Effect of Intermolecular Interaction on Ionic Conductivity of CMC-DTAB Plasticized with Ec Based Solid Biopolymer Electrolyte

2021 ◽  
Vol 1025 ◽  
pp. 26-31
Author(s):  
Nurhasniza Mamajan Khan ◽  
Noor Saadiah Mohd Ali ◽  
Ahmad Salihin Samsudin
Keyword(s):  
Ionic Conductivity ◽  
Intermolecular Interaction ◽  
Room Temperature ◽  
Ethylene Carbonate ◽  
Ammonium Bromide ◽  
Ftir Analysis ◽  
Biopolymer Electrolytes ◽  
Electrochemical Devices ◽  
Biopolymer Electrolyte ◽  
Conduction Properties

The present work highlights on the structural and conduction properties of the solid biopolymer electrolytes (SBPE) based carboxymethyl cellulose (CMC) doped dodecyltrimethyl ammonium bromide (DTAB) and plasticized with ethylene carbonate (EC). The SBPE exhibits high ionic conductivity at room temperature where the highest value reaching 1.0 x 10-3 S cm-1 for sample containing with 10 wt. % of EC and increases the ionic conductivity when temperature was increased. Complexation within the SBPE has been confirmed by the FTIR analysis where the intermolecular interaction has improvised the coordination between CMC-DTAB and EC resulting in better structural and conductivity ability. The findings suggest that the great potential of CMC and make it promising to serve as an electrolyte for electrochemical devices.

Study on Electrical Conduction Properties of Plasticized CMC-DTAB Based Solid Biopolymer Electrolytes

2021 ◽  
Vol 1025 ◽  
pp. 15-19
Author(s):  
Nor Fatihah Mazuki ◽  
Pramod Kumar Singh ◽  
Ahmad Salihin Samsudin
Keyword(s):  
Ionic Conductivity ◽  
Electrical Conduction ◽  
Ethylene Carbonate ◽  
Electrical Impedance Spectroscopy ◽  
Ammonium Bromide ◽  
Weight Percentage ◽  
Casting Technique ◽  
Solution Casting Technique ◽  
Biopolymer Electrolyte ◽  
Conduction Properties

This work focuses on the electrical properties study of solid biopolymer electrolyte (SBE) based plasticized carboxy methylcellulose (CMC) doped dodecyltrimethyl ammonium bromide (DTAB). Different weight percentage of ethylene carbonate (EC) which acts as plasticizer was incorporated into SBE system and were successfully prepared via solution casting technique. The conduction properties of SBE was investigated by using electrical impedance spectroscopy (EIS). The incorporation of 10 wt.% EC was found to achieve the highest ionic conductivity with 1.00 10-3 S cm-1 at room temperature. All SBE samples shows the ionic conductivity increased proportionally with temperature thus obeys to Arrhenius behaviour with regression value almost close to unity (R2~1). The electrical conduction behaviour of the CMC-DTAB-EC SBE reveals non-Debye behaviour without single relaxation properties.

Conductivity and Transport Properties Study of Plasticized Carboxymethyl Cellulose (CMC) Based Solid Biopolymer Electrolytes (SBE)

2013 ◽  
Vol 856 ◽  
pp. 118-122 ◽  
Author(s):  
A.S. Samsudin ◽  
M.I.N. Isa
Keyword(s):  
Ionic Conductivity ◽  
Carboxymethyl Cellulose ◽  
Room Temperature ◽  
Ethylene Carbonate ◽  
Casting Method ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
Biopolymer Electrolytes ◽  
Arrhenius Relation ◽  
Solution Casting Method

Solid biopolymer electrolytes (SBE) comprising carboxymethyl cellulose (CMC) with NH4Br-EC were prepared by solution casting method. The samples were characterized by impedance spectroscopy (EIS) and sample containing 25wt. % of NH4Br exhibited the highest room temperature conductivity of 1.12 x 10-4S/cm for salted CMC based SBE system. The ionic conductivity increased to 3.31 x 10-3S/cm when 8 wt. % of ethylene carbonate (EC) was added to the highest conductivity. The conductivity-temperature of plasticized SBE system obeys the Arrhenius relation where the ionic conductivity increases with temperature. The influence of EC addition on unplasticized CMC based SBE was found to be dependent on the number and the mobility of the ions. This results revealed that the influence of plasticizer (EC) which was confirmed play the significant role in enhancement of ionic conductivity for SBE system.

