scholarly journals A New Empirical Model for Viscosity of Sulfonated Polyacrylamide Polymers

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1046 ◽  
Author(s):  
Saeed Akbari ◽  
Syed Mohammad Mahmood ◽  
Hosein Ghaedi ◽  
Sameer Al-Hajri

Copolymers of acrylamide with the sodium salt of 2-acrylamido-2-methylpropane sulfonic acid—known as sulfonated polyacrylamide polymers—had been shown to produce very promising results in the enhancement of oil recovery, particularly in polymer flooding. The aim of this work is to develop an empirical model through the use of a design of experiments (DOE) approach for bulk viscosity of these copolymers as a function of polymer characteristics (i.e., sulfonation degree and molecular weight), oil reservoir conditions (i.e., temperature, formation brine salinity and hardness) and field operational variables (i.e., polymer concentration, shear rate and aging time). The data required for the non-linear regression analysis were generated from 120 planned experimental runs, which had used the Box-Behnken construct from the typical Response Surface Methodology (RSM) design. The data were collected during rheological experiments and the model that was constructed had been proven to be acceptable with the Adjusted R-Squared value of 0.9624. Apart from showing the polymer concentration as being the most important factor in the determination of polymer solution viscosity, the evaluation of the model terms as well as the Sobol sensitivity analysis had also shown a considerable interaction between the process parameters. As such, the proposed viscosity model can be suitably applied to the optimization of the polymer solution properties for the polymer flooding process and the prediction of the rheological data required for polymer flood simulators.

2018 ◽  
Vol 187 ◽  
pp. 01006
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Ruicheng Ma ◽  
Keliu Wu ◽  
Zhangxin Chen

In this paper, physical and numerical simulations were applied to investigate the polymer degradation performance and its effect on polymer enhanced oil recovery (EOR) efficiency in homogeneous reservoirs. Physical experiments were conducted to determine basic physicochemical properties of the polymer, including viscosity, rheology, and degradation. A new mathematical model was proposed, and an in-house simulator was designed to further explore polymer degradation. The results of the physical experiments illustrated that polymer could increase polymer solution viscosity significantly, and the relationship between polymer solution viscosity and polymer concentration exhibited a clear power law relationship. However, the viscosity of a polymer solution with the same polymer concentration decreased with an increase in the shear rate, showing shear thinning performance. Moreover, the viscosity decreased with an increase in time, which was caused by polymer degradation. The validation of the designed simulator was improved when compared to the simulation results using ECLIPSE V2013.1 software. The difference between 0 and 0.1 day-1 in the polymer degradation rate showed a decrease of 6% in oil recovery after 2,000 days, according to simulation results, which demonstrated that polymer degradation had an adverse effect on polymer flooding efficiency.


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Hong-sheng Liu ◽  
Jing-qin Wang ◽  
Li Yang ◽  
Dong-yang Jiang ◽  
Chang-sen Lv ◽  
...  

In order to study the effects of oil displacement by a foam system of ultralow interfacial tension, the interfacial activities and foam properties of a nonionic gemini surfactant (DWS) were investigated under Daqing Oilfield reservoir conditions. Injection methods and alternate cycle of the foam system were discussed here on the basis of results from core flow experiments. It was obtained that the surface tension of DWS was approximately 25 mN/m, and ultralow interfacial tension was reached between oil and DWS with a surfactant concentration between 0.05wt% and 0.4wt%. The binary system showed splendid foam performances, and the preferential surfactant concentration was 0.3wt% with a polymer concentration of 0.2wt%. When gas and liquid were injected simultaneously, flow control capability of the foam reached its peak at the gas-liquid ratio of 3 : 1. Enhanced oil recovery factor of the binary foam system exceeded 10% in a parallel natural cores displacement after polymer flooding.


Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 857 ◽  
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Zhangxin Chen ◽  
Keliu Wu ◽  
Xiaohu Dong ◽  
...  

