The Effect of NaOH Concentration and Curing Condition to the Strength and Shrinkage Performance of Recycled Geopolymer Concrete

2014 ◽  
Vol 803 ◽  
pp. 194-200 ◽  
Author(s):  
Ahmad Ruslan Mohd Ridzuan ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Mohd Fadzil Arshad ◽  
Muhammad Faheem Mohd Tahir ◽  
A.A. Khairulniza

Concrete is widely used as a material construction. Globally, the consumption of concrete was estimated to be more than 8 billion tons per year. Nowadays, many problems arise related to concrete manufacturing occur especially on environmental issues. A key concern for environmentalists has always been climate change. One of the ways to mitigate the impact activities on the climate is to reduce carbon footprint. Portland cement are commonly been used in concrete is responsible for about 5% of all CO2emission. It is reported by Davidovit that the production of one ton of Portland cement emits approximately one ton of CO2into the atmosphere. There are several ways to reduce environmental pollution that cause by production and utilization of Portland cement, one of it is Geopolymer concrete. Subsequently Geopolymer concrete incorporating with recycle concrete aggregate (RCA) is one of the alternative to further reduce carbon footprint and as well as can reduce waste. Geopolymer concrete is a concrete that use no cement and produced by the combination of alkaline activator and supplementary cementitious material (SCM) such as fly ash, boiler ash, waste paper sludge ash (WPSA), ground granulated blast-furnace slag (GGBS), and so on in order to reduce carbon emission. In this study the Waste Paper Sludge Ash (WPSA) were used as a SCM and the combination of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as a binder. Two (2) series of geopolymer concrete specimens comprising two (2) different molar of sodium hydroxide (NaOH) which are 8M and 14M were adopted. The effect variable alkaline molarity on the compressive strength and shrinkage of the geopolymer concrete specimens is tested at the age of 3, 7, 14 and 28 days. The mixture of geopolymer concete with 8M of sodium hydroxide (NaOH) concentration then was categorized into three (3) groups. Each group were been cured at different curing condition which are in ambient condition, oven, and external condition. The size of specimens prepared were 100mm x 100mm x100mm. The result shows that the molarities of sodium hydroxide (NaOH) influenced the strength of Waste Paper Sludge Ash (WPSA) based geopolymer concrete produced incorporating with increasing of recycle concrete aggregate (RCA). The result also show that the geopolymer concrete undergoes very low shrinkage. Curing condition will also effect the strength of geopolymer concrete produced.

2012 ◽  
Vol 626 ◽  
pp. 776-780
Author(s):  
Ahmad Ruslan Mohd Ridzuan ◽  
A.A. Khairulniza ◽  
M.A. Fadhil

ncreasing environmental concerns of the cement industry brings about the requirement to the development of new binders. Polymeric concrete containing no cement provides great potential in reducing the global warming problems caused by CO2emissions in Portland cement production. On the other hand, large amount of waste paper sludge ash produced annually in Malaysia has caused a disposal problem as they require a proper dumping process whereby it is very costly. The study focuses on the utilization of this high calcium Waste paper sludge ash (WPSA) in polymeric concrete containing recycled concrete aggregate (RCA). WPSA is chemically activated by a high-alkaline solution to form paste that binds aggregate in the mixture. Sodium hydroxide and sodium silicate solution are used as alkali activators of silica (Si) and aluminium (Al) in main binders. The polymeric concrete samples were exposed to external ambient condition and tested for compressive strength and shrinkage at 3, 7, 28, 56, and 90 days to identify the strength and deformation of the polymeric concrete. X-Ray Fluorescence (XRF) analysis performed to ascertain the chemical properties of the produced WPSA. The result of polymeric concrete yielded very minimum shrinkage. The measurement compressive strength is up to 7MPa at 90 days. Hence, this new green material will bring benefits to the environment and is of economical value.


2003 ◽  
Vol 9 (3) ◽  
pp. 198-202 ◽  
Author(s):  
Albinas Gailius ◽  
Živilė Laurikietytė

The aim of the research was to develop an economic binder from waste products that could have applications in the production of concrete. Portland cement (PC) production is a very high-energy intensive process that also involves significant environmental damage with respect to CO2 production and raw material acquisition. This paper investigates workability and strength of concrete made with different proportions of waste paper sludge ash (WSA) and ground granulated blast-furnace slag (GGBS) as binder, at two w/b rations: 0,5 and 0,4. Specimens were tested unconfined compressive strength after 1, 7, 28 and 90 days of curing. The results obtained show that 28 days strength varies between 15–21 MPa, and the general trend of strength development with increasing WSA content has the shape of an inverse parabola, where the highest 28 days and 90 day strengths are achieve by concrete with a mix composition of 50: 50 at both w/b ratios. Workability was evaluated by a slump test. Superplasticiser Daracem SP 1 was used for the concrete with WSA—GGBS binder in order to obtain workability, comparable to the observed for concrete with Portland cement binder at equivalent w/b ratio.


