Two Different States of Copper Ions in Zeolites

2014 ◽  
Vol 880 ◽  
pp. 151-154 ◽  
Author(s):  
Andrey Efimov ◽  
Alexey Pestryakov ◽  
Miguel Ángel Hernández Espinosa ◽  
Fernando Chávez Rivas ◽  
Vitalii Petranovskii
Keyword(s):  
Aqueous Solutions ◽  
Copper Ions ◽  
Copper Ion ◽  
Zeolite X ◽  
Copper Salts ◽  
Coordination Polyhedra ◽  
Oxygen Coordination ◽  
Different Temperatures ◽  
Copper Cations ◽  
Isolated Species

This work is devoted to the study of copper ion positions in zeolite matrices. Copper cations were exchanged in mordenite and zeolite X from aqueous solutions of different copper salts varying their concentrations. Electronic state of copper in ion-exchanged samples exchanged and dried at different temperatures was evaluated by XPS spectroscopy. Depending on conditions of exchange treatment copper was found to be distributed between two different accessible sites in zeolites. These copper ions are stabilized as isolated species with well-defined oxygen coordination polyhedra.

scholarly journals An Investigation on Design and Characterization of a Highly Selective LED Optical Sensor for Copper Ions in Aqueous Solutions

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1099
Author(s):  
Sheng-Chun Hung ◽  
Chih-Cheng Lu ◽  
Yu-Ting Wu
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Copper Ions ◽  
Incident Light ◽  
Copper Ion ◽  
Intensity Change ◽  
Optical Absorbance ◽  
Sensing System ◽  
Optic Sensor ◽  
Cu Ions

The optical characteristics of copper ion detection, such as the photometric absorbance of specific wavelengths, exhibit significant intensity change upon incident light into the aqueous solutions with different concentrations of metal ions due to the electron transition in the orbit. In this study, we developed a low-cost, small-size and fast-response photoelectric sensing prototype as an optic sensor for copper (Cu) ions detection by utilizing the principle of optical absorption. We quantified the change of optical absorbance from infra-red (IR) light emitting diodes (LEDs) upon different concentrations of copper ions and the transmitted optical signals were transferred to the corresponding output voltage through a phototransistor and circuit integrated in the photoelectric sensing system. The optic sensor for copper (Cu) ions demonstrated not only excellent specificity with other metal ions such as cadmium (Cd), nickel (Ni), iron (Fe) and chloride (Cl) ions in the same aqueous solution but also satisfactory linearity and reproducibility. The sensitivity of the preliminary sensing system for copper ions was 29 mV/ppm from 0 to 1000 ppm. In addition, significant ion-selective characteristics and anti-interference capability were also observed in the experiments by the proposed approach.

Calorimetric and Spectroscopic investigations οf β-lactoglobulin upon interaction with copper ion

2012 ◽  
Vol 79 (2) ◽  
pp. 209-215 ◽  
Author(s):  
Adeleh Divsalar ◽  
Sajedeh Ebrahim Damavandi ◽  
Ali Akbar Saboury ◽  
Arefeh Seyedarabi ◽  
Ali Akbar Moosavi-Movahedi
Keyword(s):  
Tertiary Structure ◽  
Copper Ions ◽  
Copper Ion ◽  
Industrial Applications ◽  
Titration Calorimetry ◽  
Different Temperatures ◽  
Uv Visible ◽  
Cd Studies ◽  
Effect Of Copper ◽  
Β Lactoglobulin

The effect of copper(II) ions (Cu+2) on the structure of β-lactoglobulin (β-lg) was investigated spectroscopically using UV-visible, fluorescence and circular dichroism (CD) and calorimetrically using isothermal titration calorimetry (ITC), at different temperatures. Results of the UV-visible studies showed that adding Cu+2 to β-lg solution caused increasing turbidity, indicative of protein aggregation. It was noticeable that the rate of increasing turbidity was directly proportional to increasing temperature. The far-UV CD studies displayed that the Cu+2 cannot induce any significant changes in the secondary structures of β-lg at different temperatures. Also, the ITC data indicated that the binding process of Cu+2 to β-lg is mainly entropically driven. The results highlight that copper ions cause the tertiary structure of β-lg to change and induce a slightly open structure leading to the formation of supramolecular aggregates in β-lg which may result in the reduced allergenicity of β-lg and its increased use in industrial applications.