Polymer degradation is critical for polymer flooding because it can significantly influence the viscosity of a polymer solution, which is a dominant property for polymer enhanced oil recovery (EOR). In this work, physical experiments and numerical simulations were both used to study partially hydrolyzed polyacrylamide (HPAM) degradation and its effect on polymer flooding in heterogeneous reservoirs. First, physical experiments were conducted to determine basic physicochemical properties of the polymer, including viscosity and degradation. Notably, a novel polymer dynamic degradation experiment was recommended in the evaluation process. Then, a new mathematical model was proposed and an in-house three-dimensional (3D) two-phase polymer flooding simulator was designed to examine both polymer static and dynamic degradation. The designed simulator was validated by comparison with the simulation results obtained from commercial software and the results from the polymer flooding experiments. This simulator further investigated and validated polymer degradation and its effect. The results of the physical experiments showed that the viscosity of a polymer solution increases with an increase in polymer concentration, demonstrating their underlying power law relationship. Moreover, the viscosity of a polymer solution with the same polymer concentration decreases with an increase in the shear rate, demonstrating shear thinning. Furthermore, the viscosity of a polymer solution decreased with an increase in time due to polymer degradation, exhibiting an exponential relationship. The first-order dynamic degradation rate constant of 0.0022 day−1 was greater than the first-order static degradation rate constant of 0.0017 day−1. According to the simulation results for the designed simulator, a 7.7% decrease in oil recovery, after a cumulative injection volume of 1.67 pore volume (PV) was observed between the first-order dynamic degradation rate constants of 0 and 0.1 day−1, which indicates that polymer degradation has a detrimental effect on polymer flooding efficiency.


2012 ◽  
Vol 512-515 ◽  
pp. 2439-2442 ◽  
Author(s):  
Yan Wang ◽  
Bao Wei Su ◽  
Xue Li Gao

Polyacrylamide (PAM) is an important polymer for oilfield flooding. The viscosity of PAM solution is very significant for polymer flooding to enhance oil recovery. The main factors which influence viscosity of PAM solution including polymer concentration, temperature, stirring rate, TDS and divalent cation ions were studied. The results showed that high stirring rate will reduce the viscosity of PAM solution; and the viscosity decreases gradually with temperature increasing; TDS and divalent cation ions also affect the viscosity of polymer solution greatly, the viscosity loss is more than 3% with the TDS increases by 1000 mg/L under the same concentration of divalent cation ions; the viscosity loss is around 20% with the concentration of divalent cation ions increase by 100 mg/L.


SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2260-2278 ◽  
Author(s):  
R. S. Seright ◽  
Dongmei Wang ◽  
Nolan Lerner ◽  
Anh Nguyen ◽  
Jason Sabid ◽  
...  

Summary This paper examines oil displacement as a function of polymer-solution viscosity during laboratory studies in support of a polymer flood in Canada's Cactus Lake Reservoir. When displacing 1,610-cp crude oil from field cores (at 27°C and 1 ft/D), oil-recovery efficiency increased with polymer-solution viscosity up to 25 cp (7.3 seconds−1). No significant benefit was noted from injecting polymer solutions more viscous than 25 cp. Much of this paper explores why this result occurred. Floods in field cores examined relative permeability for different saturation histories, including native state, cleaned/water-saturated first, and cleaned/oil-saturated first. In addition to the field cores and crude oil, studies were performed using hydrophobic (oil-wet) polyethylene cores and refined oils with viscosities ranging from 2.9 to 1,000 cp. In field cores, relative permeability to water (krw) remained low, less than 0.03 for most corefloods. After extended polymer flooding to water saturations up to 0.865, krw values were less than 0.04 for six of seven corefloods. Relative permeability to oil remained reasonably high (greater than 0.05) for most of the flooding process. These observations help explain why 25-cp polymer solutions were effective in recovering 1,610-cp oil. The low relative permeability to water allowed a 25-cp polymer solution to provide a nearly favorable mobility ratio. At a given water saturation, krw values for 1,000-cp crude oil were approximately 10 times lower than for 1,000-cp refined oil. In contrast to results found for the Daqing polymer flood (Wang et al. 2000, 2011), no evidence was found in our application that high-molecular-weight (MW) hydrolyzed polyacrylamide (HPAM) solutions mobilized trapped residual oil. The results are discussed in light of ideas expressed in recent publications. The relevance of the results to field applications is also examined. Although 25-cp polymer solutions were effective in displacing oil during our corefloods, the choice of polymer viscosity for a field application must consider reservoir heterogeneity and the risk of channeling in a reservoir.


