Obtaining of Composite Alloys Based on Nickel Aluminides with Rare Metals

2021 ◽  
Vol 887 ◽  
pp. 73-78
Author(s):  
Sergey N. Khimukhin ◽  
E.D. Kim ◽  
Ri Khosen

The paper presents the research results on the production of doped composite materials by the method of out-of-furnace liquid-phase self-propagating high-temperature synthesis using oxides and mineral concentrates containing Zr and W as a charge. The positive experience of producing ingots of intermetallic alloys based on the Ni-Al system in one stage of the reduction process of joint metallothermy is shown. The use of Zr in the charge leads to grinding of microstructure of the ingots and the formation of intermetallic compounds containing Zr. The additional use of C, B2O3, and W in the charge results in the formation of complex borides and tungsten carbides in the ingots. Additional introduction of Cr2O3 into the charge is necessary for the formation of W carbides in the nickel aluminide matrix.

2017 ◽  
Vol 28 (11) ◽  
pp. 2974-2979 ◽  
Author(s):  
M. Shekari ◽  
M. Adeli ◽  
A. Khobzi ◽  
M. Kobashi ◽  
N. Kanetake

2020 ◽  
pp. 31-34
Author(s):  
S. N. Khimukhin ◽  
◽  
V. B. Deev ◽  
E. Kh. Ri ◽  
E. D. Kim ◽  
...  

2012 ◽  
Vol 488-489 ◽  
pp. 300-304
Author(s):  
Tawat Chanadee ◽  
Jessada Wannasin ◽  
Sutham Niyomwas

The in-situself propagating high temperature synthesis technique were used to synthesis tungsten based intermetallic alloys from WO3/SiO2/Al and WO3/B2O3/Al reactant mixture system. The reaction was carries out in a SHS reactor under static argon gas at the pressure of 0.5 MPa. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The microstructure and phase distribution of the SHS reaction products were characterized by scanning electron microscopy (SEM) and energy dispersive x-ray (EDX), respectively. The results indicate that complete reaction of precursors to yield Al2O3-WSi2 and Al2O3-WB as product composites with clearly separation between Al2O3 and WB.


2008 ◽  
Vol 138 ◽  
pp. 159-164 ◽  
Author(s):  
Boris B. Khina ◽  
Boleslaw Formanek

The analysis of physicochemical mechanism of the influence of mechanical activation (MA) of a charge mixture on the subsequent self-propagating high-temperature synthesis (SHS) of intermetallic compounds is performed. Numerical estimates have revealed an insignificant role of the energy stored in solid reactants due to cold work during MA. The characteristic time of relaxation of non-equilibrium vacancies, which were generated in metals by MA, during heating in the SHS wave is estimated, and their insignificant influence on the reaction kinetics at high temperatures is demonstrated. It is shown that a strong effect of preliminary MA on SHS can be attributed only to deformation-enhanced solid-state diffusion during MA, which can lead to the formation of a supersaturated solid solution and thus affect the conditions for nucleation of a product phase (intermetallic compound) upon heating.


1990 ◽  
Vol 213 ◽  
Author(s):  
Michael Concannon ◽  
Edwin S. Hodge ◽  
Andrew C. Nyce ◽  
Christopher P. Turmel

ABSTRACTMonolithic Ni 3Al and composite Ni3Al/ceramic whisker bodies were fabricated by combined Self Propagating High Temperature Synthesis and in situ containerless Hot Isostatic Pressing (SHS/HIP), starting from cold pressed blends of nickel, aluminum, and boron powders, with and without additions of alumina whiskers. The resultant bodies were dense and had good ductility and mechanical strength at room temperature.


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