Electrochemical Characteristics of Platinum Nanocluster Catalysts Using Oxyfluorinated Carbon Nanotubes Supports

2007 ◽  
Vol 119 ◽  
pp. 155-158 ◽  
Author(s):  
Seok Kim ◽  
Mi Hwa Cho ◽  
Soo Han Kwon ◽  
Soo Jin Park

Multi-walled carbon nanotubes (MWNTs) were oxyfluorinated at several different temperatures. The results indicated that graphitic carbon was the major carbon functional component on the MWNT surfaces and other functional groups, such as C–O, C=O, HO–C=O, C–Fx, were also present after oxyfluorination. The changes of surface properties of oxyfluorinated MWNTs were investigated using FT-IR, EDS and XRD. From the surface analysis, it was found that surface fluorine and oxygen contents increased with increasing oxyfluorination temperature and showed a maximum value at 100 °C. Consequently, it was found that optimal treatment temperature was 100 °C for the best electro activity of Pt/MWNT-100 catalyst and the oxyfluorinated Pt/MWNTs possessed the better electrochemical properties than the pristine Pt/MWNTs.

2014 ◽  
Vol 70 (6) ◽  
pp. 964-971
Author(s):  
Xu Chen ◽  
Zhen-hu Xiong

Magnetic multi-wall carbon nanotubes (M-MWCNTs) were used as an adsorbent for removal of furaltadone from aqueous solutions, and the adsorption behaviors were investigated by varying pH, sorbent amount, sorption time and temperature. The results showed that the adsorption efficiency of furaltadone reached 97% when the dosage of M-MWCNT was 0.45 g · L−1, the pH was 7 and the adsorption time was 150 min. The kinetic data showed that the pseudo-second-order model can fit the adsorption kinetics. The sorption data could be well explained by the Langmuir model under different temperatures. The adsorption process was influenced by both intraparticle diffusion and external mass transfer. The experimental data analysis indicated that the electrostatic attraction and π–π stacking interactions between M-MWCNT and furaltadone might be the adsorption mechanism. Thermodynamic analysis reflected that adsorption of furaltadone on the M-MWCNT was spontaneous and exothermic. Our study showed that M-MWCNTs can be used as a potential adsorbent for removal of furaltadone from water and wastewater.


2021 ◽  
Author(s):  
Marzia Soligo ◽  
Fausto Maria Felsani ◽  
Tatiana Da Ros ◽  
Susanna Bosi ◽  
Elena Pellizzoni ◽  
...  

Carbon nanotubes (CNTs) are currently under active investigation for their use in several biomedical applications, especially in neurological diseases and nervous system injury due to their electrochemical properties.


2016 ◽  
Vol 52 (5) ◽  
pp. 441-448 ◽  
Author(s):  
E. O. Fedorovskaya ◽  
L. G. Bulusheva ◽  
A. G. Kurenya ◽  
I. P. Asanov ◽  
A. V. Okotrub

2012 ◽  
Vol 05 ◽  
pp. 704-711
Author(s):  
SIAVASH KHABAZIAN ◽  
SOHRAB SANJABI

Multi-walled carbon nanotubes films formed randomly aligned laterally by electrophoresis. Multi-walled carbon nanotubes with lengths of about 10 μ was shortened and functionalized by a mixture of sulfuric and nitric acid. The functional groups on carbon nanotubes were elaborated by FT-IR. Chemically shortened MWCNTs disperse in organic and aqueous solvent and deposited on electrode vertically-aligned by applying a constant DC electric field. The alignment of MWCNTs was observed by scanning electron microscopy. It also the effect of various substrates on alignment of multi-walled carbon nanotubes was investigated.


RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 79563-79577 ◽  
Author(s):  
S. A. Habibiannejad ◽  
A. Aroujalian ◽  
A. Raisi

In this study different functional groups on the surface of carbon nanotube enhanced the performance of Pebax 1657/MWNTs.


Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3567 ◽  
Author(s):  
Bogumiła Kumanek ◽  
Grzegorz Stando ◽  
Paweł S. Wróbel ◽  
Dawid Janas

Carbon nanotubes have been intensively researched for many years because of a wide array of promising properties that they have. In this paper, we present the impact of synthesis parameters on thermoelectric properties of nanocarbon material. We conducted a number of syntheses of multi-walled carbon nanotubes (MWCNTs) at different temperatures (800 and 900 °C) using various amounts of catalyst (2%, 5.5%, and 9.6%) to facilitate the process. We also tested the influence of injection rate of precursor and the necessity of material purification on thermoelectric properties of MWCNTs. The electrical conductivity, thermal conductivity, and Seebeck coefficient were measurement for all samples. Based on these parameters, the values of Power Factor and Figure of Merit were calculated. The results show that the most important parameter in the context of thermoelectric properties is purity of employed MWCNTs. To obtain appropriate material for this purpose optimum synthesis temperature and appropriate content of the catalyst must be selected. The study also reveals that post-synthetic purification of nanocarbon is essential to produce an attractive material for thermoelectrics.


2013 ◽  
Vol 667 ◽  
pp. 534-537
Author(s):  
M.Z. Nuraini ◽  
S. Aishah ◽  
S.F. Nik ◽  
Mohamad Rusop

Fermented tapioca which is a new starting material was used as a carbon precursor. Carbon nanotubes (CNTs) were deposited on silicon wafer (Si) by Thermal Chemical Vapor Deposition (TCVD). The gas flow of Argon (Ar) was constant at 70 bubbles per minute and 20 minutes of deposition time. Before the deposition process, silicon was coated with Nickel using spin coater. Various parameters such as amount of inoculums have been studied. Chemical functional groups of carbon nanotubes were characterized using FT-IR Spectroscopy. The FT-IR result shows peaks attributed to multi–walled carbon nanotubes (MWCNT) vibration modes.


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