The Effect of Biomass Contents with Heavy Metal on Gasification Efficiency during Fluidized Bed Gasification Process

2012 ◽  
Vol 512-515 ◽  
pp. 575-578
Author(s):  
Hsien Chen ◽  
Chiou Liang Lin ◽  
Wun Yue Zeng ◽  
Zi Bin Xu

Catalysis was used to increase the H2 production, syngas heating value, enhanced carbon conversion efficiency and cold gas efficiency during gasification. Due to Cu and Zn were abundant in waste according to previous researches, this research discussed the effect of Cu and Zn on artificial waste gasification. The syngas composition and total lower heating value (LHV) were determined in this study. The results showed that the existence of Cu and Zn increased production of H2 and CO. However, the production of CH4 and CO2 decreased. At same time, total LHV was also increased. Additionally, the different Cu concentration affected gas composition and LHV, but the effect of Zn concentration was not significant.

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7384
Author(s):  
M. Shahabuddin ◽  
Sankar Bhattacharya

This study assessed the entrained flow co-gasification characteristics of coal and biomass using thermodynamic equilibrium modelling. The model was validated against entrained flow gasifier data published in the literature. The gasification performance was evaluated under different operating conditions, such as equivalence ratio, temperature, pressure and coal to biomass ratio. It is observed that the lower heating value (LHV) and cold gas efficiency (CGE) increase with increasing temperature until the process reaches a steady state. The effect of pressure on syngas composition is dominant only at non-steady state conditions (<1100 °C). The variation in syngas composition is minor up to the blending of 50% biomass (PB50). However, the PB50 shows a higher LHV and CGE than pure coal by 12%and 18%, respectively. Overall, biomass blending of up to 50% favours gasification performance with an LHV of 12 MJ/kg and a CGE of 78%.


Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2081
Author(s):  
Md Tanvir Alam ◽  
Se-Won Park ◽  
Sang-Yeop Lee ◽  
Yean-Ouk Jeong ◽  
Anthony De Girolamo ◽  
...  

Solid recovered fuel (SRF) residue, which is leftovers from the SRF manufacturing process, usually is discarded in landfill because of its low heating value and high ash and moisture content. However, it could be used as a fuel after mechanical and biological treatment. Gasification experiments were conducted on treated SRF residue (TSRFR) to assess the viability of syngas production. Efforts were also made to improve the gasification performance by adding low-cost natural minerals such as dolomite and lime as bed material, and by blending with biomass waste. In the case of additive mineral tests, dolomite showed better performance compared to lime, and in the case of biomass blends, a 25 wt% pine sawdust blend with TSRFR showed the best performance. Finally, as an appropriate condition, a combined experiment was conducted at an equivalence ratio (ER) of 0.2 using a 25 wt% pine sawdust blend with TSRFR as a feedstock and dolomite as the bed material. The highest dry gas yield (1.81 Nm3/kg), with the highest amount of syngas (56.72 vol%) and highest lower heating value (9.55 MJ/Nm3) was obtained in this condition. Furthermore, the highest cold gas efficiency (48.64%) and carbon conversion rate (98.87%), and the lowest residue yield (11.56%), tar (0.95 g/Nm3), and gas pollutants content was observed.


2012 ◽  
Vol 66 (7) ◽  
Author(s):  
Afsin Gungor ◽  
Murat Ozbayoglu ◽  
Cosku Kasnakoglu ◽  
Atilla Biyikoglu ◽  
Bekir Uysal

AbstractIn this parametric study, the effects of coal and oxidiser type, air-to-fuel ratio, steam-to-fuel ratio, reactor temperature, and pressure on H2 and CO amounts at the gasifier output, H2/CO, and higher heating value of the syngas produced have been calculated using a coal gasification model. Model simulations have been performed to identify the optimum values which are assumed to be 100 % for both cold gas efficiency and carbon conversion efficiency in the gasification process. From this study, it may be observed that the moisture content of the coal type is of crucial importance for the air gasification process; the O2 content of similar coals (taking into consideration the moisture and H2 content) is of significant importance for the air gasification process. When compared with air gasification, air-steam gasification becomes a more effective coal gasification method. The optimum working condition for air-steam gasification is to carry out the process at one atmosphere. High gasifier temperatures are not needed for the air-steam gasification of coal.


