Rheological Property of the Regenerable Polyhydroxy Alcohol Fracturing Fluid System

2014 ◽  
Vol 875-877 ◽  
pp. 1462-1466
Author(s):  
Xiao Rui Li ◽  
Xiao Jia Xue ◽  
Hua Bo Fan ◽  
Xiao Juan Lai ◽  
Lei Wang

According to the characteristic of polyhydroxy alcohol fracturing fluid system, the regeneration of the system was investigated for the first time. A stable organic boron crosslinking poly (vinyl alcohol) regenerable polyhydroxy alcohol fracturing fluid system was prepared, and the rheological property of the polyhydroxy alcohol fracturing fluid system with different regenerable times was also researched. The effect of regenerable times on the rheological property of the system was studied. The results indicated that the aims of gel breaking and regeneration can be achieved by regulating its pH value and controlling its crosslinking degree. With the increment of the regenerable time, both the temperature resistance and shearing resistance performances were decreased, and the viscoelasticity of the gel was also reduced.

2011 ◽  
Vol 347-353 ◽  
pp. 995-1000
Author(s):  
Xiang Bo Wei ◽  
Xiao Rui Li ◽  
Xiao Jia Xue ◽  
Li Ding

A type of zirconium-organic cross-linking agent with excellent temperature resistance and delaying performance was prepared for acid fracturing fluid system. The factors influencing on the synthetic process of the zirconium-organic cross-linking agent were investigated and the optimum condition was obtained: 5% zirconium oxychloride, 20% ligands, reaction temperature 50~55°C, reaction time 4.0~5.0h. Then the best technology for zirconium-organic cross-linking agent and the laboratory evaluation for the acid fracturing fluid system were studied. The results showed that using the cross-linking agent can obviously improve the temperature resistance, delaying performance and the shearing resistance of the acid fracturing fluid system. Meanwhile, the zirconium-organic cross-linking agent had excellent gelout performance and sand-carrying performance, which can satisfy the fracturing operation requirement for the reservoirs below 100°C.


2016 ◽  
Vol 7 (43) ◽  
pp. 6637-6644 ◽  
Author(s):  
Hongmei Chen ◽  
Ying Li ◽  
Gong Tao ◽  
Lin Wang ◽  
Shaobing Zhou

Poly(vinyl alcohol) (PVA) supramolecular networks cross-linked by ureido-pyrimidinone (UPy) dimers via strong quadruple hydrogen bonding in donor–donor–acceptor–acceptor (DDAA) arrays have been synthesized for the first time.


2014 ◽  
Vol 71 (5) ◽  
pp. 1081-1100 ◽  
Author(s):  
Tongsai Jamnongkan ◽  
Amnuay Wattanakornsiri ◽  
Piyada Wachirawongsakorn ◽  
Supranee Kaewpirom

RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 65089-65094 ◽  
Author(s):  
Francis O. Obiweluozor ◽  
Amin GhavamiNejad ◽  
Chan Hee Park ◽  
Cheol Sang Kim

We report here for the first time a PVA film incorporated with PDNs that is capable of fast and perpetual motion driven by a humidity gradient.


SPE Journal ◽  
2019 ◽  
Vol 24 (04) ◽  
pp. 1929-1946 ◽  
Author(s):  
Tariq Almubarak ◽  
Mohammed AlKhaldi ◽  
Jun Hong Ng ◽  
Hisham A. Nasr-El-Din

Summary Typically, water-based fracturing treatments consume a large volume of fresh water. Providing consistent freshwater sources is difficult and sometimes not feasible, especially in remote areas and offshore operations. Therefore, several seawater-based fracturing fluids have been developed in an effort to preserve freshwater resources. However, none of these fluids minimizes fracture-face skin and proppant-conductivity impairment, which can be critical for unconventional well treatments. Several experiments and design iterations were conducted to tailor raw-seawater-based fracturing fluids. These fluids were designed to have rheological properties that can transport proppant under dynamic and static conditions. The optimized seawater-based fracturing-fluid formulas were developed such that no scale forms when additives are mixed in or when the fracturing-fluid filtrate is mixed with different formation brines. The tests were conducted using a high-pressure/high-temperature (HP/HT) rheometer, coreflood, and by aging cells at 250 to 300°F. The developed seawater-based fracturing fluids were optimized with an apparent viscosity greater than 100 cp at a shear rate of 100 seconds–1 and a temperature of 300°F for more than 1 hour. The use of polymeric- and phosphonate-based scale inhibitors (SIs) prevented the formation of severe calcium sulfate (CaSO4) scale in mixtures of seawater and formation brines at 300°F. Controlling the pH of fracturing fluids prevented magnesium and calcium hydroxide precipitation that occurs at a pH value of greater than 9.5. Most importantly, SIs had a negative effect on the viscosity of seawater fracturing fluid during testing because of their negative interaction with metallic crosslinkers. The developed seawater-based fracturing fluids were applied for the first time in an unconventional and a conventional carbonate well and showed very promising results; details of field treatments are discussed in this paper.


