Liquid Phase Sintering of Barium Titanate Ceramics for High Energy Density Capacitors

2008 ◽  
Vol 368-372 ◽  
pp. 40-42 ◽  
Author(s):  
Jia Jia Huang ◽  
Yong Zhang
Keyword(s):  
Liquid Phase ◽  
Barium Titanate ◽  
Volume Fraction ◽  
Breakdown Strength ◽  
High Energy ◽  
Liquid Phase Sintering ◽  
High Energy Density ◽  
High Electrical Resistivity ◽  
Titanate Ceramics ◽  
Glass Compositions

Several glass compositions with high electrical resistivity were developed and added to the barium titanate ceramics. The glass additions were found to greatly increase the breakdown strength of the composite ceramics which has a 0-3 connectivity. The electrical properties of the liquid phase sintered ceramics are sensitive to the variations of the volume fraction and connectivity of the glass phase.

scholarly journals Significantly Enhanced Energy Storage Density by Modulating the Aspect Ratio of BaTiO3 Nanofibers

2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Dou Zhang ◽  
Xuefan Zhou ◽  
James Roscow ◽  
Kechao Zhou ◽  
Lu Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Aspect Ratio ◽  
Volume Fraction ◽  
Breakdown Strength ◽  
Electric Displacement ◽  
High Energy ◽  
High Energy Density ◽  
Energy Storage Density ◽  
Storage Density

Abstract There is a growing need for high energy density capacitors in modern electric power supplies. The creation of nanocomposite systems based on one-dimensional nanofibers has shown great potential in achieving a high energy density since they can optimize the energy density by exploiting both the high permittivity of ceramic fillers and the high breakdown strength of the polymer matrix. In this paper, BaTiO3 nanofibers (NFs) with different aspect ratio were synthesized by a two-step hydrothermal method and the permittivity and energy storage of the P(VDF-HFP) nanocomposites were investigated. It is found that as the BaTiO3 NF aspect ratio and volume fraction increased the permittivity and maximum electric displacement of the nanocomposites increased, while the breakdown strength decreased. The nanocomposites with the highest aspect ratio BaTiO3 NFs exhibited the highest energy storage density at the same electric field. However, the nanocomposites with the lowest aspect ratio BaTiO3 NFs achieved the maximal energy storage density of 15.48 J/cm3 due to its higher breakdown strength. This contribution provides a potential route to prepare and tailor the properties of high energy density capacitor nanocomposites.

Enhanced electric breakdown strength and high energy density of barium titanate filled polymer nanocomposites

2013 ◽  
Vol 114 (17) ◽  
pp. 174107 ◽  
Author(s):  
Ke Yu ◽  
Yujuan Niu ◽  
Feng Xiang ◽  
Yongcun Zhou ◽  
Yuanyuan Bai ◽  
...  
Keyword(s):  
Energy Density ◽  
Barium Titanate ◽  
Polymer Nanocomposites ◽  
Breakdown Strength ◽  
High Energy ◽  
Electric Breakdown ◽  
High Energy Density ◽  
Filled Polymer

Effect of Liquid-Phase Sintering on the Breakdown Strength of Barium Titanate

2007 ◽  
Vol 90 (5) ◽  
pp. 1504-1510 ◽  
Author(s):  
A. Young ◽  
G. Hilmas ◽  
S. C. Zhang ◽  
R. W. Schwartz
Keyword(s):  
Liquid Phase ◽  
Barium Titanate ◽  
Breakdown Strength ◽  
Liquid Phase Sintering

Fluorocarboxylic acid-modified barium titanate/poly(vinylidene fluoride) composite with significantly enhanced breakdown strength and high energy density

RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64596-64603 ◽  
Author(s):  
Yujuan Niu ◽  
Ke Yu ◽  
Yuanyuan Bai ◽  
Feng Xiang ◽  
Hong Wang
Keyword(s):  
Energy Density ◽  
Barium Titanate ◽  
Vinylidene Fluoride ◽  
Breakdown Strength ◽  
High Energy ◽  
High Energy Density ◽  
Surface Modifier ◽  
Poly Vinylidene Fluoride

Fluorocarboxylic acid, as a novel surface modifier for BT nanoparticles, has significantly improved the performance of the BT/PVDF composites.

scholarly journals Recent Advances in the Synthesis of Polymer-Grafted Low-K and High-K Nanoparticles for Dielectric and Electronic Applications

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2942
Author(s):  
Bhausaheb V. Tawade ◽  
Ikeoluwa E. Apata ◽  
Nihar Pradhan ◽  
Alamgir Karim ◽  
Dharmaraj Raghavan
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
High Performance ◽  
Breakdown Strength ◽  
Polymer Nanocomposite ◽  
High Energy ◽  
Polymer Chains ◽  
High Energy Density ◽  
Grafted Nanoparticles ◽  
Grafting From

The synthesis of polymer-grafted nanoparticles (PGNPs) or hairy nanoparticles (HNPs) by tethering of polymer chains to the surface of nanoparticles is an important technique to obtain nanostructured hybrid materials that have been widely used in the formulation of advanced polymer nanocomposites. Ceramic-based polymer nanocomposites integrate key attributes of polymer and ceramic nanomaterial to improve the dielectric properties such as breakdown strength, energy density and dielectric loss. This review describes the ”grafting from” and ”grafting to” approaches commonly adopted to graft polymer chains on NPs pertaining to nano-dielectrics. The article also covers various surface initiated controlled radical polymerization techniques, along with templated approaches for grafting of polymer chains onto SiO2, TiO2, BaTiO3, and Al2O3 nanomaterials. As a look towards applications, an outlook on high-performance polymer nanocomposite capacitors for the design of high energy density pulsed power thin-film capacitors is also presented.

Enhanced dielectric properties and thermostability in polyimide composites with core-shell structured polyimide@BaTiO3 nanoparticles

2021 ◽  
pp. 095400832199352
Author(s):  
Wei Deng ◽  
Guanguan Ren ◽  
Wenqi Wang ◽  
Weiwei Cui ◽  
Wenjun Luo
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Energy Density ◽  
Breakdown Strength ◽  
In Situ Polymerization ◽  
Dielectric Materials ◽  
High Energy ◽  
Amic Acid ◽  
High Energy Density ◽  
Core Shell

Polymer composites with high dielectric constant and thermal stability have shown great potential applications in the fields relating to the energy storage. Herein, core-shell structured polyimide@BaTiO3 (PI@BT) nanoparticles were fabricated via in-situ polymerization of poly(amic acid) (PAA) and the following thermal imidization, then utilized as fillers to prepare PI composites. Increased dielectric constant with suppressed dielectric loss, and enhanced energy density as well as heat resistance were simultaneously realized due to the presence of PI shell between BT nanoparticles and PI matrix. The dielectric constant of PI@BT/PI composites with 55 wt% fillers increased to 15.0 at 100 Hz, while the dielectric loss kept at low value of 0.0034, companied by a high energy density of 1.32 J·cm−3, which was 2.09 times higher than the pristine PI. Moreover, the temperature at 10 wt% weight loss reached 619°C, demonstrating the excellent thermostability of PI@BT/PI composites. In addition, PI@BT/PI composites exhibited improved breakdown strength and toughness as compared with the BT/PI composites due to the well dispersion of PI@BT nanofillers and the improved interfacial interactions between nanofillers and polymer matrix. These results provide useful information for the structural design of high-temperature dielectric materials.

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