THE BRAY, MEHLICH AND KELOWNA SOIL P TESTS AS AFFECTED BY SOIL CARBONATES

1987 ◽  
Vol 67 (2) ◽  
pp. 399-404 ◽  
Author(s):  
A. R. YEE ◽  
K. BROERSMA

A study was conducted with five soil P tests (Bray P1 (1:10), Bray P1 (1:50), Mehlich II, Kelowna I and Kelowna II) to determine the effect of soil carbonates on postextraction pH and on the correlation between soil and plant P concentration. Alfalfa (Medicago sativa L.) was grown on five calcareous and six noncalcareous soils fertilized at 0 and 90 μg P mL−1 in a growth room experiment. The ability of the extradants to maintain a low pH with calcareous soils was poorest for the Bray P1 (1:10) followed by the Mehlich II, Kelowna I, Kelowna II and Bray P1 (1:50). The Bray P1 (1:10) did not give a statistically significant correlation coefficient between soil and plant P concentration with the calcareous soils, while the other methods did. Key words: Soil testing, calcareous soils, Bray P1, Mehlich II, Kelowna I, Kelowna II

2011 ◽  
Vol 60 (2) ◽  
pp. 343-358
Author(s):  
Péter Csathó ◽  
Marianna Magyar ◽  
Erzsébet Osztoics ◽  
Katalin Debreczeni ◽  
Katalin Sárdi

A szabadföldi trágyázási (tartam)kísérletek eredményeit talaj-, illetve diagnosztikai célú növényvizsgálatok segítségével tudjuk kiterjeszteni, általánosítani – figyelembe véve természetesen a kiterjesztés korlátait is. Célszerűnek láttuk ezen túl a talaj könnyen oldható tápelem-, közöttük P-tartalmát is meghatározni a hazánkban hivatalosan elfogadott AL- (ammónium-laktátos) módszer mellett az Európai Unióban és Észak-Amerikában alkalmazott P-tesztekkel is (CaCl2-, H2O-, Olsen-, Bray1-, LE-, Mehlich3- stb.) a hazai OMTK kísérletek talajmintáiban. A kísérleti helyek talajtulajdonságaiban megnyilvánuló jelentős különbségek lehetőséget adnak rá, hogy a talaj P-teszteket – és a növényi P-felvételt – jellegzetes hazai talajokon, sokszor szélsőséges talajparaméterek mellett vizsgáljuk. Az egyes P-szintek között a 28 év átlagában mintegy évi 50 kg P2O5·ha-1volt a különbség. A P0-szinten mért P-tartalmak jól jelezték az egyes kísérleti helyek talajának eltérő P-ellátottságát, illetve, közvetve, fizikai féleségében, pH és mészállapotában meglévő különbségeket. A P2-szinten – a hazai talajokra, P-igényes növényekre a hazai szabadföldi P-trágyázási tartamkísérleti adatbázisban talált összefüggésekre alapozott – új AL-P határértékek szerint csupán a bicsérdi csernozjom barna erdőtalajon nem javult a P-ellátottság legalább a „jó” szintig. Vizsgálataink megerősítették az AL-módszer függőségét a CaCO3-tartalomtól: a Mehlich3 módszerrel való összefüggésben a karbonátmentes és a karbonátos talajok csoportja erőteljesen elkülönült egymástól. Az AL-P korrekció elvégzése, azaz az AL-P értékeknek egy standard talajtulajdonság-sorra való konvertálása (KA: 36; pH(KCl): 6,8; CaCO3: 0,1%) látványosan csökkentette az AL-módszernek a talaj CaCO3-tartalmától való függőségét. Az AL-P és Olsen-P, valamint a korrigált AL-P és Olsen-P tartalmak összehasonlításában ugynakkor ugyanez az összefüggés nem volt állapítható, ami arra utal, hogy az Olsen módszer bizonyos fokig szintén pH- és mészállapot függő. Kísérleti eredményeink megerősítették a Sarkadi-féle AL-P korrekciós modell helytálló voltát. Fenti megállapításunkat ugyanakkor a növényi P-tartalmakkal való összefüggéseknek is igazolniuk kell. Szükséges tehát a talajvizsgálati eredményeknek a diagnosztikai célú növényvizsgálatokkal, valamint a terméseredményekkel való összevetése. A tartamkísérletek talajai lehetőséget nyújtanak a környezetvédelmi célú P-vizsgálatok értékelésére, a talaj P-feltöltöttsége környezeti kockázatának becslésére. Ezekkel a kérdésekkel a cikksorozat további részeiben kívánunk foglalkozni.


