Zeta Potential of Stable Oxidative Poly-Si-Fe (SOPSF) Coagulant

2012 ◽  
Vol 518-523 ◽  
pp. 150-153
Author(s):  
Ying Fu ◽  
Nan Shi ◽  
Hong Lan Li
Keyword(s):  
Zeta Potential ◽  
Isoelectric Point ◽  
Polysilicic Acid ◽  
Zeta Potentials

Characteristics of Zeta potential of a stable oxidative poly-Si-Fe (SOPSF) coagulant was studied with Nano Zetasizer, in comparison with that of polyferric aluminum (PFA). The results showed that the reaction between polysilicic acid (PS) negative charged and Fe positive charged is complicated, instead of a simple electro neutrality process. The Zeta potentials of SOPSF are almost near to the isoelectric point at higher concentration, while the Zeta potential of PFA is about 20 times that of SOPSF carrying negative charges at the same concentration. But after dilution, the Zeta potential of SOPSF is about equivalent to that of PFA.

The zeta potential of kaolin suspensions measured by electrophoresis and electroacoustics

2007 ◽  
Vol 61 (2) ◽  
Author(s):  
R. Greenwood ◽  
B. Lapčíková ◽  
M. Surýnek ◽  
K. Waters ◽  
L. Lapčík
Keyword(s):  
Zeta Potential ◽  
Isoelectric Point ◽  
Anionic Surfactant ◽  
Sodium Dodecyl ◽  
Isomorphic Substitution ◽  
Concentrated Suspensions ◽  
Concentrated Suspension ◽  
Zeta Potentials ◽  
Maximum Value ◽  
Triton X

AbstractThe zeta potentials of kaolin dilute and concentrated suspensions were monitored using the techniques of electrophoresis and electroacoustics, respectively. The effect of addition of salt (KCl), a polymer material (Triton X-100), and an anionic surfactant (sodium dodecyl sulphate, SDS) on the suspension properties was investigated by electrophoresis. Electroacoustics was employed for the measurement of zeta potentials for the highest possible kaolin content in suspension and the effect of dilution. The effect of aging of a freshly prepared sample and kaolin isoelectric point was also studied. Using both techniques it was noted that there was no isoelectric point, just a maximum value in the magnitude of the kaolin suspension zeta potential. These maxima were observed also in the presence of Triton X-100 and SDS. An increase of the concentration of KCl and SDS in suspension shifted the maxima towards more acidic values, while in the presence of Triton X-100 the position of the zeta potential maxima remained constant. Electroacoustic techniques revealed that a freshly prepared concentrated suspension requires about six hours to equilibrate to achieve a steady zeta potential. Diluting the concentrated suspensions led to decrease of the zeta potential as ions bound to the surface desorbed and screened the surface charge. The zeta potential maxima remained unchanged even after heating the powder in an oven at 200°C (to remove any organic material) thereby suggesting that the most likely explanation for the maxima is isomorphic substitution.

Surface behaviour of Bacterium coli - I. The nature of the surface

1956 ◽  
Vol 145 (920) ◽  
pp. 375-383 ◽  
Keyword(s):  
Zeta Potential ◽  
Isoelectric Point ◽  
Electrolyte Concentration ◽  
Surface Ph ◽  
Zeta Potentials ◽  
Naturally Occurring ◽  
Zero Potential ◽  
Common Anion

Using a microelectrophoretic method the zeta potentials of Bacterium coli suspended in a series of inorganic electrolytes having either a common anion or cation have been determined. By experiment, or extrapolation to zero potential of the curve of zeta potential against log 10 [electrolyte concentration], it has been possible to find the concentration (normality) of each electrolyte required to neutralize exactly the charge on the cells. For cations with common anions and vice versa, the ‘reversal of charge concentrations’ have been plotted in the form of spectra. Comparison with similar spectra given in Kruyt (1949 a ) for some naturally occurring substances has indicated that the exterior of the cells is polysaccharide, possibly an arabate. This conclusion is supported by the pK and isoelectric point derived from the curve of zeta potential against surface pH, and also by the relatively low zeta potentials exhibited by Bact. coli in detergents compared with the corresponding values for lipoidal substances.

scholarly journals Manipulation of surface charges of oil droplets and carbonate rocks to improve oil recovery