Proton Conducting Biopolymer Electrolytes Based on Starch Incorporated with Ammonium Thiocyanate

2015 ◽  
Vol 1112 ◽  
pp. 275-278 ◽  
Author(s):  
Fatin Nabella Zulkefli ◽  
S. Navaratnam ◽  
Azizah Hanom Ahmad
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
Corn Starch ◽  
Ammonium Thiocyanate ◽  
Casting Method ◽  
Arrhenius Model ◽  
Proton Conducting ◽  
Biopolymer Electrolytes ◽  
Solution Casting Method ◽  
Biopolymer Electrolyte

In the present study, proton conducting biopolymer electrolyte systems based on corn starch and NH4SCN salt were prepared using solution casting method. The sample with 30 wt.% NH4SCN exhibited the highest ionic conductivity of 5.54 x 10-3S cm-1at room temperature. Temperature-dependence ionic conductivity relationship obeys Arrhenius model and minimum activation energy of 0.28 eV was obtained for the highest conducting composition.

scholarly journals Caracterización Eléctrica de Membranas Poliméricas PVDF/ CF3COOLi

Respuestas ◽  
2015 ◽  
Vol 20 (1) ◽  
pp. 125 ◽  
Author(s):  
Rodrigo Andrés Vásquez-Bonilla ◽  
Nori Magali Jurado-Meneses ◽  
Miguel Iban Delgado-Rosero
Keyword(s):  
Ionic Conductivity ◽  
Impedance Spectroscopy ◽  
Polyvinylidene Fluoride ◽  
Room Temperature ◽  
Solution Method ◽  
Activation Energies ◽  
Pvdf Membrane ◽  
Conductive Membranes ◽  
Electrochemical Devices

Objetivo: Este documento estudia los efectos del trifluoroacetato de litio (CF3 COOLi) al usarse en una matriz de Polifluoruro de vinilideno (PVDF) para mejorar la conductividad iónica para usarse como electrolito para dispositivos electroquímicos. Metodología: Para esto se prepararon membranas en diferentes combinaciones por el método de solución. Las muestras se caracterizaron por espectroscopía de impedancias entre temperaturas de 298 K y 373 K con el fin de identificar el comportamiento de la conductividad de acuerdo a la concentración. Resultados: Los gráficos de conductividad dc en función del inverso de la temperatura, muestran un comportamiento Vogel-Tammann-Fulcher (VTF) con pseudo-energías de activación entre 7.30 × 10-3 y 5.05 × 10-4 eV. Conclusiones: La máxima conductividad obtenida fue de 3.85 ×10-4 S cm-1 a temperatura ambiente para altas concentraciones de CF3 COOLi, siendo este valor comparable con resultados obtenidos en otros estudios.AbstractObjective: This paper studies the effects of lithium trifluoroacetate (CF3 COOLi) when used in a Polyvinylidene fluoride (PVDF) membrane to improve its ionic conductivity for use as electrolyte for electrochemical devices. Method: CF3 COOLi/PVDF Ionic conductive membranes have been prepared by solution method. The samples were characterized by impedance spectroscopy (IS) with temperatures ranging from 298 K at 373 K. Results: The plots of conductivity with the inverse of temperature show an Vogel-Tamman-Fulcher (VTF) behavior, with pseudo activation energies between 7.30 × 10-3 y 5.05 × 10-4 eV. Conclusions: The higther conductivity (3.848 × 10-4 S cm-1) was obtain at room temperature to higth concentration of CF3 COOLi, this values is similarity with results from other documents.Palabras clave: Electrolito sólido, Membrana de compuesto CF3 COOLi/PVDF, Polímero iónicos electro-activos. 

