Mechanisms and Remediation Technologies of Sulfate Removal from Acid Mine Drainage

2012 ◽  
Vol 610-613 ◽  
pp. 3252-3256
Author(s):  
Mei Qin Chen ◽  
Feng Ji Wu

Acid mine drainage (AMD) has properties of extreme acidification, quantities of sulfate and elevated levels of soluble heavy metals. It was a widespread environmental problem that caused adverse effects to the qualities of ground water and surface water. In the past decades, most of investigations were focused on the heavy metals as their toxicities for human and animals. As another main constitution of AMD, sulfate ion is nontoxic, yet high concentration of sulfate ion can cause many problems such as soil acidification, metal corrosion and health problems. More attention should be paid on the sulfate ion when people focus on the AMD. In the paper, sulfate removal mechanisms include adsorption, precipitation, co-precipitation and biological reduction were analyzed and summarized. Meanwhile, the remediation technologies, especially the applications of them in China were also presented and discussed.

2012 ◽  
Vol 11 (2) ◽  
pp. 133-138 ◽  
Author(s):  
Alena Luptáková ◽  
Stefano Ubaldini ◽  
Eva Mačingová ◽  
Ingrida Kotuličová

Abstract The submitted paper deals with the study of combination of chemical and biological-chemical methods for the heavy metals elimination from the acid mine drainage. The experiments were carried out at the laboratory scale using a synthetic solution with similar properties to the real sample of acid mine drainage, originating from the zinc mine located in Tùnel Kingsmill outflow of the Rio Yaulì (district of Yauli - Perù). The successive repetition of the metal precipitations as hydroxides (chemical method) and sulphides (biological-chemical method) at the various acid mine drainage pH was the basis of the examined processes. For the hydrogen sulphide production the sulphate-reducing bacteria of genus Desulfovibrio were used. Results confirmed the precipitation of Fe, As, Al and Mn in the hydroxide form; Cu and Zn in the form of sulphides. For the selective removal of Cu, Zn, Al and Mn the excellent results were received. Selective precipitation of Fe and As was not so successful since the co-precipitation of Fe and As was later determined as a main mechanism of the precipitate forming.


RSC Advances ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 1039-1046 ◽  
Author(s):  
Yongwei Song ◽  
Heru Wang ◽  
Jun Yang ◽  
Lixiang Zhou ◽  
Jingcheng Zhou ◽  
...  

Acid mine drainage (AMD) is typically characterized by low pH, a high concentration of sulfate and dissolved heavy metals.


2019 ◽  
Vol 538 ◽  
pp. 132-141 ◽  
Author(s):  
Guorui Feng ◽  
Jianchao Ma ◽  
Xiaopeng Zhang ◽  
Qingfang Zhang ◽  
Yuqiang Xiao ◽  
...  

2012 ◽  
Vol 36 (2) ◽  
pp. 671-679 ◽  
Author(s):  
Igor Rodrigues de Assis ◽  
Luiz Eduardo Dias ◽  
Emerson Silva Ribeiro Jr ◽  
Walter Antônio Pereira Abrahão ◽  
Jaime Wilson Vargas de Mello ◽  
...  

Acid mine drainage (AMD) is an environmental concern due to the risk of element mobilization, including toxic elements, and inclusion in the food chain. In this study, three cover layers were tested to minimize As, Fe and S mobilization from a substrate from former gold mining, containing pyrite and arsenopyrite. For this purpose, different layers (capillary break, sealant and cover layer) above the substrate and the induction of a geochemical barrier (GB) were used to provide suitable conditions for adsorption and co-precipitation of the mobilized As. Thirteen treatments were established to evaluate the leaching of As, Fe and S from a substrate in lysimeters. The pH, As, Fe, S, Na, and K concentrations and total volume of the leachates were determined. Mineralogical analyses were realized in the substrate at the end of the experimental period. Lowest amounts of As, Fe and S (average values of 5.47, 48.59 and 132.89 g/lysimeter) were leached in the treatments that received Na and K to induce GB formation. Mineralogical analyses indicated jarosite formation in the control treatment and in treatments that received Na and K salts. However, the jarosite amounts in these treatments were higher than in the control, suggesting that these salts accelerated the GB formation. High amounts of As, Fe and S (average values of 11.7, 103.94 and 201.13 g/lysimeter) were observed in the leachate from treatments without capillary break layer. The formation of geochemical barrier and the use of different layers over the sulfide substrate proved to be efficient techniques to decrease As, Fe and S mobilization and mitigate the impact of acid mine drainage.


2002 ◽  
Vol 36 (19) ◽  
pp. 4757-4764 ◽  
Author(s):  
Matthew M Matlock ◽  
Brock S Howerton ◽  
David A Atwood

Sign in / Sign up

Export Citation Format

Share Document