Deformation Microstructures of Two-Phase Intermetallic Alloy Composed of Ni3Al and Ni3V in Single Crystalline Form

2012 ◽  
Vol 706-709 ◽  
pp. 1077-1082 ◽  
Author(s):  
T. Moronaga ◽  
Yasuyuki Kaneno ◽  
Hiroshi Tsuda ◽  
Takayuki Takasugi

Two-phase single-crystal intermetallic alloys composed of Ni3Al (L12) and Ni3V (D022) with some orientations were compressed at various temperatures, and their deformation microstructures were observed by transmission electron microscopy (TEM). The deformation at room temperature was governed by the glide motion of dislocations in the primary Ni3Al precipitates and the activation of the microtwins in the Ni3V variant structures in the channel regions. The interfaces between the primary Ni3Al precipitates and the Ni3V variant structures are suggested to work as the barriers to the dislocation motion. While, at temperature above the peak temperature (873 K), the deformation microstructures of the two-phase intermetallic alloy exhibited the ribbon-like deformation microstructures penetrating the constituent phases i.e. through the interfaces between primary Ni3Al precipitates and the Ni3V variant structures in the channel regions. It was also suggested that the superior strength in the two-phase intermetallic alloys is due to the high flow strength of the Ni3V phases and to the interfacial hardening receiving when the dislocations activated in the primary Ni3Al precipitates propagate to the channel regions.

2011 ◽  
Vol 1295 ◽  
Author(s):  
T. Moronaga ◽  
Y. Kaneno ◽  
H. Tsuda ◽  
T. Takasugi

ABSTRACTDual two-phase intermetallic alloys based on the Ni3Al-Ni3V pseudo-binary alloy system have been reported to display high phase and microstructure stabilities and good mechanical properties at high temperature and are therefore considered to be used as a next generation type of high temperature structural materials. The microstructure of the dual two-phase intermetallic alloys is composed of primary Ni3Al and the channel (eutectoid) regions consisting of Ni3Al+Ni3V. In this study, the microstructure of the channel regions was investigated by a transmission electron microscope (TEM). The contrasts of the channel regions showed a complicated microstructure in bright-field images. However, the electron beam diffraction consisted of a single set of patterns and the spots did not accompany streaks, indicating that crystallographic coherency among the constituent phases or the domains is very high. It was also shown that the lattice misfit between the a-axis of Ni3Al and the c-axis of Ni3V is larger than that between the a-axis of Ni3Al and the a-axis of Ni3V. From the dark-field observation, it was found that the c-axis of Ni3V domains in the channel regions is oriented perpendicular to the interface between primary Ni3Al and Ni3V. Therefore, it is suggested that the crystallographic orientation of Ni3V in the channel regions is aligned in the manner of lowering an internal stress caused by the lattice misfit between primary Ni3Al precipitates and Ni3V domains.


2012 ◽  
Vol 1516 ◽  
pp. 127-132
Author(s):  
Takahiro Hashimoto ◽  
Yasuyuki Kaneno ◽  
Takayuki Takasugi

ABSTRACTThe objective of this study is to establish alloy designing which can reduce the amount of V for a Ni-base dual two-phase intermetallic alloy, without degenerating the dual two-phase microstructure. It was demonstrated that the favorable dual two-phase microstructure will be maintained as far as the valence electron concentration (e/a) of the alloys added by Cr is not so much different from that of the base alloy (i.e. the alloy without additive elements). Consequently, it was found that the dual two-phase microstructure was maintained even though the amounts of V were reduced by 7 at.%, 7 at.%, and 10at.% by substituting of Cr for V, Cr for both of Ni and V, and Cr for Ni, respectively. The hardness of the alloys with reduced V content was higher than that of the base alloy.


2002 ◽  
Vol 17 (10) ◽  
pp. 2611-2614 ◽  
Author(s):  
Feng Tang ◽  
Masuo Hagiwara

Room-temperature ductility of two Ti–Al–Nb intermetallic alloys with close chemical compositions was investigated by tensile testing. The two alloys' ductilities in the B2 single-phase state were significantly different, which indicated that the ductility of B2 phase state was sensitive to the chemical composition. The alloy with more ductile B2 phase exhibited higher ductility in O + B2 two-phase state.


1997 ◽  
Vol 12 (6) ◽  
pp. 1472-1480 ◽  
Author(s):  
Katherine C. Chen ◽  
Samuel M. Allen ◽  
James D. Livingston

Microstructures of two-phase Ti–Cr alloys (Ti-rich bcc + TiCr2 and Cr-rich bcc + TiCr2) are analyzed. A variety of TiCr2 precipitate morphologies is encountered with different nominal alloy compositions and annealing temperatures. Lattice constants and crystal structures are determined by x-ray diffraction (XRD) and transmission electron microscopy (TEM). Orientation relationships between the beta bcc solid solution and C15 TiCr2 Laves phase are understood in terms of geometrical packing, and are consistent with a Laves phase growth mechanism involving twinning.


1996 ◽  
Vol 436 ◽  
Author(s):  
R.-M. Keller ◽  
W. Sigle ◽  
S. P. Baker ◽  
O. Kraft ◽  
E. Arzt

AbstractIn-situ transmission electron microscopy (TEM) was performed to study grain growth and dislocation motion during temperature cycles of Cu films with and without a cap layer. In addition, the substrate curvature method was employed to determine the corresponding stresstemperature curves from room temperature up to 600°C. The results of the in-situ TEM investigations provide insight into the microstructural evolution which occurs during the stress measurements. Grain growth occurred continuously throughout the first heating cycle in both cases. The evolution of dislocation structure observed in TEM supports an explanation of the stress evolution in both capped and uncapped films in terms of dislocation effects.


2015 ◽  
Vol 1760 ◽  
Author(s):  
Yuki Hamada ◽  
Yasuyuki Kaneno ◽  
Hiroshi Numakura ◽  
Takayuki Takasugi

ABSTRACTThe effect of Si addition on microstructure and mechanical properties of dual two-phase intermetallic alloys was investigated. Si was added to the base alloy composition Ni75Al9V13Nb3 + 50 wt. ppm B by three substitution ways in which Si was substituted either for Ni, for Al and for V, respectively. The alloys added with 1 at.% Si showed a dual two-phase microstructure composed of Ni3Al (L12) and Ni3V (D022) phases, while the alloys added with over 2 at.% Si exhibited the same dual two-phase microstructure but contained third phases. The third phases were G phase (Ni16Si7Nb6) and A2 phase (the bcc solid solution consisting of Nb and V). Yield and tensile strength of the 1 at.% Si-added alloys were high in the alloy in which Si was substituted for Al but low in the alloys in which Si was substituted for Ni or for V, in comparison with those of the base alloy. Tensile elongation was lower than that of the base alloy irrespective of substitution ways. The density of the Si added alloys was close to or slightly lower than that of the base alloy. Oxidation resistance of the Si added alloy was increased. Si addition to the dual two-phase intermetallic alloys is beneficial for reducing the density and enhancing the oxidation resistance without a harmful reduction of strength properties.


1996 ◽  
Vol 34 (6) ◽  
pp. 985-991 ◽  
Author(s):  
R. Imayev ◽  
M. Shagiev ◽  
G. Salishchev ◽  
V. Imayev ◽  
V. Valitov

2017 ◽  
Vol 32 (24) ◽  
pp. 4531-4540 ◽  
Author(s):  
Takeshi Okuno ◽  
Yasuyuki Kaneno ◽  
Takuto Yamaguchi ◽  
Satoshi Semboshi ◽  
Hideki Hagino ◽  
...  

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