1971 ◽  
Vol 11 (01) ◽  
pp. 72-84 ◽  
Author(s):  
J.T. Patton ◽  
K.H. Coats ◽  
G.T. Colegrove

Patton, J.T., Member AIME, Patton, J.T., Member AIME, Computer/Bioengineering Institute, Inc., Houston, Tex. Coats, K.H., Member AIME, International Computer Applications Ltd., Houston, Tex. Colegrove, G.T., Kelco Co., Houston, Tex. Abstract This experimental and numerical study was performed to estimate the incremental oil recovery performed to estimate the incremental oil recovery by pattern polymer flooding in a California viscous-oil reservoir. Results indicate that adding 270-ppm Kelzan to the normal flood water will boost oil production by 42 percent (at 1 PV injected) and production by 42 percent (at 1 PV injected) and will reduce water handling costs sharply. This corresponds to $8.35 incremental oil/$1.00 polymer injected, taking into account the 30 percent pore volume bank of polymer solution. The 28.6 percent additional oil recovery predicted at 0.5 PV injected yields a return of $4.60 incremental oil/$1.00 polymer injected. polymer injected. The field predictions are based onlaboratory measurements of polymer solution viscosity, adsorption and dispersion upon displacement by normal water in a sand representative of the reservoir,linear laboratory oil displacement experiments using brine and polymer solution, anda numerical model developed to simulate linear or five-spot polymer floods in single-layer or stratified reservoirs. The paper presents an analytical solution to the linear polymer flood problem, which provides a check on accuracy of the numerical model and a quick estimate of additional oil recovery by line-drive polymer floods. The numerical model developed indicates that additional oil recovery by polymer flooding is sensitive to polymer bank size polymer flooding is sensitive to polymer bank size and adsorption level and is insensitive to the extent of dispersion active at the trailing edge of the polymer slug. polymer slug Introduction The benefits of improving the mobility ratio, lambda o/lambda w, on waterflood performance is well documented and research on how best to effect this improvement has been considerable. Both producers and chemical manufacturers, spurred on producers and chemical manufacturers, spurred on by the vast reserves of oil which will be otherwise abandoned, have sought to resolve the problem. Currently, two types of additives are being marketed and field tested with promising results. Both additives increase oil recovery by lowering the mobility of the flood water, lambda w. However, they effect this lowering by distinctly different mechanisms. Mobility of the flood water is given by: lambdaw = kw/ w . Hence, one may elect to either increase viscosity, mu w, or decrease effective permeability, kw. Viscosity can be increased by adding small amounts of a water-soluble polymer. To be effective at the flood front this additive should exhibit minimum adsorption on the pore surfaces. Polymers showing minimal adsorption are generally a combination nonionic-anionic type. The negative charge repels the clay platelets to reduce adsorption and the nonionic portion provides the brine tolerance required for reservoir applications. A polymer of this type, Kelzan M, was chosen for the study. The alternate method of lowering mobility is equally well known. It consists of adding to the flood water a polymer designed to adsorb on the pore surfaces, thereby physically reducing the available flow area. This study was performed to estimate the additional oil recovery by pattern polymer flooding using Kelzan in a California viscous-oil reservoir. Laboratory experiments were performed to estimate polymer solution viscosity, adsorption and polymer solution viscosity, adsorption and dispersion upon displacement by normal injection water. Waterflood and polymer flood oil recovery curves were obtained for a laboratory core packed with sand representative of the reservoir. A numerical model was developed to simulate polymer floods in linear or five-spot patterns in single-layer or stratified reservoirs. An analytical solution to the linear polymer flood problem was developed to provide a quick estimate of incremental oil provide a quick estimate of incremental oil obtainable by polymer flooding and to provide a check on the accuracy of the numerical model. SPEJ P. 72


2020 ◽  
Vol 20 (6) ◽  
pp. 1382
Author(s):  
Tengku Amran Tengku Mohd ◽  
Shareena Fairuz Abdul Manaf ◽  
Munawirah Abd Naim ◽  
Muhammad Shafiq Mat Shayuti ◽  
Mohd Zaidi Jaafar

Polymer flooding could enhance the oil recovery by increasing the viscosity of water, thus, improving the mobility control and sweep efficiency. It is essential to explore natural sources of polymer, which is biologically degradable and negligible to environmental risks. This research aims to produce a biodegradable polymer from terrestrial mushroom, analyze the properties of the polymer and investigate the oil recovery from polymer flooding. Polysaccharide biopolymer was extracted from mushroom and characterized using Fourier Transform Infrared Spectrometer (FTIR), while the polymer viscosity was investigated using an automated microviscometer. The oil recovery tests were conducted at room temperature using a sand pack model. It was found that polymer viscosity increases with increasing polymer concentration and decreases when increase in temperature, salinity, and concentration of divalent ions. The oil recovery tests showed that a higher polymer concentration of 3000 ppm had recovered more oil with an incremental recovery of 25.8% after waterflooding, while a polymer concentration of 1500 pm obtained incremental 22.2% recovery of original oil in place (OOIP). The oil recovery from waterflooding was approximately 25.4 and 24.2% of the OOIP, respectively. Therefore, an environmentally friendly biopolymer was successfully extracted, which is potential for enhanced oil recovery (EOR) application, but it will lose its viscosity performance at certain reservoir conditions.