2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Ahmad F ◽  
◽  
Ahmad N ◽  
Asghar U ◽  
Ali A ◽  
...  

Converting rice husk into energy is a promising method of generating renewable energy and reducing greenhouse gas emissions. In this research rice hush is considered as biomass fuel. The characteristics of rice husk gasification were investigated at an Equivalence Ratio (ER) of 0.25–0.38 and a gasifier temperature of 750-870°C in 20 tons per day (TPD) using steam explosion process in fluidized bed gasifier system. Different operation conditions, temperatures and loads, are investigated for their effects on the compositions, calorific properties, gasification efficiencies of syngas. The effects of the critical parameters, namely, Steam-to-Biomass Ratio (S/B), Particle size variation and gasification temperature on the quality of the product gas as well as the gasifier cold gas efficiency were analyzed. This is the new finding in the research. The optimal conditions of the gasification operation were an ER of 0.20 and gasifier temperature of 800°C. The low heating value of the gas product and cold gas efficiency were 1390kcal/Nm³ and 75%, respectively. After passing the generated gas through the gas cleaning units, it was confirmed that the tar in the product gas was removed with an efficiency of 98%. The cleaned product gas was used for the operation of 420kW, gas engine. Pressure loss often occurred at the bottom of the gasifier during the gasification operation; we found that the agglomerates generated by the gasification process caused it. To prevent the pressure loss caused by the agglomerates, the stable control of temperature inside the gasifier is needed and an ash removal device remove agglomerates should be installed to maintain stable long-term operation. This paper leads towards the production of Syngas and further on the electricity from the rice husk, an eminent biomass, copiously available all around the world. Especially in Pakistan, the rice is used abundantly so the raw material is easily available. The gas is produced using the gasification process in dual fluidized gasifier. It is a wonderful alternative to the natural gas with high calorific value. The sulfur contents are quite less compared to natural gas. It also have a good correlation with environment as flue gases emission is negligible relative to other source like coal, wood, plastic, waste etc. Another benefit of this process is the waste management and pollution control. The results are developed by using the detailed analysis of the process values of plants which is generating electricity by rice husk gasification. We learned, all results revealed that the dual fluidized bed gasification is more economical and efficient method compared to all other methods for commercial scale production of syngas. Results are analyzed which imply that the biomass is more gigantic source which replace the fossil fuels and leads towards the green energy in a more economical way. This paper provides an overview of previous works on combustion and gasification of rice husk in atmospheric fluiuidized bed reactors and summarizes the state of the art knowledge. As the high ash content, low bulk density, p characteristics and low ash melting point makes the other types of reactors like grate furnaces and downdraft gasifers either inefficient or unsuitable for rice husk conversion to energy, the fluiuidized bed reactor seems to be the promising choice. The overview shows that the reported results are from only small bench or lab scale units. Although a combustion efficiency of about 80% can normally be attained; the reported values in the literature, which are more than 95%, seem to be in higher order. Combustion intensity of about 530kg/h/m² is reported. It is also technically feasible to gasify rice husk in a fluidized bed reactor to yield combustible producer gas, even with sufficient heating value for application in internal combustion engines.