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jian Hou ◽  
Ming Han ◽  
Jinxun Wang
Keyword(s):  
Zeta Potential ◽  
Oil Recovery ◽  
Carbonate Rocks ◽  
Zwitterionic Surfactant ◽  
Surface Charges ◽  
Oil Droplets ◽  
Zeta Potentials ◽  
Potential Value ◽  
Oil Water ◽  
Incremental Oil Recovery

AbstractThis work investigates the effect of the surface charges of oil droplets and carbonate rocks in brine and in surfactant solutions on oil production. The influences of the cations in brine and the surfactant types on the zeta-potentials of both oil droplets and carbonate rock particles are studied. It is found that the addition of anionic and cationic surfactants in brine result in both negative or positive zeta-potentials of rock particles and oil droplets respectively, while the zwitterionic surfactant induces a positive charge on rock particles and a negative charge on oil droplets. Micromodels with a CaCO3 nanocrystal layer coated on the flow channels were used in the oil displacement tests. The results show that when the oil-water interfacial tension (IFT) was at 10−1 mN/m, the injection of an anionic surfactant (SDS-R1) solution achieved 21.0% incremental oil recovery, higher than the 12.6% increment by the injection of a zwitterionic surfactant (SB-A2) solution. When the IFT was lowered to 10−3 mM/m, the injection of anionic/non-ionic surfactant SMAN-l1 solution with higher absolute zeta potential value (ζoil + ζrock) of 34 mV has achieved higher incremental oil recovery (39.4%) than the application of an anionic/cationic surfactant SMAC-l1 solution with a lower absolute zeta-potential value of 22 mV (30.6%). This indicates that the same charge of rocks and oil droplets improves the transportation of charged oil/water emulsion in the porous media. This work reveals that the surface charge in surfactant flooding plays an important role in addition to the oil/water interfacial tension reduction and the rock wettability alteration.

Electrokinetic Potential for Characterization of Nanosctructured Solid Flat Surfaces

2013 ◽  
Vol 25 ◽  
pp. 31-39 ◽  
Author(s):  
Zdeňka Kolská ◽  
Nikola Slepičková Kasálková ◽  
Jakub Siegel ◽  
Václav Švorčík
Keyword(s):  
Zeta Potential ◽  
Isoelectric Point ◽  
Electrokinetic Potential ◽  
Characteristic Parameter ◽  
Metal Nanostructures ◽  
Gold Deposition ◽  
Fast Analysis ◽  
Flat Surfaces ◽  
Acceptable Method ◽  
Point Determination

Electrokinetic potential (zeta potential) is a characteristic parameter for description of the surface chemistry of solid flat materials and it can be used for a fast analysis of materials modified by different chemical or physical methods. Due to its sensitivity, zeta potential is able to distinguish surface modified by coating with monolayers of various materials or nanostructures created after plasma treatment. Also metal nanostructures deposited on surfaces can be characterized by zeta potential. It can also be used for isoelectric point determination of materials. We present data on zeta potential in 0.001 mol/dm3 KCl at constant pH7.0 and also in pH range (2.5-7.0) for isoelectric point determination for pristine polymers PET, PTFE, PS, LDPE, HDPE, PLLA, PVF, PVDF, PMP and polyimides (Upilex R, Upilex S, Kapton). The zeta potential of selected polymers, modified by plasma and by chemical coatings (e.g. by biphenyldithiol or polyethyleneglycol) or by gold deposition was measured too. Zeta potentials of these modified materials were also studied to confirmation that electrokinetic analysis is acceptable method for their fast description.

Formation of Hydroxycarbonate Apatite Layer on Poly(Lactic Acid) Composites in Simulated Body Fluid

2005 ◽  
Vol 284-286 ◽  
pp. 489-492 ◽  
Author(s):  
Hirotaka Maeda ◽  
Toshihiro Kasuga ◽  
Masayuki Nogami
Keyword(s):  
Lactic Acid ◽  
Simulated Body Fluid ◽  
Zeta Potential ◽  
Calcium Chloride ◽  
Composite Membrane ◽  
Body Fluid ◽  
Poly Lactic Acid ◽  
Zeta Potentials ◽  
Carbonate Ion ◽  
Ft Ir

Hydroxycarbonate apatite (HCA), which formed on a poly(lactic acid) (PLA) composite membrane containing vaterite or calcium chloride after soaking in simulated body fluid, was examined to clarify the importance of the ceramic phases in the composites. FT-IR spectra showed that the ratio of CO3/PO4 in the infrared adsorption bands of HCA formed on the PLA composite containing vaterite was much larger than that of HCA formed on the PLA composite containing calcium chloride. Substitution of carbonate ion in hydroxyapatite is believed to be strongly influenced by ceramic phases in the composites. The zeta potentials of HCA formed on the PLA composite containing vaterite or calcium chloride was -6 mV or -17 mV, respectively. The zeta potential may be influenced by the amount of carbonate ion in hydroxyapatite.