2013 ◽  
Vol 807-809 ◽  
pp. 2607-2611
Author(s):  
Byung In Choi ◽  
Moon Sik Jeong ◽  
Kun Sang Lee

Water salinity and hardness have been regarded as main limitation for field application of polymer floods. It causes not only reduction of polymer concentration, but also injectivity loss in the near wellbore. Based on the mathematical and chemical theory, extensive numerical simulations were conducted to investigate performance of polymer floods in the high-salinity reservoirs. According to results from simulations, the high salinity reduces the viscosity of polymer in contacting area. That causes a poor sweep efficiency of polymer flooding. Moreover, the presence of divalent cations makes the project of polymer flooding worse. That is because of excessively increased bottom-hole pressure in injection well by the precipitation of polymer. The quantitative assessment of polymer floods needs to be required before field application. Therefore, the results in this paper are helpful for optimal polymer flooding design under harsh reservoir conditions.


Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1225 ◽  
Author(s):  
Xiankang Xin ◽  
Gaoming Yu ◽  
Zhangxin Chen ◽  
Keliu Wu ◽  
Xiaohu Dong ◽  
...  

The flow of polymer solution and heavy oil in porous media is critical for polymer flooding in heavy oil reservoirs because it significantly determines the polymer enhanced oil recovery (EOR) and polymer flooding efficiency in heavy oil reservoirs. In this paper, physical experiments and numerical simulations were both applied to investigate the flow of partially hydrolyzed polyacrylamide (HPAM) solution and heavy oil, and their effects on polymer flooding in heavy oil reservoirs. First, physical experiments determined the rheology of the polymer solution and heavy oil and their flow in porous media. Then, a new mathematical model was proposed, and an in-house three-dimensional (3D) two-phase polymer flooding simulator was designed considering the non-Newtonian flow. The designed simulator was validated by comparing its results with those obtained from commercial software and typical polymer flooding experiments. The developed simulator was further applied to investigate the non-Newtonian flow in polymer flooding. The experimental results demonstrated that the flow behavior index of the polymer solution is 0.3655, showing a shear thinning; and heavy oil is a type of Bingham fluid that overcomes a threshold pressure gradient (TPG) to flow in porous media. Furthermore, the validation of the designed simulator was confirmed to possess high accuracy and reliability. According to its simulation results, the decreases of 1.66% and 2.49% in oil recovery are caused by the difference between 0.18 and 1 in the polymer solution flow behavior indexes of the pure polymer flooding (PPF) and typical polymer flooding (TPF), respectively. Moreover, for heavy oil, considering a TPG of 20 times greater than its original value, the oil recoveries of PPF and TPF are reduced by 0.01% and 5.77%, respectively. Furthermore, the combined effect of shear thinning and a threshold pressure gradient results in a greater decrease in oil recovery, with 1.74% and 8.35% for PPF and TPF, respectively. Thus, the non-Newtonian flow has a hugely adverse impact on the performance of polymer flooding in heavy oil reservoirs.


2013 ◽  
Vol 275-277 ◽  
pp. 496-501
Author(s):  
Fu Qing Yuan ◽  
Zhen Quan Li

According to the geological parameters of Shengli Oilfield, sweep efficiency of chemical flooding was analyzed according to injection volume, injection-production parameters of polymer flooding or surfactant-polymer compound flooding. The orthogonal design method was employed to select the important factors influencing on expanding sweep efficiency by chemical flooding. Numerical simulation method was utilized to analyze oil recovery and sweep efficiency of different flooding methods, such as water flooding, polymer flooding and surfactant-polymer compound flooding. Finally, two easy calculation models were established to calculate the expanding degree of sweep efficiency by polymer flooding or SP compound flooding than water flooding. The models were presented as the relationships between geological parameters, such as effective thickness, oil viscosity, porosity and permeability, and fluid parameters, such as polymer-solution viscosity and oil-water interfacial tension. The precision of the two models was high enough to predict sweep efficiency of polymer flooding or SP compound flooding.


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