in the “sparse reticular-non reticular” flow pattern. As a result, the study on microscopic seepage mechanism of water flooding and polymer flooding and their differences becomes the complex part and key to enhance oil recovery. In this paper, the actual core samples from conglomerate reservoir in Karamay oilfield are selected as research objects to explore microscopic seepage mechanisms of water flooding and polymer flooding for hydrophilic rock as well as lipophilic rock by applying the Computed Tomography (CT) scanning technology. After that, the final oil recovery models of conglomerate reservoir are established in two displacement methods based on the influence analysis of oil displacement efficiency. Experimental results show that the seepage mechanisms of water flooding and polymer flooding for hydrophilic rock are all mainly “crawling” displacement along the rock surface while the weak lipophilic rocks are all mainly “inrushing” displacement along pore central. Due to the different seepage mechanisms among the water flooding and the polymer flooding, the residual oil remains in hydrophilic rock after water flooding process is mainly distributed in fine throats and pore interchange. These residual oil are cut into small droplets under the influence of polymer solution with stronger shearing drag effect. Then, those small droplets pass well through narrow throats and move forward along with the polymer solution flow, which makes enhancing oil recovery to be possible. The residual oil in weak lipophilic rock after water flooding mainly distributed on the rock particle surface and formed oil film and fine pore-throat. The polymer solution with stronger shear stress makes these oil films to carry away from particle surface in two ways such as bridge connection and forming oil silk. Because of the essential attributes differences between polymer solution and injection water solution, the impact of Complex Modal Pore Structure (CMPS) on the polymer solution displacement and seepage is much smaller than on water flooding solution. Therefore, for the two types of conglomerate rocks with different wettability, the pore structure is the main controlling factor of water flooding efficiency, while reservoir properties oil saturation, and other factors have smaller influence on flooding efficiency although the polymer flooding efficiency has a good correlation with remaining oil saturation after water flooding. Based on the analysis on oil displacement efficiency factors, the parameters of water flooding index and remaining oil saturation after water flooding are used to establish respectively calculation models of oil recovery in water flooding stage and polymer flooding stage for conglomerate reservoir. These models are able to calculate the oil recovery values of this area controlled by single well control, and further to determine the oil recovery of whole reservoir in different displacement stages by leveraging interpolation simulation methods, thereby providing more accurate geological parameters for the fine design of displacement oil program.

The Research on Effect Factors of the Polymer Flooding in Low Permeability Reservoir of Daqing Oilfield

2011 ◽  
Vol 383-390 ◽  
pp. 3809-3813
Author(s):  
Yong Li Wang ◽  
Tao Li ◽  
Zhi Guo Fu ◽  
Shu Xia Liu ◽  
Bai Lin Yu ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Injection Rate ◽  
Polymer Flooding ◽  
Low Permeability ◽  
Effect Factors ◽  
Field Development ◽  
Low Permeability Reservoir ◽  
Well Pattern ◽  
Simulation Results ◽  
Enhance Oil Recovery

The pilot block is a heterogeneous reservoir with low permeability which is only 100-200(mD). Polymer flooding will be used to enhance oil recovery (EOR). Therefore, some experiment will be carried out in this pilot block .According to the simulation results, we can infer the effect factors of the polymer flooding such as concentration, injection rate, slug amounts, and well pattern. It gives us effective information for the field development plan.

Experimental Investigation of the Heterogeneity Limit for the Application of Polymer Flooding in Reservoirs

2020 ◽  
Vol 143 (2) ◽  
Author(s):  
Mingchen Ding ◽  
Yugui Han ◽  
Yefei Wang ◽  
Yigang Liu ◽  
Dexin Liu ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Oil Recovery ◽  
Polymer Concentration ◽  
Experimental Information ◽  
Polymer Flooding ◽  
Polymer Injection ◽  
Low Concentration ◽  
Visual Models ◽  
Combined Use

Abstract It is generally accepted that polymer flooding gets less effective as the heterogeneity of a reservoir increases. However, very little experimental information or evidence has been collated to indicate which levels of heterogeneity correspond to reservoirs that can (and cannot) be efficiently developed using polymer flooding. Therefore, to experimentally determine a heterogeneity limit for the application of polymer flooding to reservoirs, a series of flow tests and oil displacements were conducted using parallel sand packs and visual models possessing different heterogeneities. For low-concentration polymer flooding (1.0 g/l), the limit determined corresponds to permeability contrasts (PCs) of 10.8 and 10.2, according to the parallel and visual tests, respectively. A significant increase in oil recovery can be achieved by polymer injection within these limits. Increasing the polymer concentration to 2.0 g/l increased these limiting PCs to 52.8 and 50.0, respectively. Additionally, within or beyond these limits, the combined use of polymer and gel may be the best.

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