scholarly journals Removal of copper from copper-contaminated river water and aqueous solutions using Methylobacterium extorquens modified Erzurum clayey soil

2016 ◽  
Vol 42 (4) ◽  
pp. 58-69 ◽  
Author(s):  
Neslihan Celebi ◽  
Hayrunnisa Nadaroglu ◽  
Ekrem Kalkan ◽  
Recep Kotan
Keyword(s):  
Aqueous Solutions ◽  
River Water ◽  
Clay Soil ◽  
Clayey Soil ◽  
Copper Ions ◽  
Copper Ion ◽  
Methylobacterium Extorquens ◽  
Copper Adsorption ◽  
Modified Clay ◽  
Freundlich Isotherms

Abstract The objective of this study was to investigate the possibility of using natural and bacteria-modified Erzurum clayey soil with Methylobacterium extorquens as an alternative to high cost commercial adsorbent materials for the removal of copper from aqueous solution. The copper concentrations in the samples of the polluted river water and CuCl2 solutions treated by the natural and bacteria-modified Erzurum clayey soil (ECS) have been determined by spectrophotometric method. Firstly, the surface of ECS was modified with M. extorquens and surface functionality was increased. Then, the adsorption of Cu (II) from solution phases was studied with respect to varying metal concentration, pH, and temperature and agitation time. The maximum adsorption of Cu (II) for natural and bacteria-modified Erzurum clayey soil was observed at pH: 5.0. At different copper concentrations, copper adsorption analysis was performed on 1 g using clay soil or modified clay soil. Maximum adsorption of Cu (II) was obtained as 45.7 and 48.1 mg g-1 at initial concentration (50 mg/50 mL) and optimal conditions by natural and bacteria-modified clay soil, respectively. The copper concentration was decreased in the substantial amount of the leachates solutions of natural and bacteria-modified clay soil. Langmuir and Freundlich isotherms were used to describe the adsorption behavior of Cu (II) ions. The results showed that modified clay soil had a high level of adsorption capacity for copper ion. The various thermodynamic parameters such as ΔG°, ΔH° and ΔS° were analyzed to observe the nature of adsorption. The structural properties of the natural and bacteria-modified-ECS have been characterized by SEM, FTIR and XRD techniques. Consequently, it was concluded that the bacteria-modified clay soil could be successfully used for the removal of the copper ions from the aqueous solutions.

Kinetics and thermodynamics of the sorption of furaltadone from aqueous solutions on magnetic multi-walled carbon nanotubes

2014 ◽  
Vol 70 (6) ◽  
pp. 964-971
Author(s):  
Xu Chen ◽  
Zhen-hu Xiong
Keyword(s):  
Carbon Nanotubes ◽  
Aqueous Solutions ◽  
Sorption Data ◽  
Multi Wall Carbon Nanotubes ◽  
Adsorption Behaviors ◽  
Different Temperatures ◽  
Multi Walled Carbon Nanotubes ◽  
Pseudo Second Order ◽  
Experimental Data Analysis ◽  
Walled Carbon Nanotubes

Magnetic multi-wall carbon nanotubes (M-MWCNTs) were used as an adsorbent for removal of furaltadone from aqueous solutions, and the adsorption behaviors were investigated by varying pH, sorbent amount, sorption time and temperature. The results showed that the adsorption efficiency of furaltadone reached 97% when the dosage of M-MWCNT was 0.45 g · L−1, the pH was 7 and the adsorption time was 150 min. The kinetic data showed that the pseudo-second-order model can fit the adsorption kinetics. The sorption data could be well explained by the Langmuir model under different temperatures. The adsorption process was influenced by both intraparticle diffusion and external mass transfer. The experimental data analysis indicated that the electrostatic attraction and π–π stacking interactions between M-MWCNT and furaltadone might be the adsorption mechanism. Thermodynamic analysis reflected that adsorption of furaltadone on the M-MWCNT was spontaneous and exothermic. Our study showed that M-MWCNTs can be used as a potential adsorbent for removal of furaltadone from water and wastewater.

