Alcohol Interchange Synthesis of a Novel Titanium Glycolate

2013 ◽  
Vol 634-638 ◽  
pp. 638-641
Author(s):  
Guo Liang Shen ◽  
Gui Ling Ning
Keyword(s):  
Tetraethyl Orthosilicate ◽  
Thermal Gravimetric ◽  
X Ray Diffraction ◽  
X Ray ◽  
Straightforward Method ◽  
Dta Analysis ◽  
Electron Microscopes ◽  
Scanning Electron Microscopes ◽  
Titanium Glycolate

A much simpler and more straightforward method, alcohol interchange for the synthesis of titanium glycolate has been suggested. The method implied the reaction of tetraethyl orthosilicate with ethylene glycol on heating in air. The thermal property of titanium glycolate was characterized by thermal gravimetric (TG) and Differencial Thermal Analysis (DTA) analysis. X-ray diffraction (XRD) was used to confirm the conversion of crystalline phase of titanium glycolate from anatase to rutile. The characterization of titanium glycolate and products of its pyrolysis was conducted using scanning electron microscopes.

scholarly journals A Versatile Approach to Access Trimetallic Complexes Based on Trisphosphinite Ligands

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 593
Author(s):  
Juan Miranda-Pizarro ◽  
Macarena G. Alférez ◽  
M. Dolores Fernández-Martínez ◽  
Eleuterio Álvarez ◽  
Celia Maya ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Late Transition Metal ◽  
X Ray Diffraction ◽  
X Ray ◽  
Full Characterization ◽  
Metal Precursors ◽  
Straightforward Method ◽  
One Step ◽  
Late Transition

A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of four trisphosphinite ligands of formula [CH3C{(C6H4OR2)3], where R stands for Ph (1a), Xyl (1b, Xyl = 2,6-Me2-C6H3), iPr (1c), and Cy (1d). These polyfunctional phosphinites allowed us to investigate their coordination chemistry towards a range of late transition metal precursors. As such, we report here the isolation and full characterization of a number of Au(I), Ag(I), Cu(I), Ir(III), Rh(III) and Ru(II) homotrimetallic complexes, including the structural characterization by X-ray diffraction studies of six of these compounds. We have observed that the flexibility of these trisphosphinites enables a variety of conformations for the different trimetallic species.

Analysis on Microstructure of Laser Brazing Diamond Grits with a Ni-Based Filler Alloy

2010 ◽  
Vol 97-101 ◽  
pp. 3879-3883 ◽  
Author(s):  
Zhi Bo Yang ◽  
Jiu Hua Xu ◽  
Ai Ju Liu
Keyword(s):  
Active Element ◽  
Steel Substrate ◽  
Parameters Optimization ◽  
Interfacial Region ◽  
Filler Alloy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cross Diffusion ◽  
Electron Microscopes ◽  
Scanning Electron Microscopes

Brazing diamond grits onto steel substrate using a Ni-based filler alloy was carried out via laser beam in an argon atmosphere. The microstructure of the interfacial region among the Diamond grits and the filler layer were investigated by means of scanning electron microscopes (SEM), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDS). Meanwhile, the formation mechanism of carbide layers was discussed. All the results indicated that the active element chromium in the Ni-based alloy concentrated preferentially to the surface of the grits to form a chromium-rich layer, and the hard joint between the alloy and the steel substrate is established through a cross-diffusion of iron and Ni-based alloy through parameters optimization.

Otosclerotic Stapes: Morphological and Microchemical Correlates

1977 ◽  
Vol 86 (4) ◽  
pp. 525-540 ◽  
Author(s):  
David J. Lim ◽  
William H. Saunders
Keyword(s):  
Calcium Salt ◽  
Mineral Deposit ◽  
Ground Substance ◽  
X Ray Diffraction ◽  
Typical Pattern ◽  
X Ray ◽  
Initial Stage ◽  
Electron Microscopes ◽  
Sclerotic Lesions ◽  
Scanning Electron Microscopes

A total of 32 otosclerotic stapes is thin-sectioned without decalcification and examined using transmission and scanning electron microscopes, with a nondispersive x-ray analyzer attached to the latter. These otosclerotic stapes are classified as spongiotic, sclerotic, or preotosclerotic, according to their pathologic characteristics and state of mineralization. Either diffuse or patchy demineralization in the ground substance appears to be the initial stage of otosclerosis, and this area coincides with preotosclerotic lesions (also known as blue mantle) in light microscopy. Therefore, it is interpreted that demineralization precedes the destruction of ground substance in the preotosclerotic lesion. Bone mineral deposits in new otosclerotic bone appear to be related to the collagen fibrils that are embedded in the ground substance. No mineral deposit could be seen without the ground substance deposition; therefore, it is suggested that this ground substance is the single most important factor in the poor mineralization of the otosclerosis. The sclerotic lesions are well mineralized and show a typical pattern of hydroxyapatite by x-ray diffraction study. We could not confirm the notion that the sclerotic lesion is hypermineralized as compared to the normal stapes. The spongiotic lesions are poorly mineralized, with low calcium salt. Using the Ca/P ratio and x-ray diffraction pattern as criteria, it was determined that spongiotic lesions belong to unstable, immature bone.