Dispersion of Barium Ferrite Particles for Slip Casting in Magnetic Field

2006 ◽  
Vol 317-318 ◽  
pp. 143-146 ◽  
Author(s):  
Jing Long Li ◽  
Saburo Sano ◽  
Akihiro Tsuzuki ◽  
Akihiro Gotou ◽  
Yasuo Shibasaki ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Polyethylene Glycol ◽  
Zeta Potential ◽  
Barium Ferrite ◽  
Slip Casting ◽  
Steric Repulsion ◽  
Ph Titration ◽  
Zeta Potentials ◽  
Water Based ◽  
Slip Cast

Water-based slurries containing barium ferrite particles have been prepared and slip cast in magnetic field. This paper presents the characteristics of the suspensions in terms of Iso-Electric Points (IEP) and zeta potential that were evaluated through pH titration and polymer adsorption. Both enlarging the specific surface area of particles by planetary milling and adjusting the pH to low value apparently increase the zeta potentials. Stable slurry was obtained by adding polyethylene glycol (PEG) into the suspension at pH = 2 ~ 3.5. The steric repulsion plays key role in dispersion and PEG films served as insulative layers and mechanically kept particles from contact each other. The barium ferrite particles formed many stacks of plates during slip casting, which either aligned randomly without magnetic field applied or regularly aligned to form textured structure when magnetic field was applied.

scholarly journals A Surface Complexation Model of Alkaline-SmartWater Electrokinetic Interactions in Carbonates

2020 ◽  
Vol 146 ◽  
pp. 02003
Author(s):  
Moataz Abu-Al-Saud ◽  
Amani Al-Ghamdi ◽  
Subhash Ayirala ◽  
Mohammed Al-Otaibi
Keyword(s):  
Experimental Data ◽  
Zeta Potential ◽  
Crude Oil ◽  
Oil Recovery ◽  
Surface Complexation ◽  
Surface Complexation Model ◽  
Zeta Potentials ◽  
Smart Water ◽  
Injection Water ◽  
Carbonate Formations

Understanding the effect of injection water chemistry is becoming crucial, as it has been recently shown to have a major impact on oil recovery processes in carbonate formations. Various studies have concluded that surface charge alteration is the primary mechanism behind the observed change of wettability towards water-wet due to SmartWater injection in carbonates. Therefore, understanding the surface charges at brine/calcite and brine/crude oil interfaces becomes essential to optimize the injection water compositions for enhanced oil recovery (EOR) in carbonate formations. In this work, the physicochemical interactions of different brine recipes with and without alkali in carbonates are evaluated using Surface Complexation Model (SCM). First, the zeta-potential of brine/calcite and brine/crude oil interfaces are determined for Smart Water, NaCl, and Na2SO4 brines at fixed salinity. The high salinity seawater is also included to provide the baseline for comparison. Then, two types of Alkali (NaOH and Na2CO3) are added at 0.1 wt% concentration to the different brine recipes to verify their effects on the computed zeta-potential values in the SCM framework. The SCM results are compared with experimental data of zeta-potentials obtained with calcite in brine and crude oil in brine suspensions using the same brines and the two alkali concentrations. The SCM results follow the same trends observed in experimental data to reasonably match the zeta-potential values at the calcite/brine interface. Generally, the addition of alkaline drives the zeta-potentials towards more negative values. This trend towards negative zeta-potential is confirmed for the Smart Water recipe with the impact being more pronounced for Na2CO3 due to the presence of divalent anion carbonate (CO3)-2. Some discrepancy in the zeta-potential magnitude between the SCM results and experiments is observed at the brine/crude oil interface with the addition of alkali. This discrepancy can be attributed to neglecting the reaction of carboxylic acid groups in the crude oil with strong alkali as NaOH and Na2CO3. The novelty of this work is that it clearly validates the SCM results with experimental zeta-potential data to determine the physicochemical interaction of alkaline chemicals with SmartWater in carbonates. These modeling results provide new insights on defining optimal SmartWater compositions to synergize with alkaline chemicals to further improve oil recovery in carbonate reservoirs.