Removal of Copper Ions from Aqueous Solutions via Adsorption on Carbon Nanocomposites

2015 ◽  
Vol 7 (28) ◽  
pp. 15674-15680 ◽  
Author(s):  
Anthony B. Dichiara ◽  
Michael R. Webber ◽  
William R. Gorman ◽  
Reginald E. Rogers
Keyword(s):  
Aqueous Solutions ◽  
Copper Ions ◽  
Carbon Nanocomposites

Biosorption of copper ions from aqueous solutions using the desert treeAcacia raddiana

2010 ◽  
Vol 21 (1-3) ◽  
pp. 323-327 ◽  
Author(s):  
M. F. Talhi ◽  
A. Cheriti ◽  
N. Belboukhari ◽  
L. Agha ◽  
C. Roussel
Keyword(s):  
Aqueous Solutions ◽  
Copper Ions

scholarly journals Ein Wasserstoffisotopieeffekt im CuSO4 * 5H2O

1969 ◽  
Vol 24 (10) ◽  
pp. 1502-1511
Author(s):  
Karl Heinzinger
Keyword(s):  
Water Vapor ◽  
Aqueous Solutions ◽  
Separation Factor ◽  
Room Temperature ◽  
Copper Ion ◽  
Hydrogen Isotopes ◽  
Bulk Water ◽  
Water Molecules ◽  
Hydration Water ◽  
Sulfate Solutions

Abstract There are two kinds of water in CuSO4·5H2O differing by their binding in the crystal. The oxygen of four water molecules is bonded to the copper ion, that of the fifth molecule is hydrogen bonded. It is shown that the D/H ratios of these two kinds of water differ by 5.7%, the light isotope being enriched in the water molecules coordinated with the copper ion. The results show that there is no exchange of the hydrogen isotopes during the time needed for dehydration at room temperature which takes several days. The assumption has been confirmed that the water coordinated with the copper ion leaves the crystal first on dehydration at temperatures below 50 °C. Additional measurements of the separation factor for the hydrogen isotopes between water vapor and copper sulfate solutions allow conclusions on the fractionation of the hydrogen isotopes between bulk water and hydration water in aqueous solutions.

Effect of Sodium Sulphate on the Volumetric, Rheological and Refractometric Properties of some Disaccharides in Aqueous Solutions at Different Temperatures

2008 ◽  
Vol 222 (1) ◽  
pp. 177-204 ◽  
Author(s):  
Parampaul Kaur Banipal ◽  
Harpreet Singh Dhanjun ◽  
Suman Sharma ◽  
Harneet Hundal ◽  
Tarlok Singh Banipal
Keyword(s):  
Aqueous Solutions ◽  
Sodium Sulphate ◽  
Different Temperatures

Biomimetic synthesis of needle-like fluorescent calcium phosphate/carbon dot hybrid composites for cell labeling and copper ion detection

2016 ◽  
Vol 45 (18) ◽  
pp. 7665-7671 ◽  
Author(s):  
Shanshan Guo ◽  
Shousi Lu ◽  
Pingxiang Xu ◽  
Yi Ma ◽  
Liang Zhao ◽  
...  
Keyword(s):  
Drinking Water ◽  
Calcium Phosphate ◽  
Copper Ions ◽  
Hybrid Composites ◽  
Copper Ion ◽  
Cell Labeling ◽  
Biomimetic Synthesis ◽  
Selective Detection ◽  
Sodium Carboxymethylcellulose ◽  
Biomimetic Method

We report a biomimetic method to synthesize needle-like calcium phosphate (CaP) using carbon dots (CDs) and sodium carboxymethylcellulose as dual templates. The CaP/CDs were capable of cell labeling and selective detection of copper ions in drinking water.

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