Synthesis and Fluorescence Property of Novel Zn2+ Schiff Base Complex

2012 ◽  
Vol 535-537 ◽  
pp. 1237-1240
Author(s):  
Li Hua Wang ◽  
Yong Li Wang ◽  
Zhan Zhong Hou ◽  
Yan Zhu Liu
Keyword(s):  
Schiff Base ◽  
Infrared Spectroscopy ◽  
Solid State ◽  
Zinc Chloride ◽  
Free Ligand ◽  
Schiff Base Complex ◽  
Blue Fluorescence ◽  
Peak Wavelength ◽  
Solid Fluorescence ◽  
Chloride Hydrate

The complex of ZnL2Cl4 was synthesized by using zinc chloride hydrate and ligand 2-[(4-Methylpiperazin-1-yl)iminomethyl]phenol(L) under reflux conditions and anhydrous ethanol as solvent. The complex was characterized by elemental analysis, Infrared spectroscopy, solid fluorescence. Experimental results showed that the free ligand was thermally stable, and emitted intensive blue fluorescence at the peak wavelength of 493 nm. Compared with the fluorescent emission of free ligand, the complex of ZnL2Cl4 is blue-shifted to 448 nm in solid-state and exhibiting stronger blue fluorescence.

A New Fluorescent Material of Zn (II) Complex with 1-Acetyl-2-Naphthol-4, 4’-Diaminodiphenylmethane

2011 ◽  
Vol 399-401 ◽  
pp. 1026-1029
Author(s):  
Li Hua Wang
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Organic Solvents ◽  
Green Fluorescence ◽  
Blue Fluorescence ◽  
Complex Material ◽  
Fluorescent Material

A novel bi-Schiff-base Zn (II) complex, 1-acetyl-2-naphthol-4, 4’-diaminodiphenylmethane Zn (II), has been synthesized. The luminescent characterizations of the Zn (II) complex material have been studied in solid state and in organic solvents, and the effect of Mg (II) ion on the fluorescence of Zn (II) complex has also been investigated in organic solvents. The results show that the Zn (II) complex material emits weak green fluorescence at 536 nm in solid, emits strong blue fluorescence 451 nm in DMSO. However, there do have luminescent emissions in methanol and in ethanol duo to the influence of overtones.

Synthesis and characterization of a manganese(III) schiff base complex and exploration of Br···Br interaction in the solid state structure of the complex

2019 ◽  
Vol 72 (19-21) ◽  
pp. 3237-3247 ◽  
Author(s):  
Ipsita Mondal ◽  
Kousik Ghosh ◽  
Antonio Franconetti ◽  
Antonio Frontera ◽  
Sudipta Chatterjee ◽  
...  
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Schiff Base Complex ◽  
Synthesis And Characterization ◽  
State Structure ◽  
Base Complex ◽  
Solid State Structure

scholarly journals Nickel(II)-salen Schiff Base Complex as Anion Receptor

2014 ◽  
Vol 8 (3) ◽  
Author(s):  
Salasiah Endud ◽  
Wong Wen Yee
Keyword(s):  
Fourier Transform ◽  
Schiff Base ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Binding Affinity ◽  
1H Nmr ◽  
Diffuse Reflectance ◽  
Schiff Base Complex ◽  
Anion Receptor ◽  
Salen Complex

The Schiff base salen was incorporated to nickel(II) ion to afford nickel(II) diethylamino-substituted salen complex. The diethylamino-substituted salen l salen complex were characterized by Fourier Transform Infrared Spectroscopy (FTIR), diffuse reflectance ultravisible spectroscopy (DR UV-Vis) and 1H (1H-NMR). The binding affinity of the nickel(II) diethylamino-substituted salen complex towards specific anion in dichloromethane was investigated by us

Self-assembled nanostructures of amphiphilic zinc(ii) salophen complexes: role of the solvent on their structure and morphology

2014 ◽  
Vol 43 (26) ◽  
pp. 10208-10214 ◽  
Author(s):  
Ivan Pietro Oliveri ◽  
Graziella Malandrino ◽  
Santo Di Bella
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Schiff Base Complex ◽  
Base Complex ◽  
Structure And Morphology ◽  
Self Assembled ◽  
Solvent Properties

The influence of several solvent properties, such as volatility, polarity, and Lewis basicity, on the formation of molecular self-assembled nanostructures of an amphiphilic ZnII Schiff-base complex in the solid state is reported.

scholarly journals Catecholase-Like Activity and Theoretical Study in Solid State of a New Ru(III)-Schiff Base Complex

2021 ◽  
Vol 68 (1) ◽  
pp. 212-221
Author(s):  
Niladri Biswas ◽  
Sandeepta Saha ◽  
Ennio Zangrando ◽  
Antonio Frontera ◽  
Chirantan Roy Choudhury
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Schiff Base Ligand ◽  
Metal Ion ◽  
Theoretical Study ◽  
Schiff Base Complex ◽  
Aerobic Condition ◽  
Halogen Bonding ◽  
Molecular Formula ◽  
Charge Balance

A new ruthenium(III) complex of molecular formula [Ru(PPh3)Cl2(L)] (1) has been synthesized using the Schiff base ligand obtained from 5-chlorosalicylaldehyde and N,N-dimethylethylenediamine and characterized by FT-IR, UV-Vis, cyclic voltammetry and single crystal X-ray structural analysis. The metal ion exhibits a slightly distorted octahedral environment where the chelating Schiff base ligand contributes with its NNO donor set. The coordination geometry around the Ru(III) ion is completed by a PPh3 ligand and two chloride anions, and the charge balance is assured by the phenoxo oxygen of the Schiff base. With the aim to analyse the energy related to the halogen bonding interactions in solid state, a theoretical study has been performed on complex 1, by using the MEP and NCl plot computational tools. Furthermore, complex 1 shows catecholase-like activity in conversion of the model substrate 3,5-di-tert-butylcatechol (3,5-DTBC) to the corresponding 3,5-di-tert-butylquinone (3,5-DTBQ) under aerobic condition. The parameters regarding the enzymatic kinetics have been evaluated from the Lineweaver-Burk plot using the Michaelis-Menten approach of enzyme catalysis. A significant high T.O.N value (2.346 × 103 h–1) indicates that complex 1 has a very good catalytic efficiency towards 3,5-DTBC.

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