Apparatus for determination of zeta potentials from streaming potentials

1963 ◽  
Vol 18 (6) ◽  
pp. 1263-1264 ◽  
Author(s):  
R. E. Beck ◽  
V. Mirkovitch ◽  
P. G. Andrus ◽  
R. I. Leininger
Keyword(s):  
Zeta Potential ◽  
Streaming Potential ◽  
Salt Solutions ◽  
Streaming Potentials ◽  
Zeta Potentials ◽  
Quartz Capillary ◽  
Flow Through

A system was developed to measure the streaming potential generated between the ends of a capillary by the flow of a fluid through the capillary. Zeta potential can be calculated from the streaming potential. Adequate sensitivity and reproducibility were achieved by making special electrodes: silver wires plated in KCl solution and embedded in agar, careful electrical shielding, and provision for reversal of flow through the capillary to minimize electrode errors. The apparatus was developed to measure streaming potentials generated by either RingerS's solution or blood in contact with capillaries made of different materials such as quartz, polyethylene, etc. An example of a determination using a quartz capillary is presented. interfaces; blood; salt solutions; glass; quartz Submitted on February 25, 1963

Chaotic Electroosmotic Flow

2002 ◽  
Author(s):  
Shizhi Qian ◽  
Haim H. Bau
Keyword(s):  
Zeta Potential ◽  
Electroosmotic Flow ◽  
Analytic Solution ◽  
Microfluidic Devices ◽  
Chaotic Advection ◽  
Uniform Electric Field ◽  
Periodic Modulation ◽  
Chaotic Flows ◽  
Zeta Potentials ◽  
Series Convergence

Two dimensional, time-independent and time-dependent electroosmotic flows driven by a uniform electric field in rectangular cavities with uniform and non-uniform zeta potential distributions along the cavities’ walls are investigated theoretically. The time-independent flow fields are computed with the aid of Fourier series. The series’ convergence is accelerated so that highly accurate solutions are obtained with just a few (<10) terms in the series. The analytic solution is used to compute flow patterns for various distributions of the zeta potential along the cavities’ boundaries. It is demonstrated that by time-wise periodic modulation of the zeta potentials, one can induce chaotic advection in the cavities. Such chaotic flows may be used to stir and mix fluids in microfluidic devices.

Direct Ink Printing of Cavities in DPC Ceramic Substrates With Kaolin Pastes for Hermetic Packaging

2019 ◽  
Author(s):  
Qinglei Sun ◽  
Yang Peng ◽  
Hao Cheng ◽  
Yun Mou ◽  
Mingxiang Chen
Keyword(s):  
Zeta Potential ◽  
Viscoelastic Properties ◽  
Three Dimensional ◽  
Kaolin Clay ◽  
Ceramic Substrates ◽  
Light Emitting ◽  
Zeta Potentials ◽  
Hermetic Packaging ◽  
Content Variation ◽  
Ultraviolet Light Emitting Diodes

Abstract Fabrication of three-dimensional cavities containing kaolin pastes to be used as direct plated copper (3DPC) substrates ceramics is a very important advancement for electronic packaging of hermetic and ultraviolet light emitting diodes. This work demonstrates usage of pastes consisting of 32–40 wt% of kaolin clay and polyacrylic acid for direct ink printing (DIP) of 3DPC. Rheological and zeta potential tests were performed to determine printability and stability, respectively, of these kaolin pastes. Kaolin content variation had minimum effect on absolute values of the zeta potentials. All pastes had enough stability with the absolute values larger than 30 mV. 40 wt% kaolin solids mass paste was the optimal for DIP due to its excellent shear thinning and viscoelastic properties. Cured 40 wt% kaolin solids mass paste had superior compressive, flexural and bonding strengths. DIP using pastes containing 40 wt% of kaolin is promising for electronic chip integrated hermetic packaging.

Sign in / Sign up

Export Citation Format

Share Document