Influence of Composition of Gd-Doped Ceria Electrolyte on Performance of Solid Oxide Fuel Cell

2012 ◽  
Vol 724 ◽  
pp. 389-392 ◽  
Author(s):  
Yuta Ibusuki ◽  
Yoshihiro Hirata ◽  
Soichiro Sameshima ◽  
Naoki Matsunaga
Keyword(s):  
Power Density ◽  
Open Circuit ◽  
Solid Oxide ◽  
Maximum Power ◽  
Cell Performance ◽  
Excess Oxygen ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Maximum Power Density ◽  
Oxide Ion Conductivity

Cell performance was measured for four types of Ni (40 vol%)-Gd-doped ceria (GDC) anode-supported solid oxide fuel cells with GDC electrolyte (40-120 μm thickness) of Ce1-xGdxO2-x/2 compositions (x = 0.05, 0.1, 0.15 and 0.2) at 773-1073 K using a H2 fuel. (La0.8Sr0.2)(Co0.8Fe0.2)O3 cathode was printed on the GDC films. The open circuit voltage and maximum power density at 873-1073 K showed a maximum at x = 0.1. The maximum power density at x = 0.1 was 166 and 506 mW/cm2 at 873 and 1073 K, respectively. The excess oxygen vacancy at x = 0.1-0.2, which does not contribute to the oxide ion conductivity, reacts with a H2 fuel to form electrons (H2 + VO 2H+ + VO×, VO× VO + 2e-). This reaction reduces the cell performance.

Low-Temperature Operating Micro Solid Oxide Fuel Cells with Perovskite-type Proton Conductors

2011 ◽  
Vol 1330 ◽  
Author(s):  
Hiroo Yugami ◽  
Kensuke Kubota ◽  
Yu Inagaki ◽  
Fumitada Iguchi ◽  
Shuji Tanaka ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Low Temperature ◽  
Solid Oxide Fuel Cells ◽  
Power Density ◽  
Proton Conductors ◽  
Solid Oxide ◽  
Maximum Power ◽  
Barium Zirconate ◽  
Oxide Fuel ◽  
Maximum Power Density

ABSTRACTMicro-solid oxide fuel cells (Micro-SOFCs) with yttrium-doped barium zirconate (BZY) and strontium and cobalt-doped lanthanum scandate (LSScCo) electrolytes were fabricated for low-temperature operation at 300 °C. The micro-SOFC with a BZY electrolyte could operate at 300 °C with an open circuit voltage (OCV) of 1.08 V and a maximum power density of 2.8 mW/cm2. The micro-SOFC with a LSScCo electrolyte could operate at 370 °C; its OCV was about 0.8 V, and its maximum power density was 0.6 mW/cm2. Electrochemical impedance spectroscopy revealed that the electrolyte resistance in both the micro-SOFCs was lower than 0.1 Ωcm2, and almost all of the resistance was due to anode and cathode reactions. Although the obtained maximum power density was not sufficient for practical applications, improvement of electrodes will make these micro-SOFCs promising candidates for power sources of mobile electronic devices.

Hydrocarbon Fueled Operation of Metal-Supported Solid Oxide Fuel Cell

2010 ◽  
Author(s):  
Jihoon Jeong ◽  
Seung-Wook Baek ◽  
Joongmyeon Bae
Keyword(s):  
High Temperature ◽  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Power Density ◽  
Solid Oxide ◽  
Maximum Power ◽  
Oxide Fuel ◽  
Maximum Power Density ◽  
Operating Characteristics ◽  
Synthetic Gas

The metal-supported solid oxide fuel cell (SOFC) was studied. Hydrocarbon fueled operation was used to make SOFC system. Different operating characteristics for metal-supported SOFC are used than for conventional ones. Metal-supported SOFC was successfully fabricated by a high temperature sinter-joining method and the cathode was in-situ sintered. Synthetic gas, which is compounded as the diesel reformate gas composition and low hydrocarbons was completely removed by the diesel reformer. Metal-supported SOFC with synthetic gas was operated and evaluated and its characteristics analyzed. The performance of hydrogen operation shows 0.4 W·cm−2 of maximum power density. The maximum power density of the synthetic gas operation decreased to 0.22 W·cm−2 and to 0.11 W·cm−2 after 10 hours operation, respectively. Degradation occurred because a large steam quantity made an oxidation atmosphere at high temperature, causing the metallic part damage.

Boosting solid oxide fuel cell performance via electrolyte thickness reduction and cathode infiltration

2020 ◽  
Vol 8 (23) ◽  
pp. 11626-11631
Author(s):  
Beom-Kyeong Park ◽  
Scott A. Barnett
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Power Density ◽  
Solid Oxide ◽  
Cell Performance ◽  
Thickness Reduction ◽  
Oxide Fuel ◽  
Maximum Power Density ◽  
Fuel Cell Performance ◽  
Polarization Resistances

The Ni–YSZ-supported SOFC with LSCF–GDC cathode yields the maximum power density of 2.38 W cm−2 at 800 °C via electrolyte thickness reduction and cathode infiltration with PrOx, with a resulting decrease in both the ohmic and polarization resistances.