Arc Discharge Synthesis of Oxides and Carbides of Tungsten and Aluminum

2013 ◽  
Vol 8 (2) ◽  
pp. 95-101
Author(s):  
Alexey Zaikovsky ◽  
Aleksandr Fedoseev ◽  
Salavat Sakhapov ◽  
Anton Evtushenko ◽  
Marina Serebriakova ◽  
...  
Keyword(s):  
Arc Discharge ◽  
Experimental Investigations ◽  
Gravimetric Analysis ◽  
Thermal Gravimetric ◽  
X Ray Diffraction ◽  
X Ray ◽  
Synthesis Of Nanoparticles ◽  
Synthesized Materials ◽  
Discharge Method

Experimental investigations of the possibility of arc discharge method for synthesis of nanoparticles of oxides and carbides of tungsten and aluminum have been presented. The method is based on anode atomization of composed graphite – aluminum and graphite – WO3 electrodes. The transmitted electron microscopy, thermal gravimetric analysis and X-ray diffraction were applied for the characterization of morphology and properties of synthesized materials. It was experimentally shown the arc discharge method allows to syntheses the nanoparticles of oxides and carbides of tungsten and aluminum

Purification of Bentonite Clays from the District of Cubati, PB, for Obtainment of Organoclays for Use in Drilling Fluids

2012 ◽  
Vol 727-728 ◽  
pp. 1444-1450
Author(s):  
J.M.R. de Figueirêdo ◽  
Carla Dantas da Silva ◽  
Isabelle Albuquerque da Silva ◽  
Heber Sivini Ferreira ◽  
Gelmires Araújo Neves ◽  
...  
Keyword(s):  
Petroleum Industry ◽  
Diesel Oil ◽  
The State ◽  
Drilling Fluids ◽  
X Ray Diffraction ◽  
X Ray ◽  
Granulometric Analysis ◽  
Dta Analysis ◽  
Bentonite Clays

The main deposits of bentonite clays are located in the district of Boa Vista, in the State of Paraiba, Brazil. The random exploration of these deposits for many years is causing the clays to be depleted, and this will turn into a serious problem to the national petroleum industry. So, this work aims to study the characterization of new deposits of bentonite clays in the district of Cubati, in the State of Paraiba, Brazil, with the objective of developing purified organoclays, using a hydrocyclone, from ionic and non-ionic surfactants for use in drilling fluids. The characterization of the studied clay samples was done by applying the following techniques: granulometric analysis by laser diffraction (GA), X-ray diffraction (XRD) and chemical analysis by X-ray fluorescence (EDX) and thermogravimetric (TGA) and differential thermogravimetric (DTA) analysis. The characterization is typical of bentonites and the dispersions present rheological properties which meet Petrobras’ specifications for diesel oil media, organofilized with Praepagen WB.

New polymer syntheses III. Synthesis and characterization of new unsaturated polycarbonates

1994 ◽  
Vol 6 (2) ◽  
pp. 149-154 ◽  
Author(s):  
Kamal I Aly
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermal Gravimetric ◽  
X Ray Diffraction ◽  
X Ray ◽  
1H Nuclear Magnetic Resonance ◽  
Elemental Analyses ◽  
Interesting Class

A new interesting class of linear unsaturated polycarbonates based on 3,5-bis(p-hydroxybenzylidene)-isopropylpiperidinone (T), 3,5-divanillylidene isopropylpiperidinone (IT), or 3,5-bis(m-hydroxybenzylidene)-isopropylpiperidinone (III) have been synthesized. An interfacial phosgenation technique carried out at ambient temperature was used for the synthesis of the polycarbonates. The resulting polycarbonates were characterized by elemental analyses, infrared spectroscopy, 1H nuclear magnetic resonance spectral analysis, solubility and viscometry. The thermal behaviour of the synthesized polymers was evaluated by thermal gravimetric analysis and correlated with their structures. The crystallinity of all polymers was examined by x-ray diffraction analysis.