Author(s):  
Ghulamullah Maitlo ◽  
Rasool Bux Mahar ◽  
Khan Mohammad Brohi

Gasification of coal and biomass using CO2 and air mixture as a carrier gas offers an encouraging way to eliminate the shortage of energy and reduce carbon dioxide emissions. In the present study, the EulerianLagrangian approach was applied to understand the thermochemical conversion behavior of feedstock in entrained flow gasifier. Commercial CFD (Computational Fluid Dynamics) code ANSYS FLUENT®14 was used for the simulation purpose. It was observed that with variation in the CO2 in the air and the CO2 to cotton stalk ratio had a meaningful effect on gasification performance. The different ratios of air and CO2 in varying percentages such as 20% CO2, 30% CO2, 40% CO2, 50% CO2, 60% CO2, 70% CO2 and remaining percentages of air were introduced in entrained flow gasifier. With the increase in CO2 to cotton stalk ratio, the concentration of H2 and CO2 decreased whereas as the concentration of CO improved. It is revealed that mole fraction of CO and CH4 attained maximum when CO2% in the air was 50% and H2 mole fraction was observed maximum at a CO2% in the air was 30%. At 50% CO2 mixture in air, the maximum lower heating value and cold gas efficiency were observed. Therefore, the optimum situation might be 50% percentage CO2 in the gasifying agent for this entrained flow gasifier. Hence an increase in CO and H2, the cold gas efficiency and lower heating value reached the maximum. However, this study provides an appropriate route for energy production using cotton stalks as raw material and will help in designing and operation of the entrained flow reactor. The simulations indicate the thermodynamic limits of gasification and allow for the formulation of the general principles ruling this process. Moreover, no literature is available for the parametric investigations of Pakistani biomass gasification using entrained-flow gasifier. So this is a novel work for Pakistan and will be treated as foundation work for biomass gasification in the country.


2020 ◽  
Vol 10 (1) ◽  
pp. 1-10
Author(s):  
Fadilla Noor Rahma ◽  
Cholila Tamzysi ◽  
Arif Hidayat ◽  
Muflih Arisa Adnan

Integration of gasification with CO2 capture using CaO sorbent is proposed as an alternative treatment to convert municipal solid waste (MSW) into energy. Aspen Plus process simulator was employed to study the process. Two models were built to represent the non-sorbent and the sorbent-enabled MSW gasification. The model validation against available experimental data shows high accuracy of the simulation result. The effect of CO2 capture using CaO sorbent on the syngas composition and lower heating value (LHV) was observed by comparing the two models, and sensitivity analysis was performed on both models. Several process parameters affecting the syngas composition and LHV were investigated, including CaO/MSW ratio, temperature, equivalence ratio, and steam/MSW ratio. The addition of CaO sorbent for CO2 capture was found to successfully reduce the CO2 content in the syngas, increase the H2 composition, and improve the syngas LHV at the temperature below 750 oC. The maximum H2 composition of 56.67% was obtained from the sorbent-enabled gasification. It was found that increasing equivalence ratio leads to a higher H2 concentration and syngas LHV. Raising steam/MSW ratio also increases the H2 production, but also reduces the LHV of the syngas. Observation of the temperature effect found the highest H2 production at 650 oC for both non-sorbent and sorbent-enabled gasification. 


2020 ◽  
Vol 143 (5) ◽  
Author(s):  
Krongkaew Laohalidanond ◽  
Somrat Kerdsuwan ◽  
Kiran Raj Goud Burra ◽  
Jinhu Li ◽  
Ashwani K. Gupta