Structural Study of Plasticized Carboxy Methylcellulose Based Solid Biopolymer Electrolyte

2015 ◽  
Vol 1107 ◽  
pp. 242-246 ◽  
Author(s):  
M.N. Chai ◽  
M.I.N. Isa
Keyword(s):  
Solid Polymer Electrolyte ◽  
Room Temperature ◽  
Solid Polymer ◽  
Biopolymer Electrolytes ◽  
Infrared Studies ◽  
Solution Cast ◽  
Biopolymer Electrolyte ◽  
Relationship Of ◽  
Carboxyl Methylcellulose ◽  
Cast Technique

Carboxyl methylcellulose (CMC) doped with oleic acid (OA) and plasticized with glycerol was able to be produced into solid biopolymer electrolytes using the solution cast technique. The CMC-OA-glycerol solid polymer electrolyte obtained the highest conductivity of 1.64 x 10-4 S cm-1 at room temperature for sample Gly 40 wt. %. Within the temperature range investigated, the conductivity– temperature relationship of the biopolymer electrolytes is characteristically Arrhenius behaviour, suggesting that the conductivity is thermally assisted. Fourier Transform Infrared studies was carried out to determine the dissociation of free protons (H+) from the carboxyl group (–COOH) of glycerol.

Improving Conductivity Performance of Chitosan by Carboxymethylation Reaction: Synthesis and Characterization

2018 ◽  
Vol 936 ◽  
pp. 121-125
Author(s):  
Ni Wayan Pratiwi Triandani ◽  
I.M. Arcana
Keyword(s):  
Energy Storage ◽  
Fuel Cell ◽  
Ionic Conductivity ◽  
Room Temperature ◽  
Electrical Energy ◽  
Synthesis And Characterization ◽  
Reaction Synthesis ◽  
Ftir Analysis ◽  
Electrical Energy Storage ◽  
Eis Analysis

Chitosan has been applied widely in electrical energy storage purposes like battery and fuel cell, as in electrolyte. This research purposed on improving compatibility chitosan as material for electrical energy storage by chemical reaction. Carboxymethylation reaction performed on chitosan to add carboxymethyl groups in either hydroxyl or amine sites or both. The substitution result could effect by optimizing in the ratio of reactants and reaction condition. Carboxymethylation process on chitosan will confirm by FTIR analysis and degree of carboxymethyl substitution can be calculated from 1H NMR. Its ionic conductivity will calculate from EIS. The highest degree of substitution obtained at 64.64%. This reaction had the ratio of chitosan:monochloroacetic acid about 1:6 (m/m) and was reacted in reflux system at 65°C. EIS analysis showed improvement of carboxymethyl chitosan’s conductivity where pure chitosan had 2.7 x 10-6 Scm-1 and CMC-IV had 2.7 x 10-5 Scm-1 at room temperature.

Ionic Conduction Behavior of CMC Based Green Polymer Electrolytes

2013 ◽  
Vol 802 ◽  
pp. 194-198 ◽  
Author(s):  
M.I.N. Isa ◽  
A. S. Samsudin
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolytes ◽  
Ionic Conduction ◽  
Ethylene Carbonate ◽  
Ammonium Bromide ◽  
Casting Technique ◽  
Power Law Exponent ◽  
Conduction Behavior ◽  
Solution Casting Technique ◽  
Green Polymer

The present work deals with the findings on the ionic conduction behavior based on ethylene carbonate (EC) as plasticizer in carboxymethyl cellulose (CMC) – dodecyltrimethyl ammonium bromide (DTAB) for green polymer electrolytes (GPEs) that were prepared via solution casting technique. The highest ionic conductivity obtained for CMC-DTAB film was 7.72 x 10-4 S/cm and enhanced to 2.37 x 10-3 S/cm with addition 10wt. % of EC. The conductivity-temperature of GPEs system obeys the Arrhenius relation where the ionic conductivity increases with temperature. The temperature dependence of the power law exponent for plasticized CMC-DTAB based GPEs system follows the quantum mechanical tunneling (QMT) model for conduction mechanism.

