Sustainable Porous Materials for Gas Adsorption Applications; A Concise Review

2013 ◽  
Vol 795 ◽  
pp. 96-101 ◽  
Author(s):  
Hoong Chan Wai ◽  
Mohd Noor Mazlee ◽  
Zainal Arifin Ahmad ◽  
Shamsul Baharin Jamaludin ◽  
Mohd Azlan Mohd Ishak ◽  
...  
Keyword(s):  
Porous Materials ◽  
Flue Gas ◽  
Gas Adsorption ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Cost Effective ◽  
Adsorption Properties ◽  
Concise Review ◽  
Metal Organic ◽  
Clay Materials

Many new sustainable porous materials were developed for gas adsorption applications. Common materials such as activated carbon, clay materials and metal organic framework (MOF) that utilized as potential porous adsorption materials were studied. The article was also discussed on the fabrication methods of porous materials. Adsorptions of flue gas using porous materials were reviewed. It was found that the adsorption properties of porous materials were highly dependent on surface area, selectivity and impregnation. Low cost porous adsorbents such as clay and fly ash were also reviewed as potential and cost effective materials to be used in industries.

scholarly journals Statistical Thermodynamic Model of Gas Adsorption in a Metal-Organic Framework Harboring a Rotaxane Molecular Shuttle

2019 ◽  
Author(s):  
Jonathan Carney ◽  
David Roundy ◽  
Cory M. Simon
Keyword(s):  
Thermodynamic Model ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Statistical Thermodynamic ◽  
Temperature Sensitive ◽  
Adsorption Sites ◽  
Metal Organic ◽  
Dynamic Components ◽  
Molecular Shuttle

Metal-organic frameworks (MOFs) are modular and adjustable nano-porous materials with applications in gas storage, separations, and sensing. Flexible/dynamic components that respond to adsorbed gas can give MOFs unique or enhanced adsorption properties. Here, we explore the adsorption properties that could be imparted to a MOF by a rotaxane molecular shuttle (RMS) in its pores. In an RMS-MOF, a macrocyclic wheel is mechanically interlocked with a strut. The wheel shuttles between stations on the strut that are also gas adsorption sites. We pose and analyze a simple statistical thermodynamic model of gas adsorption in an RMS-MOF that accounts for (i) wheel/gas competition for sites on the strut and (ii) the entropy endowed by the shuttling wheel. We determine how the amount of gas adsorbed, position of the wheel, and energy change upon adsorption depend on temperature, pressure, and the interactions of the gas/wheel with the stations. Our model reveals that, compared to an ordinary Langmuir material, the chemistry of the RMS-MOF can be tuned to render adsorption more or less temperature-sensitive and release more or less heat upon adsorption. The model also uncovers a non-monotonic relationship between temperature and the position of the wheel if gas out-competes the wheel for its preferable station.

A 9-connected metal–organic framework with gas adsorption properties

2011 ◽  
Vol 21 (40) ◽  
pp. 15909 ◽  
Author(s):  
Guojian Ren ◽  
Shuxia Liu ◽  
Fengji Ma ◽  
Feng Wei ◽  
Qun Tang ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Organic Framework

A novel zinc(ii) metal–organic framework with a diamond-like structure: synthesis, study of thermal robustness and gas adsorption properties

2016 ◽  
Vol 45 (3) ◽  
pp. 1233-1242 ◽  
Author(s):  
Miroslav Almáši ◽  
Vladimír Zeleňák ◽  
Arnošt Zukal ◽  
Juraj Kuchár ◽  
Jiří Čejka
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Clapeyron Equation ◽  
Structure Synthesis ◽  
Metal Organic ◽  
Organic Framework

A novel 3D metal–organic framework with a diamond-like structure has been synthesised and structurally characterized. Adsorption of Ar, CO2, H2 and N2 has been studied. Heats of CO2 and H2 adsorption were calculated according to the Clausius–Clapeyron equation.

A lead–porphyrin metal–organic framework: gas adsorption properties and electrocatalytic activity for water oxidation

2016 ◽  
Vol 45 (1) ◽  
pp. 61-65 ◽  
Author(s):  
Fangna Dai ◽  
Weidong Fan ◽  
Jiahui Bi ◽  
Peng Jiang ◽  
Dandan Liu ◽  
...  
Keyword(s):  
Alkaline Solution ◽  
Water Oxidation ◽  
Electrocatalytic Activity ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Organic Framework

A 3D non-interpenetrating porous metal–organic framework shows electrocatalytic activity for water oxidation in alkaline solution.

scholarly journals Recent Developments in the Synthesis and Applications of Metal Organic Framework: A Concise Review

2021 ◽  
Vol 33 (5) ◽  
pp. 956-962
Author(s):  
Chandan Adhikari ◽  
Rehana Farooq
Keyword(s):  
Drug Delivery ◽  
Porous Materials ◽  
Electrochemical Sensors ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Inorganic Materials ◽  
Synthetic Methods ◽  
Concise Review ◽  
Metal Organic ◽  
Organic Framework

Metal organic frameworks (MOFs) are one of those compounds which have drawn attention in various applications due to their several interesting properties like tunable shape, size, pore size, easy functionalization, high surface area, pore volume, etc. Metal organic frameworks due to their uniform structures, tunable porosity, wide variety and stability on various topology, geometry, dimension and chemical functions of the molecular network give a remarkable structural diversity in comparison to other porous materials. This enables scientists to handle numerous framework structures, porosity and functionality effectively. The unique structural architecture and tunable properties of MOF’s makes them an interesting hybrid material consisting of organic and inorganic materials. MOF can be randomly constructed like Lego bricks and superior in terms of versatility in comparisson to other porous materials. A number of MOFs containing a wide variety of metal e.g. zinc, copper, iron, aluminium, magnesium, chromium, zirconium, gadolinium, manganese are gaining rapid growth in commercial markets for gas storage, adsorption, separation and catalytic applications. This concise review emphasizes various synthetic methods e.g. solvothermal process, hydrothermal synthesis, electrochemical synthesis, microwave synthesis, sonochemical synthesis, mechanochemical synthesis, of metal organic framework developed in the last few decades. It also addresses various applications of metal organic framework e.g. hydrogen storage, gas adsorption, drug delivery systems and bioimaging agents, biocatalysts, biosensors, electrochemical sensors, etc. It also comments on various challenges and futuristic applications of metal organic frameworks in various field e.g. liquid wate management, gaseous waste management, sunlight assisted catalysis, water purification, building materials, electronic devices, battery technologies, targeted drug delivery, solar cells, etc. of science and technology in coming decades.

Metal–Organic Framework for Selective Gas Scavenging

2016 ◽  
Vol 04 (04) ◽  
pp. 1640014
Author(s):  
Jiating He ◽  
Xu Li
Keyword(s):  
Gas Adsorption ◽  
Technology Development ◽  
Metal Organic Framework ◽  
Cost Effective ◽  
Future Perspectives ◽  
Practical Application ◽  
Separation Of Gases ◽  
Hazardous Gases ◽  
Metal Organic ◽  
Gas Scavenging

Selective gas adsorption plays an important role in adsorptive separation of gases and scavenging unfavorable or hazardous gases. The use of cost-effective and environmentally friendly materials for selective gas adsorption has become one of the most pressing needs today. The development of new adsorbents is essential but difficult due to the selectivity and efficiency requirements for practical application. As potential scavengers, metal–organic frameworks (MOFs) have drawn great attention. In this review, the current progress of science and technology development of MOFs on selective gas scavenging will be highlighted. Future perspectives for exploring MOFs for practical application will also be put forward.

Sign in / Sign up

Export Citation Format

Share Document