A Keggin-type Arsenotungstate Anion-supported Transition Metal Complex: Hydrothermal Synthesis and Characterization of [Fe(2,2′-bipy)3]1.5[AsWVI10WV2O40Fe(2,2′-bipy)2(H2O)] · 0.25H2O

2008 ◽  
Vol 63 (2) ◽  
pp. 183-186 ◽  
Author(s):  
Ming-Xue Li ◽  
Hong-Yu Niu ◽  
Wei Wang ◽  
Jing-Ping Wang
Keyword(s):  
Structural Unit ◽  
Transition Metal Complex ◽  
Esr Spectra ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Keggin Type ◽  
Covalently Bonded ◽  
Dta Analysis

A Keggin-type arsenotungstate anion-supported iron-bipyridine complex, [Fe(2,2'-bipy)3]1.5- [AsWVI10WV2O40Fe(2,2'-bipy)2(H2O)] · 0.25H2O, has been hydrothermally synthesized and characterized by IR and ESR spectra, TG-DTA analysis, and single crystal X-ray diffraction. Each structural unit of the title compound consists of one [AsWVI10WV2O40Fe(2,2'-bipy)2(H2O)]3− heteropolyanion, one and a half [Fe(2,2'-bipy)3]2+ cations, and a quarter of an H2O molecule. In the heteropolyanion the [Fe(2,2'-bipy)2(H2O)]2+ unit is covalently bonded to the reduced Keggin polyoxoanion [AsWVI10WV2O40]5−. The complex ismonoclinic, space group C2/c with a = 46.8079(13), b = 14.3990(4), c = 26.1085(8) Å , β = 90.00(5)°, Z = 8, Dc = 3.10 g/cm3

Laser Welding of AISI 316 Steel: Microstructural and Stress Analysis

2013 ◽  
Vol 135 (3) ◽  
Author(s):  
B. S. Yilbas ◽  
Sohail Akhtar
Keyword(s):  
Residual Stress ◽  
Base Material ◽  
Element Model ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cooling Period ◽  
Thermal Stress Field ◽  
Electron Microscopes ◽  
Aisi 316 ◽  
Scanning Electron Microscopes

Thermal-stress field in the welded region was modeled incorporating the finite element model. Temperature and stress fields were predicted at different cooling periods. The morphological and metallurgical changes in the welded region were examined using optical and scanning electron microscopes, energy dispersive spectroscopy and X-ray diffraction. The residual stress formed at the surface vicinity of the weld was determined using the X-ray diffraction technique. It was found that the residual stress predicted agreed well with the experimental data. The solidification cracking did not occur in the weld section during the cooling period. The microhardness in the weld cross-section was almost 1.4 times the base material hardness.

scholarly journals Synthesis and Characterization of MgFe2O4@MIL-53(Al) Nanocomposite as Antibacterial Drug Nanocarrier Agent

2021 ◽  
Author(s):  
Fatemeh Shateran ◽  
Mohammad Ali Ghasemzadeh
Keyword(s):  
Antibacterial Properties ◽  
Antibacterial Activities ◽  
Antibacterial Drug ◽  
Gravimetric Analysis ◽  
Thermal Gravimetric ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Ft Ir

Abstract Metal-organic frameworks (MOFs) are developing as a powerful platform for the delivery and controlled release of drugs. In this study, we reported a novel magnetic framework including MgFe2O4@MIL-53(Al) for the delivery of tetracycline (TC) antibiotic. The obtained results of this research showed that 88% of the TC was loaded on the MgFe2O4@MIL-53(Al). The drug release study was performed in pH: 7.4 and pH: 5.0 which showed 75% and 83% release within 3 days. Moreover, antibacterial activities tests based on well agar diffusion were performed against Staphylococcus aureus and Escherichia coli bacteria which exhibited satisfactory antibacterial properties of TC-loaded MgFe2O4@MIL-53(Al). Moreover, the prepared structures including MgFe2O4@MIL-53(Al) and MgFe2O4@MIL-53(Al)/TC were identified using Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Scanning electron microscope (SEM) and thermal gravimetric analysis (TGA).

scholarly journals Preparation and properties of nanocrystalline Ni/graphene composite coatings deposited by electrochemical method

2018 ◽  
Vol 20 (1) ◽  
pp. 29-34 ◽  
Author(s):  
Grzegorz Cieślak ◽  
Maria Trzaska
Keyword(s):  
Steel Substrate ◽  
Composite Coatings ◽  
X Ray Diffraction ◽  
Dispersion Phase ◽  
X Ray ◽  
Graphene Layers ◽  
Nano Crystalline ◽  
Graphene Flakes ◽  
Electron Microscopes ◽  
Scanning Electron Microscopes

Abstract The paper presents results of studies of composite nickel/graphene coatings produced by electrodeposition method on a steel substrate. The method of producing composite coatings with nanocrystalline nickel matrix and dispersion phase in the form of graphene is presented. For comparative purposes, the study also includes nano-crystalline Ni coatings produced by electrochemical reduction without built-in graphene flakes. Graphene was characterized by Raman spectroscopy, transmission and scanning electron microscopes. Results of studies on the structure and morphology of Ni and Ni/graphene layers produced in a bath containing different amounts of graphene are presented. Material of the coatings was characterized by SEM, light microscopy, X-ray diffraction. The microhardness of the coatings was examined by Knoop measurements. The adhesion of the coatings with the substrate was tested using a scratchtester. The influence of graphene on the structure and properties of composite coatings deposited from a bath with different graphene contents was determined.

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