Soil Research ◽  
2007 ◽  
Vol 45 (4) ◽  
pp. 255 ◽  
Author(s):  
Ebrahim Adhami ◽  
Hamid Reza Memarian ◽  
Farzad Rassaei ◽  
Ehsan Mahdavi ◽  
Manouchehr Maftoun ◽  
...  

Inorganic phosphorus (P) sequential fractionation schemes are applicable techniques to interpret soil P status. The present study was initiated to determine the origin of various P fractions in highly calcareous soils. Inorganic P forms were determined by a sequential fractionation procedure extracting with NaOH (NaOH-P), Na citrate-bicarbonate (CB-P), Na citrate 2 times (C1-P and C2-P), Na citrate-ascorbate (CAs-P), Na citrate-bicarbonate-dithionite (CBD-P), Na acetate (NaAc-P), and HCl (HCl-P). Results showed that NaOH-P was negatively correlated with active iron oxides. CB-P was positively correlated with silt content and negatively related to citrate-bicarbonate-dithionite extractable Fe (Fed). This result illustrates the weathering effect on Ca-P, with Ca-P content declining as a consequence of weathering. A negative correlation was observed between C1-P and citrate ascorbate extractable Fe (FeCAs). Second citrate extractable P (C2-P) was negatively related to calcium carbonate equivalent and positively related to hydroxylamine-hydrochloride and neutral ammonium acetate-hydroquinone extractable Mn (Mnh and Mnq). Fine silt (Fsilt) was the most influential factor affecting CAs-P. It seemed citrate-dithionite-bicarbonate extractable Al (Ald), Mnh, and Mnq have been sinks for CBD-P, while free iron oxide compounds (Feo, Fec, and FeCAs) were a major contributing factor for the formation of NaAc-P. Stable P compounds (HCl-P) of highly calcareous soils originated from coarse silt (Csilt) and hydroxylamine-hydrochloride extractable Mn (Mnh).


2008 ◽  
Vol 72 (4) ◽  
pp. 985-991 ◽  
Author(s):  
Angela M. Ebeling ◽  
Larry G. Bundy ◽  
Aaron W. Kittell ◽  
Daniel D. Ebeling
Keyword(s):  

1989 ◽  
Vol 69 (2) ◽  
pp. 191-197
Author(s):  
W. VAN LIEROP

The objective of this study was to determine the effect of adding either 0.001M EDTA or 0.005M DTPA on the amount of P removed from acid and calcareous soils by the Kelowna and 0.25M HO Ac extractants. These complexing agents were studied for possible simultaneous extraction and determination of available Zn. To achieve that end, P-concentrations removed by these solutions from a group of acid, calcareous, and combined soils were compared against reference values obtained with 0.5M NaHCO3 (Olsen et al.) and the Kelowna extractant (0.25M HOAc + 0.015M NH4F) by means of graphing, correlation and regression techniques. Of the 80 soils studied, 40 were acid with pH (H2O) values ranging from 4.2 to 6.9 and the remainder having higher values up to 9.3. Results indicated that additions of either 0.001M EDTA or 0.005M DTPA to the Kelowna solution increased average extracted P concentrations by about 20 and 60%, respectively. Values removed by either of the new KEDTA and KDTPA solutions were closely related to those extracted with 0.5M NaHCO3 and Kelowna solutions on acid and calcareous soils (r values ≥ 0.96**). As EDTA and DTPA increased extracted soil P, these were added at 0.001 and 0.005M as NH4 preparations to 0.25M HOAc (AADTPA & AAEDTA; without fluoride), respectively, for determining whether these complexing agents could supplant F for P extraction. These solutions removed proportionally related amounts (r ≈ 0.94**) of P from calcareous, compared to the Kelowna and 0.5M NaHCO3 solutions, but relationships were less precise for acid soils (r ≈ 0.76**). These results suggest that the AADTPA or AAEDTA solution should be evaluated further before adoption for routine P determination in multiple element extractions. Key words: Mehlich in, acid soils, calcareous soils