Preparation of Ce0.8Sm0.2O1.9 Thin Films by Electrophoretic Deposition and their Fuel Cell Performance

2013 ◽  
Vol 566 ◽  
pp. 137-140 ◽  
Author(s):  
Hiroki Ichiboshi ◽  
Kenichi Myoujin ◽  
Takayuki Kodera ◽  
Takashi Ogihara
Keyword(s):  
Thin Films ◽  
Fuel Cell ◽  
Spray Pyrolysis ◽  
Power Density ◽  
Electrophoretic Deposition ◽  
Open Circuit Voltage ◽  
Open Circuit ◽  
Doped Ceria ◽  
Maximum Power Density ◽  
Fuel Cell Performance

Ce0.8Sm0.2O1.9 (Samaria-doped ceria: SDC) precursors were synthesized by carbon-assisted spray pyrolysis. SDC thin films were prepared by electrophoretic deposition using the SDC precursor particles. The as-prepared SDC thin films were sintered at 1600 °C for 10 h. Uniform films with a thickness of approximately 20 μm were obtained. A fuel cell using the prepared thin films showed a maximum power density of 60.6 mW/cm2 and an open circuit voltage (OCV) of 0.63 V at 700 °C.

Power Generation Properties of a Micro Tubular SOFC Bundle Under Pressurized Conditions

2008 ◽  
Author(s):  
S. Hashimoto ◽  
Y. Liu ◽  
K. Asano ◽  
M. Mori ◽  
Y. Funahashi ◽  
...  
Keyword(s):  
Power Generation ◽  
Power Density ◽  
Atmospheric Pressure ◽  
Polarization Resistance ◽  
Open Circuit Voltage ◽  
Open Circuit ◽  
Solid Oxide ◽  
Operating Pressure ◽  
Oxide Fuel ◽  
Generation Test

A micro tubular solid oxide fuel cell (SOFC) bundle was developed based on new concept. The anode-supported micro tubular SOFCs with the cell configuration, La0.6Sr0.4Co0.2Fe0.8 O3−δ (LSCF) – Ce0.9Gd0.1O2−δ (CGO) cathode / CGO electrolyte / Ni – CGO anode were fabricated and were bundled by a porous LSCF current collecting cube 1 cm on a side. The power generation test of the fabricated SOFC bundle was carried out under pressurized conditions. Using wet 30%H2 / N2 mixture gas and air, the cubic power density of the bundle at 500°C was 0.47 Wcm−3 at 0.4Acm−2, atmospheric pressure (0.1MPa). With increasing operating pressure, the performance has been improved, and the cubic power density finally reached to 0.66 Wcm−3 at 0.6MPa. Pressurization effect for the power improvement was brought about by the open circuit voltage enhancement and reduction of the polarization resistance.

Microstructure optimization of nickel/gadolinium-doped ceria anodes as key to significantly increasing power density of metal-supported solid oxide fuel cells

2019 ◽  
Vol 44 (59) ◽  
pp. 31475-31487 ◽  
Author(s):  
Cornelia Bischof ◽  
Andreas Nenning ◽  
Andreas Malleier ◽  
Lukas Martetschläger ◽  
Andre Gladbach ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Power Density ◽  
Solid Oxide ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Gadolinium Doped Ceria

Multicriteria Assessment of the Performance of Solid Oxide Fuel Cells by Cell Design and Materials Development: Design and Modeling Approach

2013 ◽  
Vol 10 (1) ◽  
Author(s):  
Junichiro Otomo ◽  
Keiko Waki ◽  
Koichi Yamada
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Power Density ◽  
State Of The Art ◽  
Solid Oxide ◽  
Cell Performance ◽  
Cell Design ◽  
Oxide Fuel ◽  
Volume Weight ◽  
Material Cost

The performance of current solid oxide fuel cells (SOFCs) was evaluated in terms of the cell designs and the physicochemical properties of the component materials such as the electrode and electrolyte in order to demonstrate the potentials of state-of-the-art SOFC technology for the widespread use of SOFCs. A flat tubular type SOFC stack for residential use was analyzed as a standard case of a production version in terms of stack volume, weight, and material cost. The power density and power generation efficiency were also evaluated by model estimation. A microtubular type SOFC was evaluated as an example of an advanced cell design. The assessment of the cell design can pinpoint performance advantages of the microtubular type in stack volume, weight, material cost, volumetric power density, and efficiency. In addition, we attempted to demonstrate an analysis for the concurrent comparison of the impact of cell designs and material properties on cell performance by using volumetric power density as a common assessment criterion. Through the assessment with the state-of-the-art SOFC technology, it is possible to make a quantitative comparison of the significances of cell design and material property. The present assessment suggests that the development of cell design is a consistent approach to improving cell and stack performance. In this way, the proposed assessment can provide hints to a reliable research strategy for improving cell performance and realizing the widespread use of SOFCs.

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