Optimum Sintering Temperature for Fabrication of 0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3 Lead-Free Ceramics by Combustion Technique

2011 ◽  
Vol 474-476 ◽  
pp. 1754-1759 ◽  
Author(s):  
Atthakorn Thongtha ◽  
Theerachai Bongkarn
Keyword(s):  
Dielectric Constant ◽  
Remanent Polarization ◽  
Sintering Temperature ◽  
Sodium Titanate ◽  
Lead Free ◽  
Bismuth Sodium Titanate ◽  
Sintered Ceramic ◽  
Lead Free Ceramics ◽  
Average Grain Size ◽  
Combustion Technique

The effect of sintering temperatures (1050-1200 °C) on the phase formation, microstructure and dielectric properties of a binary system lead-free ceramic bismuth sodium titanate–bismuth potassium titanate were investigated. 0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3; BNKT ceramics were successfully fabricated using the combustion technique. XRD results showed the rhombohedral-tetragonal morphotropic phase boundary (MPB). The SEM results showed the average grain size (0.51-2.59 µm) of the samples increased with the increase of sintering temperatures. The sample sintered at the optimum temperature of 1150 °C exhibited the maximum density, shrinkage, dielectric constant at Curie temperature and remanent polarization (Pr) which were around 5.65 g/cm3, 17.75%, 5014 and 1.6 mC/cm2, respectively. The dielectric constant was related to the XRD results and density of the sintered ceramic.

Electrical Properties of Modified BNT Based Lead-Free Ceramics

2016 ◽  
Vol 872 ◽  
pp. 87-91
Author(s):  
Supalak Manotham ◽  
Tawee Tunkasiri ◽  
Pharatree Jaita ◽  
Pichitchai Butnoi ◽  
Denis Russell Sweatman ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Solid State ◽  
Electrical Properties ◽  
Sintering Temperature ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Second Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Lead Free Ceramics

The properties of modified Bi0.5Na0.5TiO3 (BNT) based lead-free ceramics were investigated. The BNT-based ceramics were prepared by a solid-state mixed oxide method Phase formation was determined by X-ray diffraction technique (XRD). The X-ray diffraction analysis of the ceramics suggested that all samples exhibited a perovskite structure without second phase. The value of dielectric constant increased with increasing in sintering temperature. Moreover, high sintering temperatures could improve ferroelectric properties of BNT base lead-free ceramics.

Giant piezoelectricity and ultrahigh strain response in bismuth sodium titanate lead-free ceramics

2016 ◽  
Vol 165 ◽  
pp. 143-146 ◽  
Author(s):  
Renfei Cheng ◽  
Lunan Zhu ◽  
Yalong Zhu ◽  
Zhijun Xu ◽  
Ruiqing Chu ◽  
...  
Keyword(s):  
Sodium Titanate ◽  
Lead Free ◽  
Strain Response ◽  
Bismuth Sodium Titanate ◽  
Lead Free Ceramics ◽  
Titanate Lead ◽  
Bismuth Sodium ◽  
Ultrahigh Strain

The Research on the Piezoelectric and Dielectric Properties of Bi0.5(Nak)0.5-BaTiO3 Lead-Free Ceramics

2014 ◽  
Vol 1035 ◽  
pp. 422-425
Author(s):  
Jian Yong Guo ◽  
Tao Sheng Zhou ◽  
Ji Hong Liao
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Perovskite Structure ◽  
Relative Dielectric Constant ◽  
Lead Free ◽  
Reactive Sintering ◽  
Lead Free Ceramics ◽  
Xrd Patterns ◽  
Sintering Method

The Bi0.5(Na1-xKx)0.5-yBaTiO3(BNK-BT) lead-free ceramics have been prepared by the solild reactive sintering method. XRD patterns show the BNK-BT ceramics had a perovskite structure. Piezoelectric and dielectric properties of the ceramics also have been studied. The results show that the samples had the best piezoelectric and dielectric properties when x=0.20, y=0.10. And the maximum of d33is 149 pC/N, while the relative dielectric constant is 1087.

Preparation and Properties of Bi0.5Na0.5TiO3-Ba (Hf,Ti)TiO3 Lead-Free Piezoelectric Ceramics

2007 ◽  
Vol 334-335 ◽  
pp. 957-960
Author(s):  
Hu Yong Tian ◽  
Wan Ping Chen ◽  
D.Y. Wang ◽  
Y. Wang ◽  
J.T. Zeng ◽  
...  
Keyword(s):  
Piezoelectric Coefficient ◽  
Sodium Titanate ◽  
Piezoelectric Ceramics ◽  
Lead Free ◽  
Synthesis Process ◽  
Bismuth Sodium Titanate ◽  
Promising Candidate ◽  
Device Applications ◽  
The Relationship ◽  
Bismuth Sodium