2019 ◽  
Vol 819 ◽  
pp. 45-50 ◽  
Author(s):  
Nway Nway Aung ◽  
Yin Yin Myat ◽  
Tanasait Ngawhirunpat ◽  
Theerasak Rojanarata ◽  
Prasopchai Patrojanasophon ◽  
...  

This study aimed to evaluate the optimal conditions for crosslinked of PAMA/PVA microneedle (MN) arrays. Poly (acrylic acid-co-maleic acid) (PAMA)/poly (vinyl alcohol) (PVA) MN arrays were fabricated for the first time using the micromolding technique. The PAMA/PVA MN arrays at the polymer ratio of 1:4 were sharp, homogenous and perfectly formed with an elegant appearance. The successfully crosslinking MN arrays were determined using FTIR and water insolubilization. The results showed that increasing the crosslinking temperature and time, the degree of crosslinking also improved, which results in a decline in water uptake. The optimal crosslinking condition for PAMA/PVA MN arrays was 130°C for 1 h. Moreover, the highest swelling was observed from crosslinked PAMA/PVA MN arrays at 90°C for 0.5 h. These studies suggest that the combination of PAMA and PVA for fabrication of MN arrays could have a great potential to develop both hydrogel and dissolving MN devices for transdermal drug delivery.


2014 ◽  
Vol 70 (10) ◽  
pp. 1602-1609 ◽  
Author(s):  
Rui Dong ◽  
Jianxun Zhang ◽  
Bingqian Zhou ◽  
Jian Zhou

Two quaternized ammonium poly(vinyl alcohol) (QPVA)-based hybrid anion exchange membranes were successfully fabricated by using sol–gel method. The mass ratios of QPVA aqueous solution to polydimethyl allyl chloride (PDADMAC) aqueous solution were 4:1 and 2:1, then 10 wt% tetraethyl orthosilicate (TEOS) was added. The obtained membranes were separately designated as QPVA/0.25PDADMAC/0.1TEOSm and QPVA/0.5PDADMAC/0.1TEOSm. The properties for the adsorption removal of Cr(VI) and the effect on the Cr(VI) saturation adsorption amount and removal rate were investigated. Results indicated the adsorption was an exothermal reaction. Thus, low temperature was beneficial for the removal of Cr(VI). Optimal removal of Cr(VI) was achieved using the QPVA/0.5PDADMAC/0.1TEOSm membrane at a pH value of 2. Dynamic simulation was carried out simultaneously to determine if particle diffusion was the sole contributor for the adsorption rate, which was in accordance with the Langmuir isotherm adsorption model. Furthermore, the static adsorption amount (Q0) was 61.77 mg/g, and the efficiency of recycling the hybrid membranes was higher than 90%. Scanning electron microscopy (SEM) characterization showed the surface and the cross-section tightened after the Cr(VI) adsorption, thereby demonstrating the potential application of these hybrid membranes for Cr(VI) removal.


2008 ◽  
Vol 42 (1) ◽  
pp. 10-14 ◽  
Author(s):  
Dimas R. Vollet ◽  
Dario A. Donatti ◽  
Alberto Ibañez Ruiz

Small-angle X-ray scattering was used to study structural modifications in tetraethoxysilane-derived poly(vinyl alcohol) (PVA)/silica hybrids. The basic structure of the wet gels can be described as a mass-fractal structure with fractal dimensionDequal to 2 and characteristic length ξ, which increases with addition of PVA. Wet gels with high PVA content exhibit a positive deviation from the mass-fractal power-law scattering at lowq; this deviation is associated with additional scattering due to a second large correlation distance ζ, reinforced by the addition of PVA. The fraction of both contributions to the total correlation function was estimated; this is the first time that such a study has been carried out for mass-fractal structures.


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