Ionic Conductivity and Dielectric Properties of Plasticized Polyacrylonitrile Based Solid Polymer Electrolyte Films

2012 ◽  
Vol 626 ◽  
pp. 211-214
Author(s):  
W.G. Chong ◽  
Zurina Osman ◽  
Lisani Othman ◽  
Khairul Bahiyah Md. Isa
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Solid Polymer Electrolyte ◽  
Room Temperature ◽  
Ethylene Carbonate ◽  
Solid Polymer ◽  
Arrhenius Relation ◽  
Solution Cast ◽  
Host Polymer ◽  
Cast Technique

The conducting polymer electrolyte films composed of polyacrylonitrile (PAN) as the host polymer, LiCF3SO3 and NaCF3SO3 as inorganic salts and ethylene carbonate (EC) as plasticizer were prepared by the solution cast technique. The conductivities of the films were characterized by impedance spectroscopy. On addition of more than 14 wt% of salt, the NaCF3SO3-containing PAN films exhibited higher ionic conductivity than the LiCF3SO3-containing PAN films. The values of the dielectric constant, εr and dielectric loss, εi increase as frequency decreases at room temperature. The temperature dependence of the conductivity obeys Arrhenius relation in the temperature range of 303 K to 353 K.

CONDUCTIVITY STUDIES OF BIOPOLYMER ELECTROLYTE BASED ON POTATO STARCH/CHITOSAN BLEND DOPED WITH LICF3SO3

2015 ◽  
Vol 75 (7) ◽  
Author(s):  
Shanti Navaratnam ◽  
Azlin Sanusi ◽  
A. H. Ahmad ◽  
S. Ramesh ◽  
K. Ramesh ◽  
...  
Keyword(s):  
Potato Starch ◽  
Cost Effective ◽  
Casting Method ◽  
Biopolymer Electrolytes ◽  
Electrolyte Film ◽  
Solution Casting Method ◽  
Electrochemical Devices ◽  
Biopolymer Electrolyte ◽  
Blend Polymer Electrolyte ◽  
Blend Polymer

Biopolymer electrolytes are currently attracting a great deal of attention as substitute for synthetic polymers in electrochemical devices, as they are cost effective and eco-friendly. In this research, the biopolymer potato starch/chitosan blend polymer electrolyte film doped with LiCF3SO3 was prepared by solution casting method. Sample with 35wt. % LiCF3SO3 showed the highest ionic conductivity at room temperature. The dielectric studies reveal the non-Debye nature of the electrolyte. The Rice and Roth model was used quantitatively to explain the conductivity trends of the prepared electrolyte systems. The complexation of salt with the polymer host was studied using Fourier transform infrared (FTIR) spectroscopy.

Conduction Properties Study on Alginate Incorporated with Glycolic Acid Based Solid Biopolymer Electrolytes

2020 ◽  
Vol 981 ◽  
pp. 34-39
Author(s):  
Ahmad Faizrin Ahmad Fuzlin ◽  
Izan Izwan Misnon ◽  
Ahmad Salihin Samsudin
Keyword(s):  
Ionic Conductivity ◽  
Ambient Temperature ◽  
Glycolic Acid ◽  
Present System ◽  
Solution Casting ◽  
Casting Technique ◽  
Biopolymer Electrolytes ◽  
Dielectric Constant And Loss ◽  
Solution Casting Technique ◽  
Conduction Properties

This present work focuses on the conduction properties investigation on solid biopolymer electrolytes (SBEs) based alginate doped with various composition of glycolic acid (GA). The film was successfully prepared via solution casting technique and was characterized for conduction properties by using impedance spectroscopy. Based on ionic conductivity study, sample containing with 20 wt. % of GA possessed an optimum ionic conductivity of 5.32 × 10-5 Scm−1 at ambient temperature (303 K). The dielectric analysis revealed the highest ionic conductivity sample based alginate-GA SBEs has the highest dielectric constant and loss and increased significantly when temperature increases at ambient temperature. The dielectric properties shows that the entire alginate-GA SBEs are non-Debye behavior where there is no single relaxation occurred in the present system.

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