Lead-free piezoelectric ceramics based on bismuth sodium titanate (BNT) -barium hafnate titanate (BHT) were prepared by a two-step synthesis process. The final BNT-BHT ceramics sintered at 1180oC for 2 h in air showed a perovskite structure with high density. The morphotropic phase boundaries (MPB) were found in BNT based piezoelectric ceramics with 8~10 wt% BHT in composites. In the case of Bi0.5Na0.5TiO3-0.08BaHf0.05Ti0.95O3 ceramics, a maximum piezoelectric coefficient d33 of 122.6 pC/N was obtained. The remnant polarization (Pr) and coercive field (Ec) were measured and the relationship between ferroelectricity and the BHT fraction in the compounds was investigated. The BNT-BHT ceramics were expected to be a new and promising candidate for lead-free piezoelectric device applications.

scholarly journals Effect of sintering temperature on the dielectric, ferroelectric and energy storage properties of SnO2-doped Bi0.5(Na0.8K0.2)0.5TiO3 lead-free ceramics

2020 ◽  
Vol 10 (04) ◽  
pp. 2050011
Author(s):  
Nguyen Truong-Tho ◽  
Le Dai Vuong
Keyword(s):  
Dielectric Constant ◽  
Energy Storage ◽  
Sintering Temperature ◽  
High Energy ◽  
Lead Free ◽  
Energy Storage Properties ◽  
Energy Storage Efficiency ◽  
High Dielectric ◽  
Storage Properties ◽  
High Energy Storage

Sintered lead-free [Formula: see text]([Formula: see text][Formula: see text]([Formula: see text][Formula: see text]O3 ceramics (BNKTS) have been fabricated via a solid-state reaction. The effect of sintering temperature on the structural, morphological, dielectric, ferroelectric and energy storage properties of BNKTS ceramics was investigated, and it was found that the electrical properties of the synthesized ceramics increased with the increase in the sintering temperature, and the highest values were achieved at [Formula: see text]C. The ceramics sintered at the optimized temperature of [Formula: see text]C exhibited the best physical, dielectric, ferroelectric and energy storage properties, namely, high density (the relative density, [Formula: see text][Formula: see text]g.cm[Formula: see text], approximate to 96.7% of the theoretical value), high densification factor ([Formula: see text]), high dielectric constant ([Formula: see text]), low dielectric loss (tan[Formula: see text]), highest dielectric constant ([Formula: see text]), high remanent polarization ([Formula: see text]C.cm[Formula: see text], high coercive field ([Formula: see text][Formula: see text]kV/cm), high energy storage density (0.12[Formula: see text]J/cm[Formula: see text], and high energy storage efficiency (41.7% at 46.3[Formula: see text]kV/cm).

The Electrical Properties of BCZT Lead-Free Ceramics Induced by BaZrO3 Seeds

2016 ◽  
Vol 690 ◽  
pp. 114-119
Author(s):  
Piewpan Parjansri ◽  
Manlika Kamnoy ◽  
Uraiwan Intatha ◽  
Sukum Eitssayeam ◽  
Tawee Tunkasiri
Keyword(s):  
Grain Size ◽  
Electrical Properties ◽  
Perovskite Phase ◽  
Nano Particle ◽  
Sintered Ceramic ◽  
Voltage Coefficient ◽  
Lead Free Ceramics ◽  
Seed Content ◽  
Pure Perovskite Phase ◽  
Average Grain Size

Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics were produced by using the seed-induced method. The nano-particle BZ (BaZrO3) seeds were mixed with BaCO3, CaCO3, ZrO2 and TiO2 powder for preparing by the mixed oxide method. The XRD results indicated that all powder and sintered ceramic samples showed a pure perovskite phase with coexistence between rhombohedral and tetragonal phase. As the BZ seed content increased, the density of ceramics tended to decrease from 5.61 g/cm3 to 5.37 g/cm3. The average grain size of the ceramics was in the range of 12.15 -13.50 mm. The dielectric loss (tand) was less than 0.03 for all samples at room temperature (at 1 kHz). Other electrical properties, including dielectric constant (εr), remnant polarization (Pr), and piezoelectric charge coefficient (d33) values decreased with increasing BZ seed doping with relates to the decreasing grain size and density of BCZT ceramics. However, the values of coercive field (Ec) decreased and piezoelectric voltage coefficient (g33) increased with BZ seed doping.

Effect of sintering temperature on microstructure of hydrothermally prepared bismuth sodium titanate ceramics

2004 ◽  
Vol 24 (2) ◽  
pp. 517-520 ◽  
Author(s):  
Pusit Pookmanee ◽  
Gobwute Rujijanagul ◽  
Supon Ananta ◽  
Robert B Heimann ◽  
Sukon Phanichphant
Keyword(s):  
Sintering Temperature ◽  
Sodium Titanate ◽  
Bismuth Sodium Titanate ◽  
Titanate Ceramics ◽  
Bismuth Sodium
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