2015 ◽  
Vol 19 (1) ◽  
pp. 453-464 ◽  
Author(s):  
J. M. Campbell ◽  
P. Jordan ◽  
J. Arnscheidt

Abstract. This study reports the use of high-resolution water quality monitoring to assess the influence of changes in land use management on total phosphorus (TP) transfers in two 5 km2 agricultural sub-catchments. Specifically, the work investigates the issue of agricultural soil P management and subsequent diffuse transfers at high river flows over a 5-year timescale. The work also investigates the phenomenon of low flow P pollution from septic tank systems (STSs) and mitigation efforts – a key concern for catchment management. Results showed an inconsistent response to soil P management over 5 years with one catchment showing a convergence to optimum P concentrations and the other an overall increase. Both catchments indicated an overall increase in P concentration in defined high flow ranges. Low flow P concentration showed little change or higher P concentrations in defined low flow ranges despite replacement of defective systems and this is possibly due to a number of confounding reasons including increased housing densities due to new-builds. The work indicates fractured responses to catchment management advice and mitigation and that the short to medium term may be an insufficient time to expect the full implementation of policies (here defined as convergence to optimum soil P concentration and mitigation of STSs) and also to gauge their effectiveness.


Soil Research ◽  
2007 ◽  
Vol 45 (5) ◽  
pp. 397 ◽  
Author(s):  
David Nash ◽  
Murray Hannah ◽  
Kirsten Barlow ◽  
Fiona Robertson ◽  
Nicole Mathers ◽  
...  

Phosphorus (P) exports from agricultural land are a problem world-wide and soil tests are often used to identify high risk areas. A recent study investigated changes in soil (0–20 mm), soil water and overland flow in 4 recently laser-graded (<1 year) and 4 established (laser-graded >10 years) irrigated pastures in south-eastern Australia before and after 3 years of irrigated dairy production. We use the results from that study to briefly examine the relationships between a series of ‘agronomic’ (Olsen P, Colwell P), environmental (water-extractable P, calcium chloride extractable P, P sorption saturation, and P sorption), and other (total P, organic P) soil P tests. Of the 2 ‘agronomic’ soil P tests, Colwell P explained 91% of the variation in Olsen P, and Colwell P was better correlated with the other soil tests. With the exception of P sorption, all soil P tests explained 57% or more of the total variation in Colwell P, while they explained 61% or less of Olsen P possibly due to the importance of organic P in this soil. Variations in total P were best explained by the organic P (85%), Calcium chloride extractable P (83%), water-extractable P (78%), and P sorption saturation (76%). None of the tests adequately predicted the variation in P sorption at 5 mg P/L equilibrating solution concentration. The results of this limited study highlight the variability between soil P tests that may be used to estimate P loss potential. Moreover, these results suggest that empirical relationships between specific soil P tests and P export potential will have limited resolution where different soil tests are used, as the errors in the relationship between soil test P and P loss potential are compounded by between test variation. We conclude that broader study is needed to determine the relationships between soil P tests for Australian soils, and based on that study a standard protocol for assessing the potential for P loss should be developed.


1999 ◽  
Vol 79 (4) ◽  
pp. 615-625 ◽  
Author(s):  
Suzanne Beauchemin ◽  
R. R. Simard

Many agricultural fields contain excessive labile soil P in regard to crop needs. Its environmental fate must be assessed. The concept of P saturation degree is meaningful as it describes the portion of the soil binding sites already covered with P, and indicates the potential desorbability of soil P. The first objective of this study was to review different indices that have been proposed to estimate the degree of soil P saturation and the relationships between soil P saturation degree and P solubility. The second objective is to discuss their suitability as environmental indicators for P management in the province of Québec, Canada. In the Netherlands, the P saturation index is defined as the ratio of P to Al + Fe contents extracted by ammonium oxalate [Pox/( Alox + Feox ) or ( Pox/0.5( Alox + Feox )]. This approach has been mainly used with non-calcareous soils. In Québec, the ratio of Mehlich-III extractable P to Al (M3P/AlM3) is proposed as an alternative, which relies on routine laboratory test. However, the suitability of the M3P/AlM3 ratio has yet to be determined for some specific soil groups (e.g. gleyed soils, soils with Alox content >6 g kg−1) and for subsoil horizons. Regardless of the chosen index, it is suggested that the best way to manage the risk of water contamination by P in Québec (namely, defining critical levels of soil P saturation) may be to form homogeneous soil groups to account for their distinctive behaviour and characteristics. Key words: Phosphorus, saturation, management