2012 ◽  
Vol 626 ◽  
pp. 376-380 ◽  
Author(s):  
Siti Shahidah Sharipudin ◽  
Ahmad Ruslan Mohd Ridzuan

In the effort to produce sustainable concrete, considerable attempt has been placed on replacing the main ingredients in concrete mixtures with more sustainable materials with the objective to reduce the carbon footprint. One of the replacement materials is waste paper sludge ash (WPSA), a local industrial by-product generated abundantly by newsprint mills which possesses considerable cementitious properties. Parallel to this, the high amount of construction waste, particularly concrete waste has become a difficult environmental issue to cope with in todays world. For this reason, recycling of concrete waste as a new alternative aggregate is being effectively utilized in concrete production. Thus, this paper reports on a study conducted to evaluate the compressive strength characteristics of the potential of using WPSA as a binder and fine recycled concrete aggregate (FRCA) as a virgin sand replacement in producing foamed concrete. The findings of this study exhibited that the inclusion of WPSA and FRCA for replacement ratios up to 20% and 15% respectively has significantly influenced the strength properties of foamed concrete.


Author(s):  
Shahid Bashir

Abstract: Cement production is one of the sources that emit carbon dioxide, in addition to deforestation and combustion of fossil fuels also leads to ill effects on environment. The global cement industry accounts for 7% of earth’s greenhouse gas emission. To enhance the environmental effects associated with cement manufacturing and to constantly deplore natural resources, we need to develop other binders to make the concrete industry sustainable. This work offers the option to use waste paper sludge ash as a partial replacement of cement for new concrete. In this study cement in partially replaced as 5%, 10%, 15% and 20% by waste paper sludge ash in concrete for M25 mix and tested for compressive strength, tensile strength, water absorption and dry density up to the age of 28days and compared it with conventional concrete, based on the results obtained, it is found that waste paper ash may be used as a cement replacement up to 5% by weight and the particle size is less the 90µm to prevent reduction in workability. Keywords: slump test, Compressive strength, split tensile strength, water absorption test, Waste Paper Sludge Ash Concrete, Workability.


2014 ◽  
Vol 803 ◽  
pp. 88-92 ◽  
Author(s):  
A.R.M. Ridzuan ◽  
A.A. Khairulniza ◽  
M.A. Fadzil ◽  
J. Nurliza

Waste paper sludge ash (WPSA) is a byproduct that has potential to replace Ordinary Portland Cement (OPC) as a building material. The purpose of this study is to investigate the effect of NaOH concentration on the strength of Waste Paper Sludge Ash (WPSA)-based geopolymer mortar. Initially, the WPSA samples were been analyzed using X-ray Fluorescence (XRF) to determine the chemical composition. From the XRF analysis, the by-product WPSA containing higher amount of calcium, silica and alumina. Alkaline solution are from soluble sodium-based used in geopolymerization are combination of Sodium Hydroxide (NaOH) and Sodium Silicate (Na2SiO3). The mortars samples were cast with various concentration of NaOH and ratio of Na2SiO3 /NaOH which is 2.5. The specimens were carried out on size 50x50x50 mm cube and fresh mortar were been cured at 70 ̊c oven temperature and ambient temperature. The compressive strength tests were conducted after aging the specimen at 3, 7, 14, and 28 days. The results revealed that as the concentration of NaOH increased, the compressive strength of geopolymer mortar increases. However, the optimum NaOH concentration of geopolymer mortar is at 12M. More than 12M concentrations of NaOH were produced high porosity and decreasing the strength. Moreover, curing of fresh geopolymer mortar is performed mostly at an oven temperature compared to ambient temperature due to heat being a reaction accelerator. This paper also present on the morphology, and Energy dispersive x-Ray (EDX) composition analysis of WPSA based geopolymer mortar.


InCIEC 2014 ◽  
2015 ◽  
pp. 439-446 ◽  
Author(s):  
Norazlan Khalid ◽  
Mazidah Mukri ◽  
Faizah Kamarudin ◽  
Abdul Halim Abdul Ghani ◽  
Mohd Fadzil Arshad ◽  
...  

2015 ◽  
Vol 70 ◽  
pp. 9-20 ◽  
Author(s):  
Hong S. Wong ◽  
Robert Barakat ◽  
Abdulla Alhilali ◽  
Mohamed Saleh ◽  
Christopher R. Cheeseman

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