Abstract Landfill reclamation is a good solution to utilize the wasted land occupied by municipal solid waste dumpsites or landfill sites. This also offers a good means to recover valuable materials and form environmentally benign green refuse-derived fuel (RDF) for use in power production. However, due to the heterogenous composition of the wastes, it is crucial to homogenize and upgrade the waste hydrocarbon fuel properties. Torrefaction is a thermochemical process that utilizes low temperature and inert environment to drive off the moisture and volatile fractions present in wastes to form valuable fuel. This upgraded RDF from reclaimed landfills offer high energy density and favorable hydrophobicity for use as a fuel feedstock in gasification to produce syngas for power generation. The objectives of this study are to first upgrading the reclaimed landfill wastes to RDF using torrefaction followed by its conversion to form clean syngas in a downdraft gasifier. This study examines the effect of air ratio on syngas heating value and cold gas efficiency. A comparison is made on the syngas produced from gasification using reclaimed landfill wastes and torrefied RDF. Experiments were conducted using a 10 kg/h lab-scale downdraft gasifier. The air ratios examined were 0.22, 0.27, and 0.32. The results showed an optimum air ratio of 0.27 operated with a gasifier using torrefied RDF. The results showed improved syngas quality, in terms of syngas composition, lower heating value, and cold gas efficiency. The lower heating value of 4.22 MJ/Nm3 and the cold gas efficiency of 65.84% were achieved. The results showed that landfill mining can provide ultimate solution to get rid of dumped wastes from landfills using torrefaction for high-quality fuel followed by the recovery of green and clean syngas energy using gasification.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
L. F. Calvo ◽  
A. I. García ◽  
M. Otero

The gasification of sewage sludge was carried out in a simple atmospheric fluidized bed gasifier. Flow and fuel feed rate were adjusted for experimentally obtaining an air mass : fuel mass ratio (A/F) of0.2<A/F<0.4. Fuel characterization, mass and power balances, produced gas composition, gas phase alkali and ammonia, tar concentration, agglomeration tendencies, and gas efficiencies were assessed. Although accumulation of material inside the reactor was a main problem, this was avoided by removing and adding bed media along gasification. This allowed improving the process heat transfer and, therefore, gasification efficiency. The heating value of the produced gas was 8.4 MJ/Nm, attaining a hot gas efficiency of 70% and a cold gas efficiency of 57%.


Author(s):  
Nabila Aprianti ◽  
Muhammad Faizal ◽  
Muhammad Said ◽  
Subriyer Nasir

Oil palm empty fruit bunch (OPEFB is one of the enormous waste expected to become a renewable energy source. This study aimed to convert OPEFB into syngas through a gasification process using bentonite as a catalyst. The effects of temperature and product gas catalysts were investigated, and the efficiency of the gasification process was summarized. The process has used an updraft gasifier at 350-550 °C and air as the gasification medium (ER 0.2). The results indicate that syngas can be produced by updraft gasifier. When the temperature increase, the H2 and CO rising. The highest H2 and CO content of 27.74% and 20.43% are obtained at 550°C when bentonite applied. HHV and LHV range of 3.38~12.79 MJ/Nm3 and 3.03~11.58 MJ/Nm3, respectively. The maximum carbon conversion efficiency (CCE) and cold gas efficiency (CGE) reach 85.49% and 82.34%. Bentonite has been able to increase the concentration of the gas composition especially H2 and CO and the heating value of syngas.


Author(s):  
Miaomiao Niu ◽  
Baosheng Jin ◽  
Yaji Huang ◽  
Hongyan Wang ◽  
Qing Dong ◽  
...  

Abstract Gasification is a promising technology to utilize solid wastes. Co-gasification of high-ash sewage sludge and straw were studied in a fluidized bed using oxygen-enriched air. Several factors influencing co-gasification performance were investigated, including the blending ratio of straw (BR, 0–100 %), the oxygen percentage of enriched air (OP, 30.2–50 %) and the bed material type (high alumina bauxite, calcined dolomite and olivine). The results indicated that the proper increase in BR led to higher syngas yield and an increase in OP caused an increase in combustible gas components, both showing improvements for waste gasification. Correspondingly, the maximum cold gas efficiency was obtained at BR of 50 % and OP of 44.7 %, respectively. Additionally, calcined dolomite exhibited the maximum advantage in the reduction of heavy polycyclic aromatic hydrocarbons (PAHs), promoting the production of H2 and CO. The addition of high alumina bauxite was favored for improving syngas yield and gasification efficiency.


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