1,8-Naphthyridine Modified Rhodamine B Derivatives: Turn-On Colorimetric Sensor for Cu2+

2014 ◽  
Vol 881-883 ◽  
pp. 1079-1082 ◽  
Author(s):  
Gao Zhang Gou ◽  
He Ping Yan ◽  
Shi Juan Xu ◽  
Na Wu ◽  
Bo Zhou ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Complex Formation ◽  
Metal Complex ◽  
Rhodamine B ◽  
Ring Opening ◽  
High Selectivity ◽  
Colour Change ◽  
Detection Mechanism ◽  
Biologically Relevant ◽  
Turn On

A 1,8-naphthyridine modified rhodamine B derivative, one Cu2+-selective chemosensors was designed, synthesized and characterized, which display a high selectivity for Cu2+among environmentally and biologically relevant metal ions. It can detect Cu2+in aqueous solution selectively with a dramatic colour change from colorless to magenta. The detection mechanism involves a ring-opening process as a consequence of metal complex formation. Jobs plots study indicated that the chemosensor chelated Cu2+with 2:1 stoichiometry.

Colorimetric and Fluorescent Probe for Hypochlorite with High Selectivity

2013 ◽  
Vol 295-298 ◽  
pp. 475-478 ◽  
Author(s):  
Zhi Xiang Han ◽  
Ming Hui Du ◽  
Guo Xi Liang ◽  
Xiang Yang Wu
Keyword(s):  
Reactive Oxygen Species ◽  
Aqueous Solution ◽  
Detection Limit ◽  
Fluorescent Probe ◽  
Rhodamine B ◽  
High Selectivity ◽  
Reactive Oxygen ◽  
Living Cells ◽  
Oxygen Species ◽  
Turn On

Rhodamine B thiohydrazide (RBS) was firstly employed as turn-on fluorescent probe for hypochlorite in aqueous solution and living cells. It exhibits a stable response to hypochlorite from 1.0×10-6to 1.0×10-5M with a detection limit of 3.3×10-7M. The response of this probe to hypochlorite is fast and highly selective compared with other reactive oxygen species (such as.OH,1O2, H2O2) and other common anions (such as X-, ClO2-, ClO4-, NO3-, NO2-, OH-, Ac-, CO32-, SO42-).

Xanthurenic acid: a natural ionophore with high selectivity and sensitivity for potassium ions in an aqueous solution

2016 ◽  
Vol 40 (3) ◽  
pp. 1930-1934 ◽  
Author(s):  
M. Raju ◽  
Tapasya J. Patel ◽  
Ratish R. Nair ◽  
Pabitra B. Chatterjee
Keyword(s):  
Aqueous Solution ◽  
Detection Limit ◽  
Metal Ions ◽  
High Selectivity ◽  
Xanthurenic Acid ◽  
Potassium Ions ◽  
Turn On ◽  
Tryptophan Metabolite

Synopsis: A well-known tryptophan metabolite, xanthurenic acid, a natural non-fluorescent intermediate siderophore, showed a very selective turn-on response to K+ over other competing metal ions and the detection limit of this natural ionophore was found to be 53 nM at physiological pH.

A novel rhodamine-based fluorescent probe for selective detection of ClO– and its application in living cell imaging

2018 ◽  
Vol 96 (12) ◽  
pp. 1129-1133
Author(s):  
Changping Yang ◽  
Mingliang Zuo ◽  
Xiaoli Hu ◽  
Xuelin Chen ◽  
Duoduo Zhang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Cell Imaging ◽  
High Selectivity ◽  
Fluorescence Enhancement ◽  
Colour Change ◽  
Living Cells ◽  
Fluorescent Imaging ◽  
Selective Detection ◽  
Living Cell Imaging ◽  
Interfering Ions

A novel fluorescent rhodamine-based probe L for selective responding to ClO– has been synthesized and characterized. The spectroscopy showed that probe L can detect ClO– in aqueous solution without interaction with other interfering ions, and the detection is also evident by the colour change from colourless to reddish purple under white light. The remarkable fluorescence enhancement showed the high selectivity and sensitivity of probe L for the detection of ClO–. Furthermore, probe L was applied to intracellular fluorescent imaging of HeLa cells treated with ClO– and MTT assay showed nontoxicity in living cells.

A fluorescence turn-on probe for human (bovine) serum albumin based on the hydrolysis of a dioxaborine group promoted by proteins

2017 ◽  
Vol 53 (48) ◽  
pp. 6432-6435 ◽  
Author(s):  
Qian Sun ◽  
Weisi Wang ◽  
Zhaoyang Chen ◽  
Yuhua Yao ◽  
Weibing Zhang ◽  
...  
Keyword(s):  
Bovine Serum Albumin ◽  
Serum Albumin ◽  
Bovine Serum ◽  
High Selectivity ◽  
Biologically Relevant ◽  
Turn On ◽  
Fluorescence Turn On ◽  
Hydrolysis Of

A reaction-based florescence probe CBF for serum albumin (SA) was proposed by connecting a dioxaborine unit with environment-sensitive coumarin fluorophore. CBF exhibits high selectivity and sensitivity toward SA over other biologically relevant species and has potential of detecting SA in biosamples.

A reaction-based fluorescent turn-on probe for Cu2+ in complete aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87110-87114 ◽  
Author(s):  
Dongjian Zhu ◽  
Yanghe Luo ◽  
Xiaowei Yan ◽  
Wei Xie ◽  
Wen Cai ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Response Time ◽  
High Selectivity ◽  
High Sensitivity ◽  
Rapid Response ◽  
Turn On

FP can detect Cu2+ in complete aqueous solution with a rapid response time, high sensitivity, and high selectivity.

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