Soil Research ◽  
2010 ◽  
Vol 48 (8) ◽  
pp. 682 ◽  
Author(s):  
M. D. A. Bolland ◽  
W. K. Russell

Soil testing was conducted during 1999–2009 to determine lime and fertiliser phosphorus (P), potassium (K), and sulfur (S) requirements of intensively grazed, rain-fed, ryegrass dairy pastures in 48 paddocks on sand to sandy loam soils in the Mediterranean-type climate of south-western Australia. The study demonstrated that tissue testing was required in conjunction with soil testing to confirm decisions based on soil testing, and to assess management decisions for elements not covered by soil testing. Soil testing for pH was reliable for indicating paddocks requiring lime to ameliorate soil acidity, and to monitor progress of liming. Soil P testing proved reliable for indicating when P fertiliser applications were required, with no P being required when soil-test P was above the critical value for that soil, and when no P was applied, tissue testing indicated that P remained adequate for ryegrass production. Soil testing could not be used to determine paddocks requiring fertiliser K and S, because both elements can leach below the root-zone, with rainfall determining the extent of leaching and magnitude of the decrease in pasture production resulting from deficiency, which cannot be predicted. The solution is to apply fertiliser K and S each year, and use tissue testing to improve fertiliser K and S management. Research has shown that, for dairy and other grazing industries in the region, laboratories need measure and report every year soil pH and soil-test P only, together with measuring every 3–5 years the P-buffering index (estimating P sorption of soil), organic carbon content, and electrical conductivity.


Soil Research ◽  
2007 ◽  
Vol 45 (1) ◽  
pp. 55 ◽  
Author(s):  
P. W. Moody

Soil phosphorus (P) buffer capacity is the change in the quantity of sorbed P required per unit change in solution P concentration. Because P availability to crops is mainly determined by solution P concentration, as P buffer capacity increases, so does the quantity of P required to maintain a solution P concentration that is adequate for crop demand. Bicarbonate-extractable P using the Colwell method is the most common soil P test used in Australia, and Colwell-P can be considered to estimate P quantity. Therefore, as P buffer capacity increases, the Colwell-P concentration required for maximum yield also increases. Data from several published and unpublished studies are used to derive relationships between the ‘critical’ Colwell-P value (Colwell-P at 90% maximum yield) and the single-point P buffer index (PBI) for annual medics, soybean, potato, wheat, and temperate pasture. The rate of increase in critical Colwell-P with increasing PBI increases in the order: temperate pasture < medics < wheat < potato. Indicative critical Colwell-P values are given for the 5 crops at each of the PBI categories used to describe soil P buffer capacity as it increases from extremely low to very high.


1976 ◽  
Vol 56 (3) ◽  
pp. 651-657 ◽  
Author(s):  
UMESH C. GUPTA

Sulfur deficiency symptoms in barley (Hordeum distichon L. cv. Volla) and wheat (Triticum aestivum L. cv. Opal) were related to < 0.12% S in boot stage tissue (BST) and kernels. The BST and kernel S concentrations of > 0.14% in barley and wheat were in the sufficiency range. The S deficiency and sufficiency levels in the three cuts of alfalfa (Medicago sativa L. cv. Saranac) tissue were 0.15–0.23% and > 0.23%, respectively. For cauliflower, tissue S concentrations of < 0.18% and > 0.19%, respectively, were in the deficiency and sufficiency ranges. Rutabaga (Brassica napobrassica Mill. cv. York) plant tissue S concentrations of < 0.10% were in the deficiency range, while > 0.21% were sufficient. Field survey tissue samples of rutabagas and cauliflower (Brassica oleracea botrytis L. cv. Snowball Y) were in the S sufficiency range, while most alfalfa and a few cereal samples indicated a slight S deficiency problem. The percent P in the BST and kernels of wheat and barley and alfalfa plant tissues was only slightly affected by S applications. Exceptions to this were the BST of barley from the second crop and plant tissue from third-cut alfalfa where S significantly decreased the P concentration of tissue. With added S, the P concentrations increased considerably in rutabaga tissue on both soils.


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